Comparison of diagenetic fluids in the Proterozoic Thelon and Athabasca Basins, Canada: implications for protracted fluid histories in stable intracratonic basins

2002 ◽  
Vol 39 (1) ◽  
pp. 113-132 ◽  
Author(s):  
C Renac ◽  
T K Kyser ◽  
K Durocher ◽  
G Dreaver ◽  
T O'Connor
Keyword(s):  
Early Diagenesis ◽  
Uranium Deposits ◽  
Rock Interaction ◽  
Athabasca Basin ◽  
Fine Grained ◽  
Thelon Basin ◽  
Intracratonic Basins ◽  
World Class ◽  
Diagenetic Fluids ◽  
Quartz Grains

The Paleoproterozoic Thelon Basin, located on the border between Nunavut and the Northwest Territories of Canada, is a contemporaneous analog of the uranium-rich Paleoproterozoic Athabasca Basin in Canada. Early diagenesis resulted in precipitation of extensive hematite on the surfaces of detrital quartz grains throughout the Thelon Formation and minor hydroxy-phosphate in veins locally. Continued diagenesis then resulted in syntaxial quartz cementation of detrital quartz at 130°C from fluids having ca. 17 wt.% equivalent NaCl, similar to the Athabasca Basin. Cementation of this type is most pronounced in fine-grained sequences in the Thelon Basin. A period of extensive desilicification during continued burial was followed by formation, at ca. 200°C, of peak-diagenetic illite having Ar–Ar ages of ca. 1400–1690 Ma in the Thelon Formation. This illite was associated with fluids with δ18O and δD values of ca. 6‰ and –50‰, respectively, similar to those during peak diagenesis of the Athabasca Basin. Although the timing, salinity, and isotopic composition of the peak-diagenetic fluids in the Thelon and Athabasca Basins are similar, the peak-diagenetic mineral assemblage in the Athabasca Formation is dickite and illite, with minor dravite and goyasite rather than simply illite. Consequently, the fluids at peak diagenesis, which in the Athabasca Basin are synchronous with formation of world-class unconformity-type uranium deposits, had different compositions in each basin. Post-peak diagenesis in the Thelon Basin was quite distinct from that in the Athabasca Basin in that illite was replaced in the central portion of the basin by K-feldspar and then sudoite, which crystallized from saline brines at ca. 1000 Ma and 100°C. Evidence for later infiltration of these brines is absent in the Athabasca Basin, although uranium mobilization at ca. 900 Ma from fluids having the same characteristics as those at peak diagenesis was pronounced in the Athabasca Basin. Recent incursion of meteoric waters along reactivated structures into the Athabasca Basin has variably affected hydrous and uraniferous minerals, but evidence for this is lacking in the Thelon Basin. The Thelon Basin reflects less intensive fluid–rock interaction in its early history than that recorded in the basal units of the Athabasca Basin.

Sources of sulphur for the Proterozoic Kiggavik uranium deposit, Nunavut, Canada

2020 ◽  
Vol 57 (11) ◽  
pp. 1312-1323
Author(s):  
Brandi M. Shabaga ◽  
Mostafa Fayek ◽  
David Quirt ◽  
Patrick Ledru
Keyword(s):  
Low Temperature ◽  
Secondary Ion Mass Spectrometry ◽  
Uranium Mineralization ◽  
Uranium Deposits ◽  
Athabasca Basin ◽  
Thelon Basin ◽  
Mass Independent Fractionation ◽  
Hydrothermal Processes ◽  
Wide Range ◽  
Secondary Ion

