Advanced Technologies for Manufacturing High Strength Sour Grade UOE Line Pipe

Author(s):  
Kenji Kobayashi ◽  
Tomohiko Omura ◽  
Nobuaki Takahashi ◽  
Izuru Minato ◽  
Akio Yamamoto

X70 grade large diameter UOE linepipe steel for sour service has been manufactured stably by optimizing the continuous casting process, controlling the shape of inclusions and decreasing coarse precipitates. It is confirmed that the HIC and SSC resistance are good enough for severe sour conditions to apply. These higher strength linepipe steels for sour service are useful for the offshore and deep-sea pipelines. Additional improvements of HIC and SSC resistances are needed for manufacturing thicker and higher strength UOE linepipe steels for sour service. Optimizing alloying elements and ACC process are very important for the additional improvements of HIC and SSC resistance. In addition, the HIC evaluation method should be revised in order to match applied field conditions.

Author(s):  
Kenji Kobayashi ◽  
Tomohiko Omura ◽  
Masahiko Hamada ◽  
Hiroyuki Nagayama ◽  
Izuru Minato ◽  
...  

High-strength large-diameter UOE line pipes over X70 grade are difficult to apply to actual fields, including H2S, because of a deterioration of sour resistance and a lack of past performance. However, API X70 grade large-diameter UOE line pipes for sour service have been manufactured stably by optimizing the continuous casting process, controlling the shape of inclusions and decreasing coarse precipitates. A full-ring test can simulate fairly well the actual applied conditions of line pipes and evaluate hydrogen induced cracking (HIC), sulfide stress cracking (SSC) and stress oriented hydrogen induced cracking (SOHIC) of line pipes for sour service simultaneously. It was confirmed that the X70 grade UOE line pipes have a good sour resistance from standard HIC tests, four-point bent beam SSC tests and the full-ring test including a seam weld under severe sour conditions (NACE solution A with 0.1 MPa H2S). In addition, the SSC resistance of a girth welded portion was also investigated by using simulated HAZ.


2021 ◽  
Vol 73 (03) ◽  
pp. 60-61
Author(s):  
Judy Feder

This article, written by JPT Technology Editor Judy Feder, contains highlights of paper OTC 30558, “Development and Implementation of Heavy-Wall, High-Strength, Sour-Service Accessory and Risers for HP/HT Application in the Gulf of Mexico,” by Carine Landier, Jonathas Oliveira, and Christelle Gomes, Vallourec, et al., prepared for the 2020 Offshore Technology Conference, originally scheduled to be held in Houston, 4–7 May. The paper has not been peer reviewed. Copyright 2020 Offshore Technology Conference. Reproduced by permission. As oil and gas development in the Gulf of Mexico increasingly requires high-pressure/high-temperature (HP/HT) applications, the need for sour-service (SS) resistance also has grown. To meet these needs, continual innovation and improvement is needed in SS-grade materials from a technical and cost-effectiveness perspective. The complete paper discusses the material properties achieved with several large-diameter, heavy-wall SS pipes. The complete paper presents a detailed, illustrated discussion of the applications for the high-strength SS pipe and its manufacturing process. Applications The authors write that improved materials to meet HP/HT requirements such as those in the Gulf of Mexico are needed particularly for two applications: for risers, which require high-strength, thick-wall sour service; and as a substitute for corrosion-resistant alloy (CRA) with sour carbon material on defined accessories. Vallourec has developed high-strength [125,000-psi specified minimum yield strength (SMYS)] and resistant carbon steel pipes in sizes with outer diameter (OD) up to 23 in. and wall thickness up to 2.5 in. These sizes are common in lower-strength material, but meeting the high-pressure requirements with higher-grade material enables cost savings and eliminates some CRA components. It also enables the use of much-lighter-weight pipe than the 80,000-psi SMYS material that is standard for SS applications in oversize OD and heavy wall. Risers. Most deepwater drilling is performed with classic subsea blowout-preventer (BOP) systems. Access to the well through the BOP is accomplished with low-pressure, large-diameter (19-in. internal diameter) drilling riser pipe. Pipes are supplied in weldable grades (API 5L X65–X80). Large-diameter forged flanges are then welded onto the tubes. Connections are made by multiple bolts. High pressures, required as part of the drilling process, are supplied by small-diameter choke-and-kill lines. This system has served the industry well, but, as well pressures increase, so have cost and feasibility requirements of subsea BOP technology. These costs, driven by the complexity of redundant systems, have driven a desire to explore an alternative solution—a surface BOP with high-pressure drilling riser pipe. Using a surface BOP reduces the complexity and cost of the system significantly because of the ability to inspect it. The drilling riser then carries the pressure to the surface and must be able to contain it. The high-pressure environment that instigated a new solution was based on a 15,000-psi well pressure with NACE Region 2 SS performance. Because of the requirement for weldable grades for attaching the flange as well as SS, the maximum yield strength has been limited to 80,000 psi. At that strength, a very high wall thickness is required to meet 15,000 psi and greater. This becomes very heavy and can be limited by the rig hook-load capacity. Alternatives in weldable grades are nickel-based alloys with SS performance. A full string, however, is prohibitively expensive.


