scholarly journals A tale of five enclaves: Mineral perspectives on origins of mafic enclaves in the Tuolumne Intrusive Complex

Geosphere ◽  
2021 ◽  
Author(s):  
C.G. Barnes ◽  
K. Werts ◽  
V. Memeti ◽  
S.R. Paterson ◽  
R. Bremer

The widespread occurrence of mafic magmatic enclaves (mme) in arc volcanic rocks attests to hybridization of mafic-intermediate magmas with felsic ones. Typically, mme and their hosts differ in mineral assemblage and the compositions of phenocrysts and matrix glass. In contrast, in many arc plutons, the mineral assemblages in mme are the same as in their host granitic rocks, and major-element mineral compositions are similar or identical. These similarities lead to difficulties in identifying mixing end members except through the use of bulk-rock compositions, which themselves may reflect various degrees of hybridization and potentially melt loss. This work describes the variety of enclave types and occurrences in the equigranular Half Dome unit (eHD) of the Tuolumne Intrusive Complex and then focuses on textural and mineral composition data on five porphyritic mme from the eHD. Specifically, major- and trace-element compositions and zoning patterns of plagioclase and hornblende were measured in the mme and their adjacent host granitic rocks. In each case, the majority of plagioclase phenocrysts in the mme (i.e., large crystals) were derived from a rhyolitic end member. The trace-element compositions and zoning patterns in these plagioclase phenocrysts indicate that each mme formed by hybridization with a distinct rhyolitic magma. In some cases, hybridization involved a single mixing event, whereas in others, evidence for at least two mixing events is preserved. In contrast, some hornblende phenocrysts grew from the enclave magma, and others were derived from the rhyolitic end member. Moreover, the composition of hornblende in the immediately adjacent host rock is distinct from hornblende typically observed in the eHD. Although primary basaltic magmas are thought to be parental to the mme, little or no evidence of such parents is preserved in the enclaves. Instead, the data indicate that hybridization of already hybrid andesitic enclave magmas with rhyolitic magmas in the eHD involved multiple andesitic and rhyolitic end members, which in turn is consistent with the eHD representing an amalgamation of numerous, compositionally distinct magma reservoirs. This conclusion applies to enclaves sampled <30 m from one another. Moreover, during amalgamation of various rhyolitic reservoirs, some mme were evidently disrupted from a surrounding mush and thus carried remnants of that mush as their immediately adjacent host. We suggest that detailed study of mineral compositions and zoning in plutonic mme provides a means to identify magmatic processes that cannot be deciphered from bulk-rock analysis.

2020 ◽  
Author(s):  
Silvia Volante ◽  
William Collins ◽  
Chris Spencer ◽  
Eleanore Blereau ◽  
Amaury Pourteau ◽  
...  

<p>In this contribution, we compare and test the reliability of zircon and monazite thermometers and suggest a new and independent method to constrain the H<sub>2</sub>O content in granitic magmas from coeval zircon and monazite minerals. We combine multi-method single-mineral thermometry (bulk-rock zirconium saturation temperature (T<sub>zr</sub>), Ti-in-zircon (T<sub>(Ti-zr</sub><sub>)</sub>) and monazite saturation temperature (T<sub>mz</sub>)) with thermodynamic modelling to estimate water content and P–T conditions for strongly-peraluminous (S-type) granitoids in the Georgetown Inlier, NE Queensland. These granites were generated within ~30 km thick Proterozoic crust, and emplaced during regional extension associated with low-pressure high-temperature (LP–HT) metamorphism.</p><p>SHRIMP U–Pb monazite and zircon geochronology indicates synchronous crystallization ages of c. 1550 Ma for granitic rocks emplaced at different crustal levels—from the eastern deep crustal domain (P = 6–9 kbar), through the middle crustal domain (P = 4–6 kbar), to the western upper crustal domain (P = 0–3 kbar).</p><p>Bulk-rock T<sub>zr</sub> and T<sub>(Ti-zr</sub><sub>)</sub> yielded magma temperature estimates for the eastern domain of ~800°C and ~910–720°C, respectively. Magma temperatures in the central and western domains were ~730°C (T<sub>zr</sub>) and ~870–750°C (T<sub>(Ti-zr)</sub>) in the central domain, and ~810°C (T<sub>zr</sub>) and ~890–720°C (T<sub>(Ti-zr)</sub>) in the western domain, respectively. These temperature estimates were compared with P–T conditions recorded in the host rocks to determine if the magmas had equilibrated thermally with the crust. Similar temperatures were obtained for the middle and lower crust suggesting that the associated magmas thermally equilibrated at their respective depths, whereas the sub-volcanic rocks were, as expected, significantly hotter than the adjacent crust.</p><p>By plotting the results on a P–T–X<sub>H2O</sub> petrogenetic grid, and assuming adiabatic ascent through the crust, the sub-volcanic magmas appear to be drier (~3 wt% H<sub>2</sub>O) than the granitic magmas (~7 wt% H<sub>2</sub>O) which formed at greater depth. Monazite saturation temperatures (which depends on the water content, light–REE content and composition of the granitic melt), are in agreement with the zircon thermometers only if water values of ~3 wt% H<sub>2</sub>O and ~7 wt% H<sub>2</sub>O are assumed for the upper crustal magmas and deeper magmas, respectively. Moreover, melt compositions extracted from a modelled pseudosection of a sillimanite-bearing metapelite, which was interpreted to be the typical source rock for the surrounding granites (P=5 kbar and T=690°C–850°C), show comparable water content values.</p><p>The T<sub>mz</sub> results provide independent evidence for the H<sub>2</sub>O content in magmas, and we suggest that reconciling T<sub>zr</sub> with T<sub>mz</sub> is a new and independent way of constraining H<sub>2</sub>O content in granitic magmas.</p>