The Thelon Basin is temporally and spatially related to the Athabasca Basin in Saskatchewan, Canada, which hosts the highest-grade unconformity-related uranium deposits in the world. Several uranium deposits occur within the Aberdeen sub-basin of the Thelon Basin, and it has been suggested that they may also be unconformity-related deposits. However, the genesis of the deposits is still debated and the age of the uranium mineralization event remains loosely constrained. In this study, we use secondary ion mass spectrometry to measure three sulphur (S) isotopes in pyrite from the Kiggavik deposit to constrain the sources of sulphur. We use this information to determine whether these sulphides, if dated by the Re–Os method, would provide a better constraint on the timing of uranium mineralization. The Kiggavik deposit comprises three zones (Main, Centre, and East) that formed from ∼200 °C fluids at ∼1600 Ma. Non-hydrothermal pyrite and galena from all three zones have a wide range of δ34S values, from −41.2‰ to +37.4‰. The Δ33S values (>0‰) indicate recycling of mass independent fractionation sulphur, suggesting that pyrite from the Kiggavik deposit derived sulphur from the Neoarchean metagraywacke host rock. The preservation of these anomalous Δ33S values suggests that the pyrite formed from low-temperature processes rather than hydrothermal processes. Low-temperature, high-latitude fluids may have been involved in the formation of the pyrite because some of these sulphides are also associated with uranium minerals that are devoid of Pb and contain corroded calcite. Based on these data, Re–Os geochronology of these sulphides would not yield an age that would constrain the timing of hydrothermal uranium mineralization.

Thermotectonic events recorded by U-Pb geochronology and Zr-in-rutile thermometry of Ti oxides in basement rocks along the P2 fault, eastern Athabasca Basin, Saskatchewan, Canada

2021 ◽  
Author(s):  
E. Adlakha ◽  
K. Hattori
Keyword(s):  
Regional Metamorphism ◽  
Hydrothermal Activity ◽  
Uranium Mineralization ◽  
Uranium Deposits ◽  
Athabasca Basin ◽  
The North ◽  
Basement Rocks ◽  
Major Fault ◽  
World Class ◽  
Basement Structures

Basement rocks below the Athabasca Basin, Saskatchewan, have been intensely altered through paleoweathering and multiple hydrothermal events, including the formation of world-class unconformity-type uranium deposits. Here, we demonstrate the utility of Ti-oxide thermochronology for identifying thermotectonic events in these altered rocks leading to uranium mineralization along basement structures. Rutile grains along the P2 fault, a major fault in the eastern Athabasca Basin, exhibit 207Pb/206Pb ages of ca. 1850−1700 Ma, with a weighted mean of 1757 ± 6 Ma (mean square of weighted deviation [MSWD] = 1.4, n = 116). The older ages (>1770 Ma) record regional metamorphism reaching a temperature of 875 °C during the Trans-Hudson orogeny. Pb diffusion modeling indicates that metamorphic rutile should exhibit cooling ages of 1760−1750 Ma. Rutile grains showing young ages, <1750 Ma, reflect isotopic resetting during regional asthenospheric upwelling between 1770 and 1730 Ma related to the emplacement of the Kivalliq igneous suite to the north. This thermotectonic event (temperature > 550 °C) promoted hydrothermal activity to produce silicified rocks, i.e., “quartzite,” along the P2 fault, which later focused mineralizing fluids for unconformity-type uranium deposits. The young rutile ages also indicate that the basement rocks remained hot until 1700 Ma, providing the maximum age for the deposition of the Athabasca sediments. Anatase yields a concordia age of 1569 ± 31 Ma (MSWD = 0.30, n = 5), which is within uncertainty of the oldest ages for uraninite of the McArthur River deposit. This age corresponds to the incursion of basinal fluids in the basement along the P2 fault during uranium mineralization.

Diagenetic fluorapatite and aluminum phosphate–sulphate in the Paleoproterozoic Thelon Formation and Hornby Bay Group, northwestern Canadian Shield

2006 ◽  
Vol 43 (5) ◽  
pp. 617-629 ◽  
Author(s):  
Q Gall ◽  
J A Donaldson
Keyword(s):  
Earth Element ◽  
Aluminum Phosphate ◽  
Canadian Shield ◽  
Northwestern Part ◽  
Athabasca Basin ◽  
Thelon Basin ◽  
Hydrated Aluminum ◽  
Element Bearing ◽  
Diagenetic Fluids ◽  
Lines Of Evidence

