Optical and electrical properties of ammonium perchlorate doped with chromate ions
Keyword(s):
The presence of CrO42− ions incorporated substitutionally in single crystals of NH4ClO4 grown from saturated solutions containing 0.1 mol% or 1 mol% CrO42− ion has been demonstrated by measurements of optical absorption, Raman scattering, dielectric loss, and ionic thermoconductivity. The three latter experiments also show the presence of dipoles associated with the CrO42− ions. The dc conductivity of NH4ClO4 crystals is enhanced by doping with CrO42− so that charge transport by defects introduced by the CrO42− ions is inferred. The implications of this finding with respect to mechanisms of charge transport in ammonium perchlorate are discussed.
2014 ◽
Vol 119
(2)
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pp. 1047-1052
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2004 ◽
Vol 24
(2)
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pp. 255-261
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2017 ◽
Vol 47
(2)
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pp. 1497-1504
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Keyword(s):
2018 ◽
Vol 2018
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pp. 1-8
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