ON THE STRUCTURAL, THERMAL, ELECTRICAL, AND MAGNETIC PROPERTIES OF AuSn

1963 ◽  
Vol 41 (12) ◽  
pp. 2252-2266 ◽  
Author(s):  
J.-P. Jan ◽  
W. B. Pearson ◽  
A. Kjekshus ◽  
S. B. Woods

The Au1−xSn phase has a homogeneity range within the limits 50.0 and 50.5 at.% Sn. The lattice constants and observed densities vary between the limits:[Formula: see text]The thermal conductivity, electrical resistivity, and absolute thermoelectric power of oriented single crystals of Au1−xSn have been measured between 2.5° K and room temperature. The results exhibit pronounced anisotropies. Measurements of the magnetic susceptibility between liquid air temperature and 650–750° K are also reported for three different Au1−xSn alloys.The various results are discussed, and some speculations are presented regarding the number of conduction electrons in AuSn.

2019 ◽  
Vol 289 ◽  
pp. 85-92
Author(s):  
Chihiro Sekine ◽  
Toshihide Osanai ◽  
Hariharan Ponmani ◽  
Atachariya Phuangyod ◽  
Yukihiro Kawamura ◽  
...  

We have succeeded in synthesizing new arsenic-based filled skutterudite compounds CaFe4As12and BaOs4As12under high pressure. These compounds have lattice constants of 8.3288 and 8.5809 Å, respectively. The magnetic properties of CaFe4As12and BaOs4As12have been studied by means of electrical resistivity, magnetic susceptibility and magnetization measurements. The electrical resistivity and magnetic measurements indicate that CaFe4As12is a nearly ferromagnetic metal with spin fluctuations of Fe 3delectrons and BaOs4As12is a new superconductor with a transition temperature around 3 K.


2004 ◽  
Vol 848 ◽  
Author(s):  
Andriy V. Tkachuk ◽  
Shane J. Crerar ◽  
Xing Wu ◽  
Craig P. T. Muirhead ◽  
Laura Deakin ◽  
...  

ABSTRACTTernary rare-earth transition-metal antimonides RExMySbz have provided fertile ground for discovering materials with varied electrical and magnetic properties such as superconductivity and ferromagnetism. The properties of two important classes of these compounds, RE3TiSb5 and RECrSb3, have been previously investigated. These studies have now been extended to RE3MSb5 (M = Zr, Hf), which show anomalies in their resistivity curves suggestive of electronic transitions, and YbCrSb3, which undergoes long-range magnetic ordering at 285 K, the highest Tc observed so far of all RECrSb3 members. Strong magnetic exchange interactions develop through coupling of f and d electrons in these compounds. The substitution of uranium for rare earth in RE3MSb5 results in the compounds U3MSb5 (M = Zr, Hf, Nb), which also display prominent transitions in their electrical resistivity and magnetic susceptibility curves.


1956 ◽  
Vol 34 (12A) ◽  
pp. 1190-1211 ◽  
Author(s):  
J. Friedel

The resistivity, thermoelectric power, and magnetic susceptibility of metallic solid solutions at room temperature are reviewed, and their relation with their electronic structure emphasized. The special properties of transitional impurities are related to the emptying of their d shells.


The electrical resistivities of lithium -6 and lithium of natural isotopic composition have been studied between 4°K and room temperature. In addition, their absolute resistivities have been carefully compared at room temperature. These measurements show that the effect of ionic mass on electrical resistivity agrees with simple theoretical predictions, namely, that the properties of the conduction electrons in lithium do not depend on the mass of the ions, and that the characteristic lattice frequencies for the two pure isotopes are in the inverse ratio of the square roots of their ionic masses. A comparison with the specific heat results of Martin (1959, 1960), where the simple theory is found not to hold, indicates the possibility that anharmonic effects are present which affect the specific heat but not the electrical resistivity.


2003 ◽  
Vol 793 ◽  
Author(s):  
Y. Amagai ◽  
A. Yamamoto ◽  
C. H. Lee ◽  
H. Takazawa ◽  
T. Noguchi ◽  
...  

ABSTRACTWe report transport properties of polycrystalline TMGa3(TM = Fe and Ru) compounds in the temperature range 313K<T<973K. These compounds exhibit semiconductorlike behavior with relatively high Seebeck coefficient, electrical resistivity, and Hall carrier concentrations at room temperature in the range of 1017- 1018cm−3. Seebeck coefficient measurements reveal that FeGa3isn-type material, while the Seebeck coefficient of RuGa3changes signs rapidly from large positive values to large negative values around 450K. The thermal conductivity of these compounds is estimated to be 3.5Wm−1K−1at room temperature and decreased to 2.5Wm−1K−1for FeGa3and 2.0Wm−1K−1for RuGa3at high temperature. The resulting thermoelectric figure of merit,ZT, at 945K for RuGa3reaches 0.18.