In the northwestern part of the Canadian Shield, fluorapatite and a rare-earth element-bearing hydrated aluminum phosphate–sulphate mineral (APS) occur as cements in continental successions near the base of the Paleoproterozoic Thelon Formation (Thelon Basin) and Hornby Bay Group (Hornby Bay Basin). These minerals occupy interstitial sites, form euhedral crystals, display micro-scale zonation, make up part of an unmetamorphosed paragenetic assemblage, and are distributed in correlative units across thousands of square kilometres, suggesting a diagenetic origin. Stratigraphy, geochronology, and other lines of evidence suggest that the Thelon Formation and Hornby Bay Group containing these phosphatic cements, as well as the Ellice Formation and Athabasca Group, are correlative and may have been originally interconnected. The evidence suggests that the basal Thelon Formation and the Hornby Bay Group underwent similar, and approximately coeval, diagenetic mineral paragenesis. Furthermore, the diagenetic fluids in these different locations must have been remarkably similar, especially those that produced the delicate APS mineral. Compared to phosphatic cements in the Hornby Bay and Thelon basins, unmineralized sandstone in the Athabasca Basin contains "crandallite group" and fluorapatite cements higher in the basin fill sequence (Wolverine Point Formation) in tuffaceous sandstone and as relatively early cement in the paragenetic sequence.

Chemical brecciation processes in the Sue unconformity-type uranium deposits, Eastern Athabasca Basin (Canada)

2003 ◽  
Vol 80 (2-3) ◽  
pp. 241-258 ◽  
Author(s):  
G Lorilleux ◽  
M Cuney ◽  
M Jébrak ◽  
J.C Rippert ◽  
P Portella
Keyword(s):  
Uranium Deposits ◽  
Athabasca Basin

scholarly journals Paragenetic and petrographic study of uranium mineralization along the Midwest Trend, Northeastern Athabasca Basin

2020 ◽  
Vol 6 (1) ◽  
Author(s):  
Daniel Peter Ferguson ◽  
Guoxiang Chi ◽  
Charles Normand ◽  
Patrick Ledru ◽  
Odile Maufrais-Smith
Keyword(s):  
Mineral Resource ◽  
Genetic Model ◽  
Uranium Deposit ◽  
Current Model ◽  
Uranium Mineralization ◽  
Mining District ◽  
Uranium Deposits ◽  
Athabasca Basin ◽  
Technical Report ◽  
Petrographic Study

The Athabasca Basin in northern Saskatchewan is host to many world-class uranium deposits associated with the unconformity between the Paleoproterozoic sandstone of the basin and the underlying crystalline basement (Jefferson et al., 2007).  While the style and tonnage of these deposits vary, the current genetic model for unconformity-related uranium deposits has been a practical tool for exploration in the Athabasca Basin. However, the factors which control the location and formation of these deposits is still not fully understood. A paragenetic and petrographic study of mineralization along the Midwest Trend, located on the northeastern margin of the Athabasca Basin, aims to refine the current model and to address the general problem: What are the factors which control mineralization and non-mineralization? The Midwest Trend will be used as a "modèle réduit" for uranium mineralization, as it displays many features characteristic of unconformity type deposits. The Midwest Trend comprises three mineral leases that encompass two uranium deposits, the Midwest Main and Midwest A (Allen et al., 2017a, b). Mineralization occurs along a NE-trending graphitic structure, and is hosted by the sandstone, at the unconformity, and in much lesser amounts in the underlying basement rocks. Petrographic observations aided by the use of RAMAN spectroscopy and SEM-EDS, have been used to create a paragenetic sequence of mineralization (Fig.1). Future work will focus on fluid inclusion studies using microthermometry, LA-ICP-MS, and mass spectrometry of contained gases. References:Allen, T., Quirt, D., Masset, O. (2017a). Midwest A Uranium Deposit, Midwest Property, Northern Mining District, Saskatchewan, NTS Map Area 741/8: 2017 Mineral Resource Technical Report. AREVA Resources Canada Inc. Internal Report No. 17-CND-33-01. Allen, T., Quirt, D., Masset, O. (2017b). Midwest Main Uranium Deposit, Midwest Property, Northern Mining District, Saskatchewan, NTS Map Area 741/8: 2017 Mineral Resource Technical Report. AREVA Resources Canada Inc. Internal Report No. 17-CND-33-01. Jefferson, C.W., Thomas, D.J., Gandhi, S.S., Ramaekers, P., Delaney, G., Brisbin, D., Cutts, C., Portella, P., and Olson, R.A., 2007: Unconformity-associated uranium deposits of the Athabasca Basin, Saskatchewan and Alberta. Geological Survey of Canada, Bulletin 588, p. 23–67.

