Refrigerative Stereolithography Using Sol-Gel Transformable Photopolymer Resin and Direct Masking

2000 ◽  
Author(s):  
Tamotsu Murakami ◽  
Akiya Kamimura ◽  
Naomasa Nakajima

Abstract The authors have been studying a new fabrication method termed “refrigerative stereolithography” which uses a gel resin layer instead of a liquid layer used in conventional stereolithography. In this paper, we propose the “direct masking method” in which a masking pattern is drawn directly on a gel layer surface to block harmful light exposure of photopolymer resin. With such masks, we can avoid surplus growth only in the regions where it is unnecessary to improve height direction accuracy and resolution. The possibility of surplus growth in the width direction caused by light reflection from the mask surface is pointed out, and the effect is analyzed and confirmed by simulation and experiment. This new surplus growth is termed “reflective surplus growth”. Also, we can solidify the required section shape selectively using the masks and a lamp instead of laser scan patterns. The effectiveness of refrigerative stereolithography with the direct masking method is discussed and confirmed by some experimental results.

2000 ◽  
Vol 625 ◽  
Author(s):  
T. Murakami ◽  
A. Kamimura ◽  
N. Nakajima

AbstractThe authors have been studying a new fabrication method termed “refrigerative stereolithography” which uses a gel resin layer instead of a liquid layer as in conventional stereolithography. This paper proposes the “direct masking method” in which a masking pattern is drawn to block direct light exposure to the surface of the gel resin layer. With such masks, we can avoid surplus growth only in the regions where it is unnecessary to improve height direction accuracy and resolution. Also, we can solidify the required section shape selectively using the masks and a lamp instead of laser scan patterns. The effectiveness of refrigerative stereolithography with the direct masking method is discussed and confirmed by some experimental results.


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 631
Author(s):  
Narges Shaabani ◽  
Nora W. C. Chan ◽  
Abebaw B. Jemere

A molecularly imprinted sol-gel is reported for selective and sensitive electrochemical determination of the drug naloxone (NLX). The sensor was developed by combining molecular imprinting and sol-gel techniques and electrochemically grafting the sol solution onto a functionalized multiwall carbon nanotube modified indium-tin oxide (ITO) electrode. The sol-gel layer was obtained from acid catalyzed hydrolysis and condensation of a solution composed of triethoxyphenylsilane (TEPS) and tetraethoxysilane (TES). The fabrication, structure and properties of the sensing material were characterized via scanning electron microscopy, spectroscopy and electrochemical techniques. Parameters affecting the sensor’s performance were evaluated and optimized. A sensor fabricated under the optimized conditions responded linearly between 0.0 µM and 12 µM NLX, with a detection limit of 0.02 µM. The sensor also showed good run-to-run repeatability and batch-to-batch performance reproducibility with relative standard deviations (RSD) of 2.5–7.8% (n = 3) and 9.2% (n = 4), respectively. The developed sensor displayed excellent selectivity towards NLX compared to structurally similar compounds (codeine, fentanyl, naltrexone and noroxymorphone), and was successfully used to measure NLX in synthetic urine samples yielding recoveries greater than 88%.


RSC Advances ◽  
2015 ◽  
Vol 5 (129) ◽  
pp. 106485-106491 ◽  
Author(s):  
A. Foroozan E. ◽  
R. Naderi

In this study, the effect of coating composition on the protective performance of an eco-friendly silane sol–gel film applied on a mild steel substrate was investigated using electrochemical impedance spectroscopy and surface analysis methods.


2018 ◽  
Vol 89 (1) ◽  
pp. 244-254 ◽  
Author(s):  
Cyrille Delneuville ◽  
Emeric P. Danloy ◽  
Li Wang ◽  
Bao-Lian Su

Catalysts ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1463
Author(s):  
Lucas A. Almeida ◽  
Margarita Habran ◽  
Rafael dos Santos Carvalho ◽  
Marcelo E. H. Maia da Costa ◽  
Marco Cremona ◽  
...  