2004 ◽  
Vol 848 ◽  
Author(s):  
Evan Lyle Thomas ◽  
Erin E. Erickson ◽  
Monica Moldovan ◽  
David P. Young ◽  
Julia Y. Chan

AbstractA new member of the LnMIn5 family, ErCoIn5, has been synthesized by a flux-growth method. The structure of ErCoIn5 was determined by single crystal X-ray diffraction. It crystallizes in the tetragonal space group P4/mmm, Z = 1, with lattice parameters a = 4.5400(4) and c = 7.3970(7) Å, and V = 152.46(2) Å3. Electrical resistivity data show metallic behavior. Magnetic susceptibility measurements show this compound to be antiferromagnetic with TN = 5.1 K. We compare these experimental results with those of LaCoIn5 in an effort to better understand the effect of the structural trends observed on the transport and magnetic properties.


2020 ◽  
Vol 846 ◽  
pp. 156368
Author(s):  
Mohammad Shahnawaze Ansari ◽  
Mohd Hafiz Dzarfan Othman ◽  
Mohammad Omaish Ansari ◽  
Sana Ansari ◽  
Huda Abdullah ◽  
...  

1996 ◽  
Vol 10 (20) ◽  
pp. 955-961
Author(s):  
LAUREAN HOMORODEAN ◽  
IULIU POP ◽  
ION BURDOI

The changes in the temperature dependences of the magnetic susceptibility and the electrical resistivity of a very-high-T c superconducting YBa 2 Cu 3 O 7−δ sample during the thermal cycling between the liquid-nitrogen temperature and the room temperature are studied. Some singularities corresponding to the superconducting transition, the possible existence of a super-high-temperature superconducting phase and the migration of the oxygen atoms in the Cu-O chains are emphasized on these dependencies.


2018 ◽  
Vol 25 (02) ◽  
pp. 1850058
Author(s):  
T. KACEL ◽  
A. GUITTOUM ◽  
M. HEMMOUS ◽  
E. DIRICAN ◽  
R. M. ÖKSÜZOGLU ◽  
...  

We have studied the effect of thickness on the structural, microstructural, electrical and magnetic properties of Ni films electrodeposited onto [Formula: see text]-Si (100) substrates. A series of Ni films have been prepared for different potentials ranging from [Formula: see text]1.6[Formula: see text]V to [Formula: see text]2.6[Formula: see text]V. Rutherford backscattering spectrometry (RBS), X-ray diffraction (XRD), four point probe technique, atomic force microscopy (AFM) and vibrating sample magnetometry (VSM) have been used to investigate the physical properties of elaborated Ni thin films. From the analysis of RBS spectra, we have extracted the films thickness [Formula: see text] ([Formula: see text] ranges from 83[Formula: see text]nm to 422[Formula: see text]nm). We found that the Ni thickness, [Formula: see text] (nm), linearly increases with the applied potential. The Ni thin films are polycrystalline and grow with the [Formula: see text] texture. The lattice parameter [Formula: see text] (Å) monotonously decreases with increasing thickness. However, a positive strain was noted indicating that all the samples are subjected to a tensile stress. The mean grain sizes [Formula: see text] (nm) and the strain [Formula: see text] decrease with increasing thickness. The electrical resistivity [Formula: see text] ([Formula: see text]cm) increases with [Formula: see text] for [Formula: see text] less than 328[Formula: see text]nm. The diffusion at the grain boundaries may be the important factor in the electrical resistivity. From AFM images, we have shown that the Ni surface roughness decreases with increasing thickness. The coercive field [Formula: see text], the squareness factor [Formula: see text], the saturation field [Formula: see text] and the effective anisotropy constant [Formula: see text] are investigated as a function of Ni thickness and grain sizes. The correlation between the magnetic and the structural properties is discussed.


2005 ◽  
Vol 19 (01n03) ◽  
pp. 361-367
Author(s):  
H. K. LEE ◽  
Y. H. KIM ◽  
D. H. HA

We have investigated the Ca -doping effects on the structural, electrical and magnetic properties of ( Pb 0.5 Cu 0.5) Sr 2( Pr 1-x Ca x Cu 2 O z( x =0-0.5) bulk ceramic samples. The electrical resistivity, thermoelectric power and magnetic susceptibility measurements reveal that the Ca doping introduces holes into the system and thereby superconductivity with onset T c, of about 36 K is induced for a phase with x =0.5. These results are discussed in conjunction with the roles of hole doping, structural changes and Pr - O hybridization in CuO 2 layers.


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