Infrared spectra of N-acetyl-L-α-amino-acid N'-methylamides with aliphatic side chains in non-polar solvents
1981 ◽
Vol 46
(3)
◽
pp. 772-780
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Keyword(s):
Infrared spectra of the L-alanine (I), L-leucine (II), L-valine (III) and L-tert-leucine (IV) N-acetyl N'-methylamides were measured. Amides I-IV are not self associated in tetrachlormethane in the concentration 2 . 10-5 mol l-1 at room temperature and in tetrachloroethylene in the concentration 1.5 . 10-4 mol l-1 at temperatures above 65° C. True conformational changes are observable only with the least flexible amide IV which exists at room temperature in a C5 conformation. This conformational type is also highly populated in the valine derivative III, but is less important in the alanine and leucine derivatives I and II in which the intramolecularly bonded C7 and the distorted hydrogen-nonbonded conformations contribute seriously.
2019 ◽
1979 ◽
Vol 34
(11)
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pp. 1269-1274
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Keyword(s):
2015 ◽
Vol 17
(32)
◽
pp. 20687-20698
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1965 ◽
Vol 32
(2)
◽
pp. 193-201
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Keyword(s):