The improvement of photocatalytic activity of TiO2-based nanomaterials is widely investigated due to the tentative of their industrialization as environmental photocatalysts and their inherently low solar spectrum sensitivity and rapid recombination of charge carriers. Coupling of oxygen-based bidentate diketone to nanocrystalline TiO2 represents a potential alternative for improving the holdbacks. Formation of TiO2-acetylacetone charge transfer complex (CTC) by sol-gel route results in a hybrid semiconductor material with photodegradation activity against toxic NOx gas. In this research, the influence of the chelating agent acetylacetone (ACAC) content on the CTC photocatalytic efficiency under visible light was evaluated. A high content of ACAC in the CTC is not a decisive factor for efficiency of photocatalytic reactions. In fact, the highest efficiency for NOx degradation (close to 100%, during 1 h of visible light exposure) was reported for the material calcined in air at 300 °C with the content of strongly bonded acetylacetone not higher than 3 wt.%. Higher calcination temperature (400 °C) left TiO2 almost completely depleted in ACAC, while at the highest applied temperature (550 °C) a portion of anatase was transformed into rutile and the sample is free of ACAC. The analyses pointed out that superoxide anion radical (O2−) plays an active role in photo-oxidation of NOx. Our findings indicate that this CTC has both high visible light spectral sensitivity and photocatalytic efficiency.


2007 ◽  
Vol 280-283 ◽  
pp. 1609-1612 ◽  
Author(s):  
Xiao Feng Chen ◽  
Ying Jun Wang ◽  
Na Ru Zhao ◽  
Jian Dong Ye ◽  
Yu Dong Zheng ◽  
...  

The biomaterials in system CaO-P2O5-SiO2 were synthesized via sol-gel method. The biomaterials can be applied to bone reparation and bone tissue engineering scaffolds The nano-pore structure, degradability, bioactivity and bio-mineralization characteristic of the biomaterials were investigated in details using XRD, SEM/EDX, FTIR, BET and DSC/TG techniques. It was indicated that the sol-gel derived biomaterials have a higher bioactivity than that of the melt derived bioactive glasses or glass-ceramics. It just takes 4-8 hours for HCA to form on the surface of the sol-gel samples in SBF solution at 37°C. The spherical HCA crystal clusters formed on the surface of the sol-gel derived samples immersed in SBF for 8 hours have a low crystallinity. Owing to their interconnected nano-sized pores, the sol-gel samples possess much higher surface areas and the hydrous porous SiO2 gel layer containing a great amount of ºSi-OH groups can be rapidly formed on the biomterials’ surface through a quick ion exchange between H3O+ in the solution and Ca2+ in the surface of the materials. ºSi-OH groups can play a very important role in inducing formation of HCA. They make the material surfaces electronegative, which resulted in a double electrode layer formed between the samples surface and SBF solution. The double electrode layer is in favor of formation of HCA on the surface of the materials.


2002 ◽  
Vol 21 (1-2) ◽  
pp. 183-188 ◽  
Author(s):  
Othman Belhadj Miled ◽  
Hafedh Ben Ouada ◽  
Jacques Livage
Keyword(s):  
Sol Gel ◽  

2005 ◽  
Vol 113 (1321) ◽  
pp. 634-636 ◽  
Author(s):  
Ryoji TAKAHASHI ◽  
Satoshi SATO ◽  
Toshiaki SODESAWA ◽  
Yuta HAGA ◽  
Masanari ISHIZUKI ◽  
...  

2014 ◽  
Vol 12 (11) ◽  
pp. 1682-1687 ◽  
Author(s):  
Tajamal Hussain ◽  
Hifza Munir ◽  
Adnan Mujahid ◽  
Muhammad Umar Farooq ◽  
Khurram Shehzad ◽  
...  
Keyword(s):  
Sol Gel ◽  

Sign in / Sign up

Export Citation Format

Share Document