scholarly journals Denudation systematics inferred from in situ cosmogenic <sup>10</sup>Be concentrations in fine (50–100 µm) and medium (100–250 µm) sediments of the Var River basin, southern French Alps

2019 ◽  
Vol 7 (4) ◽  
pp. 1059-1074 ◽  
Author(s):  
Apolline Mariotti ◽  
Pierre-Henri Blard ◽  
Julien Charreau ◽  
Carole Petit ◽  
Stéphane Molliex ◽  
...  
Keyword(s):  
Glacial Cycles ◽  
Size Fractions ◽  
French Alps ◽  
Fine Grained ◽  
Denudation Rates ◽  
Variable Morphology ◽  
Cosmogenic 10Be ◽  
The Impact ◽  
Quartz Grains

Abstract. Marine sedimentary archives are well dated and often span several glacial cycles; cosmogenic 10Be concentrations in their detrital quartz grains could thus offer the opportunity to reconstruct a wealth of past denudation rates. However, these archives often comprise sediments much finer (<250 µm) than typically analyzed in 10Be studies, and few studies have measured 10Be concentrations in quartz grains smaller than 100 µm or assessed the impacts of mixing, grain size, and interannual variability on the 10Be concentrations of such fine-grained sediments. Here, we analyzed the in situ cosmogenic 10Be concentrations of quartz grains in the 50–100 and 100–250 µm size fractions of sediments from the Var basin (southern French Alps) to test the reliability of denudation rates derived from 10Be analyses of fine sands. The Var basin has a short transfer zone and highly variable morphology, climate, and geology, and we test the impact of these parameters on the observed 10Be concentrations. Both analyzed size fractions returned similar 10Be concentrations in downstream locations, notably at the Var's outlet, where concentrations ranged from (4.02±0.78)×104 to (4.40±0.64)×104 atoms g−1 of quartz. By comparing expected and observed 10Be concentrations at three major river junctions, we interpret that sediment mixing is efficient throughout the Var basin. We resampled four key locations 1 year later, and despite variable climatic parameters during that period, interannual 10Be concentrations were in agreement within uncertainties, except for one upper subbasin. The 10Be-derived denudation rates of Var subbasins range from 0.10±0.01 to 0.57±0.09 mm yr−1, and spatial variations are primarily controlled by the average subbasin slope. The integrated denudation rate of the entire Var basin is 0.24±0.04 mm yr−1, in agreement with other methods. Our results demonstrate that fine-grained sediments (50–250 µm) may return accurate denudation rates and are thus potentially suitable targets for future 10Be applications, such as studies of paleo-denudation rates using offshore sediments.

Petrology and geochronology of Paleoproterozoic intrusive rocks, Kiggavik uranium camp, Nunavut

2015 ◽  
Vol 52 (7) ◽  
pp. 495-518 ◽  
Author(s):  
J.M.J. Scott ◽  
T.D. Peterson ◽  
W.J. Davis ◽  
C.W. Jefferson ◽  
B.L. Cousens
Keyword(s):  
Granitic Rocks ◽  
Uranium Deposits ◽  
Zircon Age ◽  
Core Samples ◽  
Thelon Basin ◽  
Intrusive Rocks ◽  
Uranium Exploration ◽  
Melt Infiltration ◽  
Granitic Intrusions ◽  
Baker Lake

