In oil and gas industries there are a lot off heat transfer devices used for different purposes. These devices are widely used in various industrial, transportation, or domestic applications such as heat exchangers thermal power plants, means of transport, heating and air conditioning systems, electronic equipments and space vehicles. In all these applications, improvements in the efficiency of heat exchangers can lead to substantial cost, space and materials savings. The research work summarized in this articles presents an experimental investigation on the effect of fin space (s) and aluminum materials on the fin performance using rectangular fins. The steady-state natural convection heat transfer from vertical rectangular fins extending perpendicularly from horizontal square base was investigated experimentally at new range not found in the previous works, this range of temperatures from 50 to 150 Co . The effects of fin space parameter and base-to-ambient temperature difference on the heat transfer performance of fin arrays were observed and the environmental condition were determined. Five fin space settings,( 22, 27, 30, 35 and 38 mm) with a constant fin height is 50mm for all types of configuration are presented in this work were employed under free convection heat transfer conditions. This range of fin space not found on previous study or research. The heat transfer area was kept the same. The performance of the fin expressed in terms of fin efficiency, effectiveness and thermal resistance as a function of the ambient temperature and fin space parameters has been study in this work. The dimensionless parameter Biot no. on the locally variable environmental condition is examined for different fin spaces to the fin heat transfer rate. Also, the effect of environmental condition is study. Experimental results show that the effect fin space on fin performance is more significant.. The maximum increase in convection heat transfer coefficient value obtained is about 22 percent. The increase in heat transfer coefficient value is also manifested by a corresponding decrease in the fin base temperature. Also, it is concluded from the experimental results that the performance of heat transfer rate increase with decreasing the fin space in respect of heat transfer coefficient, thermal resistance ,overall efficiency and effectiveness.