1991 ◽  
Vol 28 (2) ◽  
pp. 172-183 ◽  
Author(s):  
Michel Jébrak ◽  
Luc Harnois

The Taschereau stock occurs north of Timmins and Val-d'Or, Quebec, in the Abitibi greenstone belt of the Superior Province. This late Archean composite pluton is composed mainly of diorite–tonalite–trondhjemite cut by granitic rocks. Gold–molybdenum occurrences are associated with a zone of albite-rich rocks surrounding the granitic rocks. Diabase dykes and shear zones postdate all rock units. Field and geochemical evidence suggests that the Taschereau stock was emplaced diachronously. Trace-element geochemical modelling shows that trace-element abundances (rare-earth elements, Ti, Zr) of Taschereau granitic rocks are consistent with partial melting of preexisting Taschereau tonalitic rocks and implies that these two rock types are not end members of a single magma that evolved through fractional crystallization.


2020 ◽  
Vol 105 (1) ◽  
pp. 77-91 ◽  
Author(s):  
Kevin Werts ◽  
Calvin G. Barnes ◽  
Valbone Memeti ◽  
Barbara Ratschbacher ◽  
Dustin Williams ◽  
...  

Abstract Bulk-rock compositions are commonly used as proxies for melt compositions, particularly in silicic plutonic systems. However, crystal accumulation and/or melt loss may play an important role in bulk-rock compositional variability (McCarthy and Hasty 1976; McCarthy and Groves 1979; Wiebe 1993; Wiebe et al. 2002; Collins et al. 2006; Deering and Bachmann 2010; Miller et al. 2011; Vernon and Collins 2011; Lee and Morton 2015; Lee et al. 2015; Barnes et al. 2016a; Schaen et al. 2018). Recognizing and quantifying the effects of crystal accumulation and melt loss in these silicic systems is challenging. Hornblende-melt Fe/Mg partitioning relationships and hornblende (Hbl) chemometry are used here to test for equilibrium with encompassing bulk-rock and/or glass compositions from several plutonic and volcanic systems. Furthermore, we assess the extent to which these tests can be appropriately applied to Hbl from plutonic systems by investigating whether Hbl from the long-lived (~10 Ma) Tuolumne Intrusive Complex preserves magmatic crystallization histories. On the basis of regular zoning patterns, co-variation of both fast- and slow-diffusing trace elements, Hbl thermometry, and compositional overlap with volcanic Hbl we conclude that Hbl from plutons largely preserve records supporting the preservation of a magmatic crystallization history, although many compositional analyses yield calculated temperatures <750 °C, which is unusual in volcanic Hbl. Hornblende is only rarely in equilibrium with host plutonic bulk-rock compositions over a wide range of SiO2 contents (42–78 wt%). Hornblende chemometry indicates that the majority of Hbl from the plutonic systems investigated here is in equilibrium with melts that are typically more silicic (dacitic to rhyolitic in composition) than bulk-rock compositions. These results are consistent with crystal accumulation and/or loss of silicic melts within middle- to upper-crustal plutons. Although the processes by which melts are removed from these plutonic systems is uncertain, it is evident that these melts are either redistributed in the crust (e.g., leucogranite dikes, plutonic roofs, etc.) or are instead erupted. In contrast, Hbl from volcanic rocks is more commonly in equilibrium with bulk-rock and glass compositions. In most cases, where Hbl is out of equilibrium with its host glass, the glasses are more evolved than the calculated melts indicating crystallization from a less fractionated melt and/or mixed crystal populations. Where Hbl is not in equilibrium with volcanic bulk-rocks, the bulk-rock compositions are typically more mafic than the calculated melts. In some intermediate volcanic samples, the occurrence of wide-ranges of calculated melt compositions is indicative of magma mixing. The general absence of Hbl with temperatures <750 °C from volcanic systems suggests that magmatic mushes below this temperature are unlikely to erupt. Our results indicate that bulk-rock compositions of granitic plutonic rocks only rarely approximate melt compositions and that the possibility of crystal accumulation and/or melt loss cannot be ignored. We suggest that detailed assessments of crystal accumulation and melt loss processes in magmatic systems are crucial to evaluating magma differentiation processes and discerning petrogenetic links between plutonic and volcanic systems.


