Corrosion Resistance of Electroless Ni-P-W/ZrO2 Nanocomposite Coatings in Peracid Solutions

In current investigation, the Ni-P-W/ZrO2 electroless nanocomposite coatings are deposited upon mild steel substrate (AISI 1040 grade). The W/ZrO2 nanoparticles (50 to 130 nm range) were incorporated separately into acidic electroless Ni-P matrix as a second phase materials. The as-plated EL Ni-P-W/ZrO2 depositions were also heated at 400 οC in Argon atmosphere for one hour duration and analyzed by SEM/EDAX and XRD physical methods. The Ni-P-W/ZrO2 as-plated coupons revealed nebulous type structures while heated coupons showed crystalline structures in both cases. Furthermore Ni-P-ZrO2 coatings have very less cracks and gaps as compared to Ni-P-W coatings. The corrosion tests result in peracid (0.30 ± 0.02 % active oxygen) solutions point up that corrosivity of peracid ( 500 ppm Cl) is more than peracid (0 ppm Cl) and corrosion resistance of tested coupons varies as Ni-P-ZrO2 (as-plated) > Ni-P-ZrO2 (heated) > Ni-P-W (as-plated) > Ni-P-W (heated) > MS. The utilization of Ni-P-ZrO2 nanocomposite coatings in peracid solutions can be considered a cost effective option on the basis of its better cost/strength ratio in addition to its fair corrosion resistance.

Effect of pH and Immersion Time on the Corrosion Protection of SDBS:ZnSO4 Pretreated Mild Steel in Sodium Chloride Solution

In this study, mild steel was treated with SDBS:ZnSO4 compound by immersing the mild steel substrates in a SDBS:ZnSO4 bath of varying pH. The effect of bath solution pH and immersion time on the corrosion protection properties of SDBS:ZnSO4 pre-treated mild steel in sodium chloride solution was investigated using electrochemical impedance spectroscopy (EIS) and polarization measurements. From the EIS results, it was found that the inhibition efficiency provided by the pre-treatment was significantly affected by the pH of the bath solution, where inhibition was highest at pH 6. This is due to the formation of a good protective layer on mild steel substrate caused by the deposition of zinc hydroxide/oxide and SDBS compound. Increasing the immersion time from 1 h to 24 h increased the inhibition efficiency. From the polarization measurements, the current density was significantly reduced, and the shift to a more positive corrosion potential value indicated a higher protection layer was formed on the metal surface during more prolonged immersion. It has been found that longer pre-treatment immersion time allows a denser protective layer formed, which prevented the diffusion of water towards the mild steel substrate that can lead to corrosion.

Performance of a Direct Bonded Sub-Millimeter Peek Coating for Hydrodynamic Plain Bearings

Despite their superior tribological properties, thick-layer bearing coatings based on polyetheretherketone (PEEK) have up to now not been applied in a very high number of plain bearings for industrial applications. This can at least partly be credited to the high costs and low flexibility associated with the coating process for these materials. At the same time, while thick-layer polytetrafluoroethylene (PTFE) coatings have been successfully applied in industrial plain bearings for around 50 years, thin-layer PTFE coatings today constitute the majority of applications of PTFE in plain bearings. It is therefore reasonable to assume a similar approach for thin-layer PEEK coatings. This article reports the performance of a thin-layer PEEK coating directly applied on a mild steel substrate, with results ranging from first sample test through component tests to application in an actual machine and behavior during realistic operating conditions and induced bearing failure.