scholarly journals Unifying fluctuation-dissipation temperatures of slow-evolving nonequilibrium systems from the perspective of inherent structures

2021 ◽  
Vol 7 (31) ◽  
pp. eabg6766
Author(s):  
Jianhua Zhang ◽  
Wen Zheng ◽  
Shiyun Zhang ◽  
Ding Xu ◽  
Yunhuan Nie ◽  
...  

For nonequilibrium systems, how to define temperature is one of the key and difficult issues to solve. Although effective temperatures have been proposed and studied to this end, it still remains elusive what they actually are. Here, we focus on the fluctuation-dissipation temperatures and report that such effective temperatures of slow-evolving systems represent characteristic temperatures of their equilibrium counterparts. By calculating the fluctuation-dissipation relation of inherent structures, we obtain a temperature-like quantity TIS. For monocomponent crystal-formers, TIS agrees well with the crystallization temperature Tc, while it matches with the onset temperature Ton for glass-formers. It also agrees with effective temperatures of typical nonequilibrium systems, such as aging glasses, quasi-static shear flows, and quasi-static self-propelled flows. From the unique perspective of inherent structures, our study reveals the nature of effective temperatures and the underlying connections between nonequilibrium and equilibrium systems and confirms the equivalence between Ton and Tc.

Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 956 ◽  
Author(s):  
Yongbo Ma ◽  
Xueyan Du

To recover iron from water-quenched nickel slags, CaO was added. Thermodynamic analysis showed that CaO promotes the reaction between fayalite (Fe2SiO4) and O2. Phase diagrams of the FeO-SiO2-MgO-CaO slag with various CaO contents in an air atmosphere drawn by FactSage 7.1 showed that the phase components can be significantly affected by the CaO contents. With increasing CaO content, the fusion characteristic temperatures decreased rapidly to a minimum and subsequently increased slightly. The oxidization of Fe2SiO4 in nickel slags was accelerated significantly by the addition of CaO, which led to an increase of FeO activity and decrease of Fe2O3 activity to promote the formation of MgFe2O4. Excess addition of CaO led to the formation of more silicates. In addition, the crystallization temperature was also reduced with increasing CaO content, causing less spinel to crystalize. With increasing CaO content, the iron recovery and yield of concentrate first increased and subsequently decreased, while the total iron (TFe) content was almost not influenced and maintained a relatively stable value.


2008 ◽  
Vol 84 (2) ◽  
pp. 20006 ◽  
Author(s):  
S. Jabbari-Farouji ◽  
D. Mizuno ◽  
D. Derks ◽  
G. H. Wegdam ◽  
F. C. MacKintosh ◽  
...  

2016 ◽  
Vol 69 (2) ◽  
pp. 7945-7954 ◽  
Author(s):  
Ezequiel Pérez-Monterroza ◽  
Héctor José Ciro-Velásquez ◽  
Julio César Arango Tobón

The effect of the concentration of monodiglycerides, beeswax and sorbitan monostearate (SMS) on the thermal behavior of oleogels prepared from avocado oil, as well as the effect of the cooling rate on the onset temperature (Tonset) and the crystallization temperature (Tc), were evaluated by DSC and X-ray diffraction. The results showed that the structuring agents have a significant effect (P<0.05) on the Tc and Tonset, which demonstrated their ability to form solid lipids. Moreover, it was found that the presence of SMS decreased the Tc and Tonset, possibly due to their cocrystallization process. It was found only in the presence of the polymorphic form b' in the oleogels prepared. The Tc varied between 1.6 and 51.4 °C and Tonset between 3.9 and 53.8 °C.


Author(s):  
N. Rozhanski ◽  
A. Barg

Amorphous Ni-Nb alloys are of potential interest as diffusion barriers for high temperature metallization for VLSI. In the present work amorphous Ni-Nb films were sputter deposited on Si(100) and their interaction with a substrate was studied in the temperature range (200-700)°C. The crystallization of films was observed on the plan-view specimens heated in-situ in Philips-400ST microscope. Cross-sectional objects were prepared to study the structure of interfaces.The crystallization temperature of Ni5 0 Ni5 0 and Ni8 0 Nb2 0 films was found to be equal to 675°C and 525°C correspondingly. The crystallization of Ni5 0 Ni5 0 films is followed by the formation of Ni6Nb7 and Ni3Nb nucleus. Ni8 0Nb2 0 films crystallise with the formation of Ni and Ni3Nb crystals. No interaction of both films with Si substrate was observed on plan-view specimens up to 700°C, that is due to the barrier action of the native SiO2 layer.


Author(s):  
F. Khoury ◽  
L. H. Bolz

The lateral growth habits and non-planar conformations of polyethylene crystals grown from dilute solutions (<0.1% wt./vol.) are known to vary depending on the crystallization temperature.1-3 With the notable exception of a study by Keith2, most previous studies have been limited to crystals grown at <95°C. The trend in the change of the lateral growth habit of the crystals with increasing crystallization temperature (other factors remaining equal, i.e. polymer mol. wt. and concentration, solvent) is illustrated in Fig.l. The lateral growth faces in the lozenge shaped type of crystal (Fig.la) which is formed at lower temperatures are {110}. Crystals formed at higher temperatures exhibit 'truncated' profiles (Figs. lb,c) and are bound laterally by (110) and (200} growth faces. In addition, the shape of the latter crystals is all the more truncated (Fig.lc), and hence all the more elongated parallel to the b-axis, the higher the crystallization temperature.


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