RECOGNITION OF A 600-KM-LONG LATE TRIASSIC RARE METAL (Li-Rb-Be-Nb-Ta) PEGMATITE BELT IN THE WESTERN KUNLUN OROGENIC BELT, WESTERN CHINA

The rising demand of strategic metals, especially lithium, necessitates discovery of new resources to meet the global supply chain. Recently, several pegmatite-hosted rare metal (Li-Rb-Be-Nb-Ta) deposits have been discovered in the Western Kunlun orogenic belt, making it a new world-class rare metal resource (estimated ~7 Mt Li2O and 0.16 Mt BeO). Understanding the metallogenesis of this belt is critical to further evaluate the rare metal potential. In this study, columbite-tantalite (coltan) and monazite from rare metal pegmatites and zircon from potential parental granites were collected from five representative rare metal pegmatite deposits in the western, middle, and eastern parts of the Western Kunlun orogenic belt for U-Pb geochronology. The results indicate that despite the distances of the sampling localities in different parts of the Western Kunlun orogenic belt, the ages of pegmatite-hosted rare metal mineralization fall in a narrow range of ca. 208–204 Ma. These rare metal pegmatites are temporally and spatially related to adjacent postorogenic granites emplaced following the closure of the Paleo-Tethys Ocean. The compositional characteristics of K-feldspar, biotite, and muscovite of the granites and pegmatites, along with regional mineralogical and textural zonation of the pegmatites, suggest that the rare metal pegmatites were derived from the volumetrically much more important, highly fractionated granitic intrusions. We propose that, in combination with the data from previous studies, the 218–204 Ma interval represents a newly recognized rare metal metallogenic period linked with granitic intrusions in the Western Kunlun orogenic belt, revealing a 600-km-long late Triassic rare metal pegmatite belt composed of multiple ore fields formed in a similar metallogenic setting. These results emphasize the importance of identifying fertile, Late Triassic to Early Jurassic granitic intrusions for rare metal pegmatite exploration. Furthermore, combined with recent studies on the Songpan-Ganzi rare metal pegmatite belt along the eastern segment of the Paleo-Tethys, this study further highlights the great potential of rare metal resources in this global tectonic zone.

The Formation of Magmatic-Hydrothermal Features in Sn-Mineralized and Barren Tasmanian Intrusions, Southeast Australia: Insights from Quartz Textures, Trace Elements, and Microthermometry

Tasmania is the most important tin province in Australia, having been endowed with >0.65 Mt Sn. Some granitic intrusions in western Tasmania have distinctive tourmaline- and quartz-rich magmatic-hydrothermal features, whether they are mineralized (e.g., Heemskirk Granite) or barren (Pieman Heads Granite). The Devonian Heemskirk and Pieman Heads plutons crop out on the western coast of Tasmania and are characterized by similar mineralogical and geochemical compositions and ages. The magmatic-hydrothermal textural features include tourmaline patches, tourmaline orbicules, and tourmaline-muscovite veins, as well as miarolitic cavities and quartz-fluorite-sulfide veins in the Heemskirk Granite. Cathodoluminescence (CL) imaging, laser ablation-inductively coupled plasma-mass spectrometry, and microthermometric analyses of quartz have revealed the physicochemical evolution of the magmatic-hydrothermal fluids from which these tourmaline- and quartz-bearing assemblages precipitated. High Ti quartz (20–28 ppm) in tourmaline patches, orbicules, and cavities typically have homogeneous CL-bright intensity, whereas CL-dark fractures have cut and/or offset the CL-bright and -gray domains that characterize low Ti quartz (3.4–8.5 ppm) from the tourmaline veins. The earliest fluid inclusion assemblages in the quartz-tourmaline orbicules and cavities have a salinity range from 3 to 14 wt % NaCl equiv with intermediate density and were probably trapped at lithostatic pressures of 1.57 ± 0.2 kbar and temperatures of 550° to 570°C, suggesting a depth of 5.9 ± 0.8 km. Prolonged depressurization and cooling may have led to the evolution of a brine (~39 wt % NaCl equiv salinity) from the primary magmatic liquid, which formed halite-bearing hypersaline inclusions in the tourmaline orbicules. Continuous pressure decrease explains the intense brittle failure and fluid migration outward from the apical portions of the pluton, where magmatic fluids partially mixed with and were cooled by external meteoric water. These mechanisms triggered the formation of tourmaline-muscovite-quartz veins and local cassiterite-bearing greisens from a moderate-salinity fluid (~12 wt % NaCl equiv) at temperatures of ~300°C and hydrostatic pressures of 120 bars. Retrograde dissolution textures evident from CL-bright quartz cores surrounded by oscillatory growth zones with gray CL response characterize the low Ti (<1 ppm) and high Al (500–1,000 ppm) quartz from the fluorite-sulfide veins that precipitated from a low-salinity (5.7 wt % NaCl equiv) acidic fluid at temperatures of 200° ± 25°C and hydrostatic pressures of <50 bars. High Sb concentrations (up to 80 ppm) in quartz may be an indicator of low-temperature base metal mineralization related to granitic intrusions. Abundant fluid percolation, protracted fractional crystallization, and high tin concentrations in exsolved hydrothermal fluids may explain why the Heemskirk Granite is well endowed in Sn and base metal deposits, whereas the Pieman Heads Granite is barren.

