The distribution of nitrogen (N) was determined on 1238 surface sediment samples (0–3 cm) and 24 cores from Lakes Superior, Huron, St. Clair, Erie, and Ontario. The concentration of N was greatest in the depositional basins of the lakes. The N concentrations decreased sharply from high values at the sediment–water interface to uniformly lower N values at the base of the cores. The surface enrichment was related to increased inputs of N to the lakes since settlement of the region in the order: Lake Ontario > Lake Erie [Formula: see text] Lake Superior > Lake Huron > Georgian Bay.The organic carbon: total nitrogen (C/N) ratios averaged 10.2 in the surface sediments with a range of 5.1 to 66.0. The lowest ratios were found in the depositional basins, with the exception of Lake St. Clair. The magnitude of the C/N ratios was related to the source of the organic matter. Plankton, which are the main source of Org-N in the lakes, accounted for C/N ratios between 7 and 9. Dilution of the modern sediment with organic matter from glacial deposits yielded the higher ratios and low Org-C contents in the nondepositional zones. The high C/N ratios and Org-C contents in Lake St. Clair were believed to be due to a large component of macrophytes in the inputs of organic matter to the lake sediments.
Rapid wetland expansion during European settlement and its implication for marsh survival under modern sediment delivery rates