We investigated the age and petrology of Paleoproterozoic granitic intrusions in the area of the Kiggavik uranium exploration camp, near the southeast margin of the Aberdeen subbasin of the Thelon Basin. A subset of these intrusions (e.g., the Lone Gull stock) is spatially associated with and mineralized by basement hosted, unconformity-related uranium deposits. Surface (outcrop) samples have field relations, textures, and compositions consistent with Hudson Suite granitoids and mixtures of monzogranite with minette. We obtained U–Pb (zircon) ages ranging from ca. 1818 to 1840 Ma, within the known range of the Hudson Suite and cogenetic minettes of the Baker Lake Group (1.80–1.84 Ga). Core samples of granitic rocks adjacent to mineralized zones are more complex and indicate an influence from the younger Nueltin Granite (Kivalliq Igneous Suite, ca. 1.77–1.73 Ga). One sample from the Lone Gull stock contains two zircon populations in texturally distinctive domains, one at 1806 ± 41 Ma and the other at 1748 ± 9.4 Ma. A porphyritic hypabyssal syenite below the Bong deposit yielded a U–Pb zircon age of 1837.8 ± 7.7 Ma and a U–Pb titanite age of 1758.5 ± 44 Ma. We recognize a Kivalliq-age overprint in the form of metasomatism and partial remelting or melt infiltration in the drill core samples, which is not evident at the surface and is consistent with the presence of a Nueltin Granite intrusive complex at depth. The geochemistry and primary igneous textures of the Bong syenite, including its euhedral zircons, resemble those of lava flows near the base of the Baker Lake Group, and we recognize a mixed magma (i.e., Martell Syenite) continuum between intrusive Hudson granitoids and minette with extrusive equivalents in the lower felsic minette member of the Christopher Island Formation.

Geological environment of the Cigar Lake uranium deposit

1993 ◽  
Vol 30 (4) ◽  
pp. 653-673 ◽  
Author(s):  
P. Bruneton
Keyword(s):  
Uranium Deposit ◽  
Transitional Zone ◽  
Uranium Deposits ◽  
Athabasca Basin ◽  
Structural Framework ◽  
Basement Rocks ◽  
Metamorphic Basement ◽  
Basement Ridge ◽  
Archean Basement ◽  
East West

The Cigar Lake uranium deposit occurs within the Athabasca Basin of northern Saskatchewan, Canada. Like other major uranium deposits of the basin, it is located at the unconformity separating Helikian sandstones of the Athabasca Group from Aphebian metasediments and plutonic rocks of the Wollaston Group. The Athabasca Group was deposited in an intra-continental sedimentary basin that was filled by fluviatile terrestrial quartz sandstones and conglomerates. The group appears undeformed and its actual maximum thickness is about 1500 m. On the eastern side of the basin, the detrital units correspond to the Manitou Falls Formations where most of the uranium deposits are located. The Lower Pelitic unit of the Wollaston Group, which lies directly on the Archean basement, is considered to be the most favourable horizon for uranium mineralization. During the Hudsonian orogeny (1800–1900 Ma), the group underwent polyphase deformation and upper amphibolite facies metamorphism. The Hudsonian orogeny was followed by a long period of erosion and weathering and the development of a paleoweathering profile.On the Waterbury Lake property, the Manitou Falls Formation is 250–500 m thick and corresponds to units MFd, MFc, and MFb. The conglomeratic MFb unit hosts the Cigar Lake deposit. However, the basal conglomerate is absent at the deposit, wedging out against an east–west, 20 m high, pre-Athabasca basement ridge, on top of which is located the orebody.Two major lithostructural domains are present in the metamorphic basement of the property: (1) a southern area composed mainly of pelitic metasediments (Wollaston Domain) and (2) a northern area with large lensoid granitic domes (Mudjatik Domain). The Cigar Lake east–west pelitic basin, which contains the deposit, is located in the transitional zone between the two domains. The metamorphic basement rocks in the basin consist mainly of graphitic metapelitic gneisses and calcsilicate gneisses, which are inferred to be part of the Lower Pelitic unit. Graphite- and pyrite-rich "augen gneisses," an unusual facies within the graphitic metapelitic gneisses, occur primarily below the Cigar Lake orebody.The mineralogy and geochemistry of the graphitic metapelitic gneisses suggest that they were originally shales. The abundance of magnesium in the intercalated carbonates layers indicates an evaporitic origin.The structural framework is dominated by large northeast–southwest lineaments and wide east–west mylonitic corridors. These mylonites, which contain the augen gneisses, are considered to be the most favourable features for the concentration of uranium mineralization.Despite the presence of the orebody, large areas of the Waterbury Lake property remain totally unexplored and open for new discoveries.

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