Author(s):  
K. Biermann ◽  
C. Kaucke ◽  
M. Probst-Hein ◽  
B. Koschlig

Offshore oil and gas production worldwide is conducted in increasingly deep waters, leading to more and more stringent demands on line pipes. Higher grades and heavier wall thicknesses in combination with deep temperature toughness properties, good weldability and suitability for sour service applications are among the characteristics called for. It is necessary that pipe manufacturers develop materials to meet these at times conflicting requirements. An alloying concept based on steel with very low carbon content is presented. This type of material provides excellent toughness properties at deep temperatures in line pipe with a wall thickness of up to 70 mm, produced by hot rolling followed by QT heat treatment. Pipes from industrial production of identical chemical composition and heat treatment achieved grades X65 to X80, depending on wall thickness. The properties of the steel used in pipes are presented. The resistance of the pipe material to the influence of sour gas was assessed by standard tests. To demonstrate weldability, test welds were performed and examined.


The demand for large diameter gas line pipe with high yield strength and high notch toughness has led to increased research in high strength low alloy steels. Physical metallurgists have developed both a fundamental and an empirical understanding of the properties and microstructures of ferrite pearlite steels. As specifications become more rigorous, alternative microstructures (low carbon bainite or tempered bainite and martensite) are being used in line pipe. There is a definite need for metallurgists to develop a clearer understanding of the interrelationships between their properties, microstructures, and processing before these alternatives are completely accepted for use in line pipe.


2021 ◽  
Author(s):  
Lam-Thanh Luc ◽  
Hamdi Saad ◽  
Matta Tanios ◽  
Dr. Al Bannay Aamer ◽  
Meer Mumtaz Ali Imtiaz Sirsimth ◽  
...  

Abstract In the wake of failures of large diameter pipelines made from plates using the Thermo-Mechanically Controlled Process (TMCP), the suitability of carbon steel material for sour environments where the H2S partial pressure is largely over 1 bar has been questioned. Understanding that seamless quench and tempered material are not prone to the same phenomenon as large diameter TMCP pipes, it has been decided to ensure the integrity of the DIYAB pipeline by qualification using the actual production environment pH=3.5 at 24°C and 6.84 bar H2S plus 6.84 bar CO2. The global approach includes the qualification to sour service resistance under 6.84bar H2S of the base material and the welds without post weld heat treatment. Fracture toughness tests under 6.84bar H2S were also conducted, and the results fed into an Engineering Criticality Assessment (ECA) to define the Non-Destructive Testing (NDT) acceptance criteria. The NDT tools were selected for their ability to detect the critical flaws and validated. The global approach methodology and results are presented.


Author(s):  
L. E. Collins ◽  
K. Dunnett ◽  
T. Hylton ◽  
A. Ray

A decade ago, the pipeline industry was actively exploring the use of high strength steels (X80 and greater) for long distance, large diameter pipelines operating at high pressures. However in recent years the industry has adopted a more conservative approach preferring to utilize well established X70 grade pipe in heavier wall thicknesses to accommodate the demand for increased operating pressures. In order to meet this demand, EVRAZ has undertaken a substantial upgrade of both its steelmaking and helical pipemaking facilities. The EVRAZ process is relatively unique employing electric arc furnace (EAF) steelmaking to melt scrap, coupled with Steckel mill rolling for the production of coil which is fed into helical DSAW pipe mills for the production of large diameter line pipe in lengths up to 80 feet. Prior to the upgrade production had been limited to a maximum finished wall thickness of ∼17 mm. The upgrades have included installation of vacuum de-gassing to reduce hydrogen and nitrogen levels, upgrading the caster to improve cast steel quality and allow production of thicker (250 mm) slabs, upgrades to the power trains on the mill stands to achieve greater rolling reductions, replacement of the laminar flow cooling system after rolling and installation of a downcoiler capable of coiling 25.4 mm X70 material. As well a new helical DSAW mill has been installed which is capable of producing large diameter pipe in thicknesses up to 25.4 mm. The installation of the equipment has provided both opportunities and challenges. Specific initiatives have sought to produce X70 line pipe in thicknesses up to 25.4 mm, improve low temperature toughness and expand the range of sour service grades available. This paper will focus on alloy design and rolling strategies to achieve high strength coupled with low temperature toughness. The role of improved centerline segregation control will be examined. The use of scrap as a feedstock to the EAF process results in relatively high nitrogen contents compared to blast furnace (BOF) operations. While nitrogen can be reduced to some extent by vacuum de-gassing, rolling practices must be designed to accommodate nitrogen levels of 60 ppm. Greater slab thickness allows greater total reduction, but heat removal considerations must be addressed in optimization of rolling schedules to achieve suitable microstructures to achieve both strength and toughness. This optimization requires definition of the reductions to be accomplished during roughing (recrystallization rolling to achieve a fine uniform austenite grain size) and finishing (pancaking to produce heavily deformed austenite) and specification of cooling rates and coiling temperatures subsequent to rolling to obtain suitable transformation microstructures. The successful process development will be discussed.


