scholarly journals Coordination-induced polymerization of P═C bonds leads to regular (P─C)n polycarbophosphanes

2021 ◽  
Vol 7 (11) ◽  
pp. eabf4272
Author(s):  
Yanbo Mei ◽  
Juan José Gamboa-Carballo ◽  
Yinyin Bao ◽  
Na Wu ◽  
Grégoire Le Corre ◽  
...  

The replacement of carbon in (C─C)n chains of polyolefins by phosphorus leads to polycarbophosphanes (P─C)n, which may possess unique chemical and physical properties. However, macromolecules with a regular (P─C)n chain have never been unambiguously identified. Here, we demonstrate that addition polymerization, a general concept to polymerize olefins, can be extended to P═C double bonds. The polymerization of monomeric 2-phosphanaphthalenes is mediated by copper(I) halides and leads to polycarbophosphanes with an Mn of 14 to 34 kDa. Each phosphorus is coordinated to Cu(I), which can be easily removed. Unlike long-term durable polyolefins, the metal-free polymers depolymerize rapidly back to monomers under sunlight or ultraviolet irradiation at λ = 365 nm. The monomers can be recycled for repolymerization, demonstrating a cradle-to-cradle life cycle for polycarbophosphanes.


Alloy Digest ◽  
2010 ◽  
Vol 59 (1) ◽  

Abstract Kubota KNC-03 is a grade with a combination of high strength and excellent resistance to oxidation. These properties make this alloy suitable for long-term service at temperature up to 1250 deg C (2282 deg F). This datasheet provides information on physical properties, hardness, elasticity, tensile properties, and compressive strength as well as creep. It also includes information on high temperature performance as well as casting and joining. Filing Code: Ni-676. Producer or source: Kubota Metal Corporation, Fahramet Division. See also Alloy Digest Ni-662, April 2008.



Alloy Digest ◽  
2011 ◽  
Vol 60 (12) ◽  

Abstract Kubota Alloy HD (UNS J93005) is a heat-resisting stainless steel casting alloy suitable for long-term service at temperatures up to 1095 deg C (2000 deg F). The nearest wrought equivalent is type 327. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as creep. It also includes information on corrosion resistance as well as casting and joining. Filing Code: SS-1110. Producer or source: Kubota Metal Corporation, Fahramet Division.



Alloy Digest ◽  
2010 ◽  
Vol 59 (5) ◽  

Abstract Kubota Alloy HC is a heat resisting stainless steel casting suitable for long term service at temperatures up to 1093 deg C (2000 deg F). This alloy can maintain resistance to sulfur bearing environments up to 1093 deg C (2000 deg F). This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on corrosion resistance as well as casting and joining. Filing Code: SS-1065. Producer or source: Kubota Metal Corporation, Fahramet Division.



Alloy Digest ◽  
1997 ◽  
Vol 46 (5) ◽  

Abstract Duracorr is low-cost, utilitarian 11% Cr stainless steel with more corrosion resistance and life-cycle cost advantages than weathering steels. The steel may be used where a combination of abrasion and corrosion resistance is required. This datasheet provides information on composition, physical properties, microstructure, hardness, tensile properties, and bend strength as well as fracture toughness. It also includes information on corrosion resistance as well as joining. Filing Code: SS-680. Producer or source: Lukens Steel Company.



2003 ◽  
Vol 67 (2) ◽  
pp. 637 ◽  
Author(s):  
Achmad Rachman ◽  
S. H. Anderson ◽  
C. J. Gantzer ◽  
A. L. Thompson


2016 ◽  
Vol 2016 (14) ◽  
pp. 830-854
Author(s):  
Tzahi Y Cath ◽  
Ryan W Holloway ◽  
Leslie Miller-Robbie ◽  
Mehul Patel ◽  
Jennifer R Stokes ◽  
...  


2019 ◽  
Vol 43 (6) ◽  
pp. 347-354 ◽  
Author(s):  
Daniela Popp ◽  
Romanus Diekmann ◽  
Lutz Binder ◽  
Abdul R. Asif ◽  
Sara Y. Nussbeck

Abstract Various information technology (IT) infrastructures for biobanking, networks of biobanks and biomaterial management are described in the literature. As pre-analytical variables play a major role in the downstream interpretation of clinical as well as research results, their documentation is essential. A description for mainly automated documentation of the complete life-cycle of each biospecimen is lacking so far. Here, the example taken is from the University Medical Center Göttingen (UMG), where the workflow of liquid biomaterials is standardized between the central laboratory and the central biobank. The workflow of liquid biomaterials from sample withdrawal to long-term storage in a biobank was analyzed. Essential data such as time and temperature for processing and freezing can be automatically collected. The proposed solution involves only one major interface between the main IT systems of the laboratory and the biobank. It is key to talk to all the involved stakeholders to ensure a functional and accepted solution. Although IT components differ widely between clinics, the proposed way of documenting the complete life-cycle of each biospecimen can be transferred to other university medical centers. The complete documentation of the life-cycle of each biospecimen ensures a good interpretability of downstream routine as well as research results.