Zircon U–Pb Ages and Geochemistry of Granitoid in the Yuejinshan Copper–Gold Deposit, NE China: Constraints on Petrogenesis and Metallogenesis

Yuejinshan copper–gold orebodies form a hydrothermal deposit located southwest of the Wandashan massif in the western Pacific oceanic tectonic regime. The orebodies are veins and lenses in granite porphyry and skarn or contact zones between these rocks. Early Cretaceous Yuejinshan magmatism provides critical evidence for regional mineralization and tectonic history. In this work, whole-rock major and trace elements and zircon U–Pb data for Yuejinshan granitic intrusions were studied to investigate the geochronological framework, petrogenesis, tectonic implications, and metallogenesis. Granodiorites are calc-alkaline and have geochemical characteristics that indicate affinities with subduction-related crust–mantle magmas derived from partial melting of a mantle wedge and subducted sediments metasomatized by subduction-related fluids. These magmas have experienced fractional crystallization and assimilated crustal materials. Granite porphyries, monzogranites, and quartz diorites are peraluminous, geochemically similar to remelted granites, and derived from partial melting of the crust. Zircon U–Pb LA-ICP-MS data and previous ages indicate that the granitoids were emplaced in the Early Cretaceous. We propose that mineralization mainly occurred at 130 Ma, while magmatism during 116–109 Ma triggered the enrichment of copper and gold in this deposit. Magmatism of different geological ages overlapped spatially and formed the Yuejinshan copper–gold deposit in an active continental margin setting related to the subduction of the Paleo-Pacific Plate.

Petrology and volcanology of the Mesoproterozoic igneous rocks of the Saint Francois Mountains terrane, southeast Missouri, USA

ABSTRACT The Saint Francois Mountains are the physiographic expression of the central part of the Ozark Dome of southeastern Missouri. The mountains are made up of a quaquaversal-dipping series of Paleozoic units cored by the Mesoproterozoic-aged rocks of the broader Saint Francois Mountains terrane. The Saint Francois Mountains terrane lies within the Eastern Granite-Rhyolite province along the eastern margin of Laurentia and contains at least four mapped caldera complexes (Eminence, Lake Killarney, Butler Hill, and Taum Sauk), associated volcanic and volcaniclastic rocks, and four distinct types of intrusive units. The Mesoproterozoic rocks represent two major pulses of magmatic activity: (1) an older 1.48–1.45 Ga episode of caldera-forming volcanism and associated subvolcanic to massif-type granitic intrusions; and (2) a younger 1.33–1.28 Ga episode of bimodal intrusions. Volcanism included primarily high-silica rhyolite and volcaniclastic sediments associated with caldera-forming volcanism with lesser amounts of basalt and basaltic andesite that formed as flows and subvolcanic intrusions. The older (ca. 1.4 Ga) intrusive rocks can be divided into three broad categories: (1) granite massifs including the Butler Hill/Breadtray massif-type granites, (2) caldera ring–type granites such as the Silvermine Granite, and (4) mafic- to intermediate-composition intrusive rocks such as the Silver Mines Mafic Series. The younger (ca. 1.3 Ga) bimodal intrusions are represented by the highly evolved felsic Graniteville-types granites and the gabbros of the Skrainka Mafic Group. This field guide provides an overview of the magmatic history of the Mesoproterozoic rocks exposed in the eastern Saint Francois Mountains. Field-trip stops are divided into two days, highlighting well-known stops and lesser-known localities that illustrate the magmatic activity of one the premier igneous locations in the midcontinent region. The field trip is focused on two main areas. Day 1 focuses on the rhyolite sequence and associated caldera-forming eruption of the Taum Sauk caldera. Day 2 focuses on the volcanic rocks and granitic intrusions related to the Butler Hill caldera and ends with a visit to one of the youngest granitoids in the terrane, the Graniteville Granite. The field guide presents a summary of the volcanic history and petrogenesis of the Saint Francois Mountains rhyolites and granites.