2019 ◽  
Vol 60 (11) ◽  
pp. 2227-2240 ◽  
Author(s):  
Calvin G Barnes ◽  
Kevin Werts ◽  
Vali Memeti ◽  
Katie Ardill

Abstract Cumulate processes in granitic magma systems are thought by some to be negligible and by others to be common and widespread. Because most granitic rocks lack obvious evidence of accumulation, such as modal layering, other means of identifying cumulate rocks and estimating proportions of melt lost must be developed. The approach presented here utilizes major and trace element compositions of hornblende to estimate melt compositions necessary for zircon saturation. It then compares these estimates with bulk-rock compositions to estimate proportions of extracted melt. Data from three arc-related magmatic systems were used (English Peak pluton, Wooley Creek batholith, and Tuolumne Intrusive Complex). In all three systems, magmatic hornblende displays core-to-rim decreases in Zr, Hf, and Zr/Hf. This zoning indicates that zircon must have fractionated during crystallization of hornblende, at temperatures greater than 800 °C. This T estimate is in agreement with Ti-in-zircon thermometry, which yields a maximum T estimate of 855 °C. On the basis of this evidence, concentrations of Zr in melts from which hornblende and zircon crystallized were calculated by (1) applying saturation equations to bulk-rock compositions, (2) applying saturation equations to calculated melt compositions, and (3) using hornblende/melt partition coefficients for Zr. The results indicate that melt was lost during crystallization of the granitic magmas, conservatively at least as much as 40 %. These results are in agreement with published estimates of melt loss from other plutonic systems and suggest that bulk-rock compositions of many granitic rocks reflect crystal accumulation and are therefore inappropriate for use in thermodynamic calculations and in direct comparison of potentially consanguineous volcanic and plutonic suites.


2021 ◽  
pp. 1-26
Author(s):  
Taylor A. Ducharme ◽  
Christopher R.M. McFarlane ◽  
Deanne van Rooyen ◽  
David Corrigan

Abstract The Flowers River Igneous Suite of north-central Labrador comprises several discrete peralkaline granite ring intrusions and their coeval volcanic succession. The Flowers River Granite was emplaced into Mesoproterozoic-age anorthosite–mangerite–charnockite–granite (AMCG) -affinity rocks at the southernmost extent of the Nain Plutonic Suite coastal lineament batholith. New U–Pb zircon geochronology is presented to clarify the timing and relationships among the igneous associations exposed in the region. Fayalite-bearing AMCG granitoids in the region record ages of 1290 ± 3 Ma, whereas the Flowers River Granite yields an age of 1281 ± 3 Ma. Volcanism occurred in three discrete events, two of which coincided with emplacement of the AMCG and Flowers River suites, respectively. Shared geochemical affinities suggest that each generation of volcanic rocks was derived from its coeval intrusive suite. The third volcanic event occurred at 1271 ± 3 Ma, and its products bear a broad geochemical resemblance to the second phase of volcanism. The surrounding AMCG-affinity ferrodiorites and fayalite-bearing granitoids display moderately enriched major- and trace-element signatures relative to equivalent lithologies found elsewhere in the Nain Plutonic Suite. Trace-element compositions also support a relationship between the Flowers River Granite and its AMCG-affinity host rocks, most likely via delayed partial melting of residual parental material in the lower crust. Enrichment manifested only in the southernmost part of the Nain Plutonic Suite as a result of its relative proximity to multiple Palaeoproterozoic tectonic boundaries. Repeated exposure to subduction-derived metasomatic fluids created a persistent region of enrichment in the underlying lithospheric mantle that was tapped during later melt generation, producing multiple successive moderately to strongly enriched magmatic episodes.


2010 ◽  
Vol 74 (4) ◽  
pp. 645-658 ◽  
Author(s):  
F. C. J. Vilalva ◽  
S. R. F. Vlach

AbstractTurkestanite, a rare Th- and REE-bearing cyclosilicate in the ekanite–steacyite group was found in evolved peralkaline granitesfrom the Morro Redondo Complex, south Brazil. It occurswith quartz, alkali feldspar and an unnamed Y-bearing silicate. Electron microprobe analysis indicates relatively homogeneous compositions with maximum ThO2, Na2O and K2O contentsof 22.4%, 2.93% and 3.15 wt.%, respectively, and significant REE2O3 abundances(5.21 to 11.04 wt.%). The REE patterns show enrichment of LREE over HREE, a strong negative Eu anomaly and positive Ce anomaly, the latter in the most transformed crystals. Laser ablation inductively coupled plasma mass spectrometry trace element patterns display considerable depletions in Nb, Zr, Hf, Ti and Li relative to whole-rock sample compositions. Observed compositional variations suggest the influence of coupled substitution mechanisms involving steacyite, a Na-dominant analogue of turkestanite, iraqite, a REE-bearing end-member in the ekanite–steacyite group, ekanite and some theoretical end-members. Turkestanite crystals were interpreted as having precipitated during post-magmatic stages in the presence of residual HFSE-rich fluidscarrying Ca, the circulation of which wasenhanced by deformational events.


1991 ◽  
Vol 86 (10) ◽  
pp. 459-472 ◽  
Author(s):  
Keiichi Shiraki ◽  
Kenji Nagao ◽  
Takashi Nagao ◽  
Susumu Kakubuchi ◽  
Yukio Matsumoto
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