Author(s):  
Serenella Sala ◽  
Andrea Martino Amadei ◽  
Antoine Beylot ◽  
Fulvio Ardente

Abstract Purpose Life cycle thinking (LCT) and life cycle assessment (LCA) are increasingly considered pivotal concept and method for supporting sustainable transitions. LCA plays a relevant role in decision support, for the ambition of a holistic coverage of environmental dimensions and for the identification of hotspots, possible trade-offs, and burden shifting among life cycle stages or impact categories. These features are also relevant when the decision support is needed in policy domain. With a focus on EU policies, the present study explores the evolution and implementation of life cycle concepts and approaches over three decades. Methods Adopting an historical perspective, a review of current European Union (EU) legal acts and communications explicitly mentioning LCT, LCA, life cycle costing (LCC), and environmental footprint (the European Product and Organisation Environmental Footprint PEF/OEF) is performed, considering the timeframe from 1990 to 2020. The documents are categorised by year and according to their types (e.g. regulations, directives, communications) and based on the covered sectors (e.g. waste, energy, buildings). Documents for which life cycle concepts and approaches had a crucial role are identified, and a shortlist of these legal acts and communications is derived. Results and discussion Over the years, LCT and life cycle approaches have been increasingly mentioned in policy. From the Ecolabel Regulation of 1992, to the Green Deal in 2019, life cycle considerations are of particular interest in the EU. The present work analysed a total of 159 policies and 167 communications. While in some sectors (e.g. products, vehicles, and waste) life cycle concepts and approaches have been adopted with higher levels of prescriptiveness, implementation in other sectors (e.g. food and agriculture) is only at a preliminary stage. Moreover, life cycle (especially LCT) is frequently addressed and cited only as a general concept and in a rather generic manner. Additionally, more stringent and rigorous methods (LCA, PEF/OEF) are commonly cited only in view of future policy developments, even if a more mature interest in lifecycle is evident in recent policies. Conclusion The EU has been a frontrunner in the implementation of LCT/LCA in policies. However, despite a growing trend in this implementation, the development of new stringent and mandatory requirements related to life cycle is still relatively limited. In fact, there are still issues to be solved in the interface between science and policy making (such as verification and market surveillance) to ensure a wider implementation of LCT and LCA.



Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3549
Author(s):  
Tulane Rodrigues da Silva ◽  
Afonso Rangel Garcez de Azevedo ◽  
Daiane Cecchin ◽  
Markssuel Teixeira Marvila ◽  
Mugahed Amran ◽  
...  

The urbanization process contributes to the growth of solid waste generation and causes an increase in environmental impacts and failures in the management of solid waste. The number of dumps is a concern due to the limited implementation and safe disposal of this waste. The interest in sustainable techniques has been growing in relation to waste management, which is largely absorbed by the civil construction sector. This work aimed to review plastic waste, especially polyethylene terephthalate (PET), that can be incorporated with construction materials, such as concrete, mortars, asphalt mixtures, and paving. The use of life-cycle assessment (LCA) is related, as a tool that allows the sustainability of products and processes to be enhanced in the long term. After analyzing the recent literature, it was identified that studies related to plastic wastes in construction materials concentrate sustainability around the alternative destination of waste. Since the plastic waste from different production chains are obtained, it was possible to affirm the need for a broader assessment, such as the LCA, providing greater quantification of data making the alternative processes and products more sustainable. The study contributes to enhance sustainability in alternative building materials through LCA.



Buildings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 215
Author(s):  
Bojana Petrović ◽  
Xingxing Zhang ◽  
Ola Eriksson ◽  
Marita Wallhagen

The objective of this paper was to explore long-term costs for a single-family house in Sweden during its entire lifetime. In order to estimate the total costs, considering construction, replacement, operation, and end-of-life costs over the long term, the life cycle cost (LCC) method was applied. Different cost solutions were analysed including various economic parameters in a sensitivity analysis. Economic parameters used in the analysis include various nominal discount rates (7%, 5%, and 3%), an inflation rate of 2%, and energy escalation rates (2–6%). The study includes two lifespans (100 and 50 years). The discounting scheme was used in the calculations. Additionally, carbon-dioxide equivalent (CO2e) emissions were considered and systematically analysed with costs. Findings show that when the discount rate is decreased from 7% to 3%, the total costs are increased significantly, by 44% for a 100-year lifespan, while for a 50 years lifespan the total costs show a minor increase by 18%. The construction costs represent a major part of total LCC, with labor costs making up half of them. Considering costs and emissions together, a full correlation was not found, while a partial relationship was investigated. Results can be useful for decision-makers in the building sector.



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