Geophysical reassessment of the role of ancient lineaments on the development of the western Laurentian margin and its sediment-hosted Zn-Pb deposits, Yukon and NWT, Canada

A new 3-D inversion strategy is applied to new compilations of gravity and magnetic data, to reassess the role of crustal lineaments in the development of the western Laurentian margin, Selwyn basin and associated sediment-hosted Zn-Pb deposits. The region’s history is obscured by multiple tectonic overprints including terrane accretion, plutonism, and thrust faulting. Regionally continuous, broadly NE-trending crustal lineaments including the Liard line, Fort Norman structure, and Leith Ridge fault, were interpreted as having had long-standing influence on craton, margin, and sedimentary basin development. An ENE-trending lineament, Mackenzie River, traced from the Misty Creek Embayment to Great Bear Lake, is interpreted as the southern edge of a cratonic promontory. The location of the Liard line, associated with a transfer fault that bounds the Macdonald Platform promontory, is refined. New geophysical results support the continuity of the Fort Norman structure below the Selwyn basin, but limited evidence exists for the Leith Ridge fault in this area. A NW-trending lineament that bounds the craton is interpreted as a crustal manifestation of lithospheric thinning of the Laurentian margin, as echoed by a change in the depth of the lithosphere-asthenosphere boundary. The structure delimits the eastern extent of mid-Late Cretaceous granitic intrusions and is straddled by Mississippi Valley-type Zn-Pb occurrences, following their palinspastic restoration. Clastic-dominated Zn-Pb occurrences are aligned along another NW-trending lineament interpreted to be associated with a shallowing of lower crustal rocks.

Preservation of late Palaeozoic glacial rock surfaces by burial prior to Cenozoic exhumation, Fleurieu Peninsula, southeastern Australia

The antiquity of the Australian landscape has long been the subject of debate, with some studies inferring extraordinary longevity (>108 Myr) for some subaerial landforms dating back to the early Palaeozoic. A number of early Permian glacial erosion surfaces in the Fleurieu Peninsula, southeastern Australia, provide an opportunity to test the notion of long-term subaerial emergence, and thus tectonic and geomorphic stability, of parts of the Australian continent. Here we present results of apatite fission-track analysis (AFTA) applied to a suite of samples collected from localities where glacial erosion features of early Permian age are developed. Our synthesis of AFTA results with geological data reveals four cooling episodes (C1-4), which are interpreted to represent distinct stages of exhumation. These episodes occurred during the Ediacaran to Ordovician (C1), mid-Carboniferous (C2), Permian to mid-Triassic (C3) and Eocene to Oligocene (C4).The interpretation of AFTA results indicates that the Neoproterozoic-Lower Palaeozoic metasedimentary rocks and granitic intrusions upon which the glacial rock surfaces generally occur were exhumed to the surface by the latest Carboniferous-earliest Permian during episodes C2 and/or C3, possibly as a far-field response to the intraplate Alice Springs Orogeny. The resulting landscapes were sculpted by glacial erosive processes. Our interpretation of AFTA results suggests that the erosion surfaces and overlying Permian sedimentary rocks were subsequently heated to between ∼60 and 80°C, which we interpret as recording burial by a sedimentary cover comprising Permian and younger strata, roughly 1 kilometre in thickness. This interpretation is consistent with existing thermochronological datasets from this region, and also with palynological and geochronological datasets from sediments in offshore Mesozoic-Cenozoic-age basins along the southern Australian margin that indicate substantial recycling of Permian-Cretaceous sediments. We propose that the exhumation which led to the contemporary exposure of the glacial erosion features began during the Eocene to Oligocene (episode C4), during the initial stages of intraplate deformation that has shaped the Mt Lofty and Flinders Ranges in South Australia. Our findings are consistent with several recent studies, which suggest that burial and exhumation has played a key role in the preservation and contemporary re-exposure of Gondwanan geomorphic features in the Australian landscape.

