Preparation and characterization of self-healing poly (urea-formaldehyde) microcapsules

Author(s):  
Haiyan Li ◽  
Rongguo Wang ◽  
Xiaodong He ◽  
Wenbo Liu ◽  
Huanying Hao
2009 ◽  
Vol 113 (3) ◽  
pp. 1501-1506 ◽  
Author(s):  
Rongguo Wang ◽  
Haiyan Li ◽  
Honglin Hu ◽  
Xiaodong He ◽  
Wenbo Liu

2012 ◽  
Vol 430-432 ◽  
pp. 960-963 ◽  
Author(s):  
Wan Peng Ma ◽  
Wei Zhang ◽  
Yang Zhao ◽  
Le Ping Liao ◽  
Si Jie Wang

Urea-formaldehyde microcapsules containing epoxy resin is a promising material for self-healing design. The microcapsules were prepared by in-situ polymerization in an oil-in-water emulsion. The microcapsule formation process was monitored using optical microscopy. Surface morphology was observed using field emission scanning electron microscopy. The thermal property of microcapsules was characterized using thermogravimetric analysis. The results indicate that microcapsule wall has a rough outer surface and a smooth inner surface. The microcapsule size is controlled by different agitation rates. Microcapsules have a good thermal stability below 157°C.


Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 869
Author(s):  
Minghua Wei ◽  
Shaopeng Wu ◽  
Haiqin Xu ◽  
Hechuan Li ◽  
Chao Yang

Steel slag is the by-product of the steelmaking industry, the negative influences of which prompt more investigation into the recycling methods of steel slag. The purpose of this study is to characterize steel slag filler and study its feasibility of replacing limestone filler in asphalt concrete by evaluating the resistance of asphalt mastic under various aging methods. Firstly, steel slag filler, limestone filler, virgin asphalt, steel slag filler asphalt mastic and limestone filler asphalt mastic were prepared. Subsequently, particle size distribution, surface characterization and pore characterization of the fillers were evaluated. Finally, rheological property, self-healing property and chemical functional groups of the asphalt mastics with various aging methods were tested via dynamic shear rheometer and Fourier transform infrared spectrometer. The results show that there are similar particle size distributions, however, different surface characterization and pore characterization in the fillers. The analysis to asphalt mastics demonstrates how the addition of steel slag filler contributes to the resistance of asphalt mastic under the environment of acid and alkaline but is harmful under UV radiation especially. In addition, the pore structure in steel slag filler should be a potential explanation for the changing resistance of the asphalt mastics. In conclusion, steel slag filler is suggested to replace limestone filler under the environment of acid and alkaline, and environmental factor should be taken into consideration when steel slag filler is applied to replace natural fillers in asphalt mastic.


2021 ◽  
pp. 102450
Author(s):  
Shubin Li ◽  
Xiao Wang ◽  
Jiang Zhu ◽  
Zhenyu Wang ◽  
Lu Wang

BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 6795-6810
Author(s):  
Nurul Fatiha Osman ◽  
Paimon Bawon ◽  
Seng Hua Lee ◽  
Pakhriazad Hassan Zaki ◽  
Syeed SaifulAzry Osman Al-Eldrus ◽  
...  

Particleboard was produced by mixing oil heat-treated rubberwood particles at different ratios, with the goal of achieving high dimensional stability. Rubberwood particles were soaked in palm oil for 2 h and heat treated at 200 °C for 2 h. The treated particles were soaked in boiling water for 30 min to remove oil and were tested for chemical alteration and thermal characterization via Fourier-transform infrared spectroscopy and thermogravimetric analysis. Particleboard was fabricated by mixing treated rubberwood particles (30%, 50%, and 70%) with untreated particles (70%, 50%, and 30%, respective to previous percentages) and bonded with urea-formaldehyde (UF) resin. The results revealed that oil-heat treated particles had greater thermal stability than the untreated particles. The addition of oil heat treated particles improved the physical properties of the particleboard with no significant reduction in mechanical strength. However, this was only valid for ratios of 70% untreated to 30% treated and 50% untreated to 50% treated. When a ratio of 70% oil heat treated particles was used, both the physical and mechanical properties were reduced drastically, due to bonding interference caused by excessive oil content. Particleboard made with a ratio of 5:5 (treated to untreated) exhibited the best physical and mechanical properties.


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