Author(s):  
Kimberly K. Cameron ◽  
Alfred M. Pettinger

Over time, the demand for high-strength linepipe has increased significantly. One of the challenges for developing higher strength linepipe has been maintaining an appropriate level of fracture toughness, yield to tensile strength ratio, and weldability. Fortunately, significant progress has been made in the production of high strength line pipe steel. A major improvement in steel making has been the utilization of secondary steel treatments to refine the steel and accurately control alloy additions to achieve a higher level of steel cleanliness. In particular, these refining treatments have enabled the achievement of extremely low sulfur levels. For most purposes, restricting sulfur content is desirable to help prevent a reduction in mechanical properties such as fracture toughness of the steel. Fortunately, steelmaking and desulfurization technologies have advanced to the point where pipeline steel with sulfur contents less than the requirements by API 5L are available on a large scale. Extremely low sulfur contents, however, can lead to other problems when welding steels. These weldability problems are related to the fact that sulfur is a known surface active agent for steels. Low sulfur concentrations lead to a reversal of the Marangoni convection in the weld pool, which is responsible for the large differences in weld penetration on otherwise identical steels. Additionally, when welding heats of unmatched sulfur concentrations, the arc will tend to deviate towards the low sulfur heat and axially shift the root of the weld if one of the heats was below a critical value for the sulfur content and the other was above this value. Although this phenomenon has been primarily observed in stainless steels, the increasing ability to produce linepipe steel with extremely low sulfur contents has led to the possibility that this phenomenon could also occur in low carbon pipeline steels. One pipeline system utilizing cellulosic consumables for shielded metal arc welding (SMAW) of X70 steel with sulfur contents an order of magnitude below that permitted by API 5L and with widely varying sulfur contents shows evidence of this effect. The profiles of the welds in this system exhibited a tendency for lack of penetration, asymmetric weld roots, and concave welds. One approach to ameliorate this would be the specification of a lower permissible amount of sulfur.


Author(s):  
Joachim Konrad ◽  
Diana Toma ◽  
Volker Rohden ◽  
Guido Kubla

The continued shift of exploration and production to deep water fields will require the industry to develop alternative pipe solutions to cope with the challenging demands of these exploration regions. Because of the complexity of exploration conditions in deep water fields, e.g. high pressures, low temperature and sour reservoirs, higher grades and heavier wall thickness in combination with low temperature toughness and suitability for sour service are required. The Vallourec&Mannesmann Tubes’s alloying concept for line pipe steels based on low carbon concept [1] was extended to grades X70 and X80 with wall thicknesses up to 75mm. In this paper the latest results on industrial studies on high strength heavy-wall steels manufactured by seamless hot rolling and subsequent quench and temper treatment are presented. The work is a part of the development program for high performance heavy wall seamless pipes for special applications such as J-lay collars, buckle arrestors and risers. Mechanical properties, advanced metallographic examinations, results of the sour service resistance and weldability are reported.


Author(s):  
Yuji Arai ◽  
Kunio Kondo ◽  
Masahiko Hamada ◽  
Nobuyuki Hisamune ◽  
Nobutoshi Murao ◽  
...  

High strength heavy wall sour service seamless line pipe suitable for deep water applications has been developed by Sumitomo Metal Industries, Ltd.,. This paper describes the concept of developing these pipes applying inline heat treatment technology, equipped in a newly constructed, medium-size seamless mill. Increasing hardenability through inline heat treatment achieved higher strength (X70) for heavy wall pipe (40mm) even though carbon equivalent was lower than in a conventional Q&T process. Good toughness was obtained by the control of microalloying elements such as titanium or sulfur. The produced pipe passed the hydrogen-induced cracking (HIC) test conducted according to NACE TM 0284 solution A. Controlling the microstructure and suppressing maximum hardness, utilizing the uniform quenching facility during inline heat treatment, contributed to the test result. Satisfactory data on weldability for practical use were also obtained.


Author(s):  
Tom Zimmerman ◽  
Gary Stephen ◽  
Alan Glover

There has been a general trend in the natural gas pipeline transmission industry towards high-pressure pipelines using higher strength steels. However, as the strength has been increased, so have issues of weldability and fracture control. TransCanada PipeLines has been developing and testing a hybrid product since 1996 called Composite Reinforced Line Pipe (CRLP®) to address these issues. This is a patented technology developed by NCF Industries and licensed on a worldwide basis to TransCanada PipeLines. CRLP® is composed of high performance, composite material reinforcing a proven high-strength, low alloy steel pipe. The composite reinforces the steel pipe in the hoop direction, thereby increasing its pressure carrying capacity, while providing a tough, corrosion-resistant coating. This paper discusses recent research work concerning the use of CRLP® for large-diameter gas pipeline systems. Aspects discussed include analysis and design methodologies, full-scale testing, and field trials.


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