Radiogenic heat production in granitoids from the Sierras de Córdoba, Argentina

One of the most important processes of heat generation from the Earth's interior is the radioactive decay of isotopes. The main hosts of the major radiogenic elements U, Th and K in the crust are granitoids. The Sierras de Córdoba are formed of dissimilar granitic intrusions emplaced by a series of magmatic events that occurred during the Paleozoic. The different granitoids are classified as A-type, I-type, and S-type, and there is also a magmatic expression corresponding to the Famatinian period which exhibits TTG-type characteristics. In this work, the geochemical concentrations of the radiogenic elements of the granitic intrusions making up the Sierras de Córdoba were compiled in a single database. The radiogenic heat production of the Sierras de Córdoba granitoids was evaluated, making this the first study of radiogenic heat generation in the area. The radiogenic heat production showed variability for the different events, with the highest values found in Achalian magmatism and early Carboniferous magmatism, which are represented by A-type granitoids. The Capilla del Monte pluton has the highest heat production rate, with a value of 4.54 ± 1.38 µW/m3. The lowest values were found in the TTG-type granitoids and in the S-type granitoids, all of which belong to the Famatinian magmatic event. The range of values for this magmatic event goes from 0.26 ± 0.05 µW/m3 for the San Agustin pluton to 1.19 ± 0.50 µW/m3 for the La Playa pluton. An empirical ternary model is presented for the Sierras de Córdoba that involves the concentrations of the elements U, Th and K, and the radiogenic heat production, with a distinction for the petrogenetic types according to the S-I-A-M classification. The thermal manifestations located on the Capilla del Monte pluton could be related to the radioactive heat generation of the intrusion, involving both the neotectonic activity of the area and the radiogenic heat production. The results provide new opportunities for studying temperature variation within some of these intrusions and to evaluate the geothermal potential of the granitoids of Córdoba.

Palaeogene plutonic magmatism in Central Afghanistan, and its relation to the India-Eurasia collision

Numerous granitic intrusions occur along the southern margin of the Tajik Block and the Band-e-Bayan Zone in the Ghor Province of Central Afghanistan. Previously, they used to be linked to the Cimmerian igneous episodes of Triassic and Cretaceous ages. However, the new U-Pb dating has revealed that these granite intrusions occurred during the Eocene within a narrow time span of 41–36 Ma. They are related to the number of local depressions filled with the volcanic-sedimentary sequence of the same age. These data indicate an intense short-termed magmatic event that affected the region in the Palaeogene. The magmatism might be related to the India-Eurasia collision, which started approximately at the same time. It is likely to have induced the horizontal displacement of crustal blocks westwards along the Hari Rod fault.

Geochemical characteristics of Precambrian Basement rocks from southeastern Nigeria: an approach to their petrogenesis and tectonic setting.

Trace and Rare-Earth element geochemical study of twenty samples of migmatitic banded gneisses, garnet biotite schists, dolerites, granites and rhyolites was carried out in a bid to determine their petrogenetic and tectonic significance in the evolution of the southeastern Basement complex of Nigeria. The data shows that partial melting (crustal anatexis) of migmatitic gneisses and schists played a significant role in the evolution of the granitic intrusions. This is supported by the high incompatible (Rb/Sr = 0.16 to 1.31 and Ba/Sr = 0.75 to 6.21) elements ratio in the granitic intrusions than that of the migmatitic gneisses and schists (Rb/Sr, 0.051 to 0.824; Ba/Sr, 0.7 to 5). High ratios of Ba/Sr and Rb/Sr and lesser values of Ba/Rb ratios in some granitic intrusions than in others suggests increasing fractionation during the anatexis. The role of partial melting is also evident in the smooth REE patterns shown by most of these rocks and the negative Eu anomaly as indicated by the values of Eu/Eu* (0.097 to 0.7). LREE enrichment is evident in the high values of Ce/YbN (12.08-174.5), La/YbN (15.2-228.4) and La/SmN (2.6-7.2) in the granitic intrusions. Tectonic discrimination diagrams of the rocks indicate that the basement rocks were most probably formed in a post-collision orogenic setting while the dolerite and the rhyolite were formed in within-plate anorogenic setting.