Rotational analysis of bands of the 3400 Å system of disulphur monoxide (S2O)

1977 ◽  
Vol 55 (21) ◽  
pp. 1858-1867 ◽  
Author(s):  
K-E. J. Hallin ◽  
A. J. Merer ◽  
D. J. Milton
Keyword(s):  
Electronic Transition ◽  
Flow System ◽  
Type A ◽  
High Dispersion ◽  
Rotational Analysis ◽  
State Structure ◽  
Intensity Pattern ◽  
Rotational Constants ◽  
Long Wavelength

S2O has been prepared in a flow system, and various bands at the long wavelength end of the 3400 Å electronic transition photographed in absorption at high dispersion. Rotational analysis of the bands at 3235 and 3278 Å has shown that the bands are type A–B hybrids, with the type A component accounting for nearly all the observed structure. The electronic transition is therefore 1A′–1A′ (ππ*). The rotational constants imply the upper state structure r(S—S) = 2.14 Å, [Formula: see text], with r(S—O) = 1.50 Å (assumed).The vibrational intensity pattern is found to be in agreement with this structure if the electronic origin is placed at 29 696 cm−1 (3367 Å).

ROTATIONAL ANALYSIS OF THE γ SYSTEM OF THE PO MOLECULE

1958 ◽  
Vol 36 (11) ◽  
pp. 1526-1535 ◽  
Author(s):  
K. Suryanarayana Rao
Keyword(s):  
Ground State ◽  
Electronic Transition ◽  
Lower State ◽  
High Dispersion ◽  
Rotational Analysis ◽  
Small Perturbations ◽  
Rotational Constants ◽  
The One

The bands of the γ system of the PO molecule have been photographed under high dispersion (0.35 Å/mm). A rotational analysis of the 0–0, 0–1, and 1–0 bands is given, which differs from the one previously given by Sen Gupta. In addition, four more bands, namely, the 1–2, 2–1, 2–3, and 2–4 bands, have been analyzed. The bands are attributed to the electronic transition, A3Σ–X2Πreg, the lower state being the ground state of the molecule. The new rotational constants for the ground state are the following:[Formula: see text]The spin doubling in the upper state is small. Perturbations in the v = 0 level of the upper state, which were not reported previously, are observed and discussed. They supply a welcome confirmation of the correctness of the analysis here presented.

ROTATIONAL ANALYSIS OF THE VISIBLE BAND SYSTEM OF THE BiF MOLECULE

1962 ◽  
Vol 40 (9) ◽  
pp. 1077-1084 ◽  
Author(s):  
T. A. Prasada Rao ◽  
P. Tiruvenganna Rao
Keyword(s):  
Band System ◽  
High Dispersion ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Visible Band ◽  
System A

A rotational analysis of five bands, (1,0), (0,0), (0,1), (0.2), and (0,3), of the visible band system A of BiF has been carried out by photographing the bands under high dispersion (1.25 Å/mm). The analysis has shown that the bands arise from a 0+(3Σ−)–0+(3Σ−) transition. The rotational constants for the upper and lower states of the system are obtained.

A 3Σ–3Π transition of the SiO molecule

1970 ◽  
Vol 48 (12) ◽  
pp. 1436-1440 ◽  
Author(s):  
S. Nagaraj ◽  
R. D. Verma
Keyword(s):  
Quartz Tube ◽  
High Dispersion ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Single Sequence

The spectrum in the region 4200–4300 Å, attributed to the SiO molecule, has been excited strongly in a r.f. discharge through a mixture of argon and a trace of SiCl4 vapor flowing through a quartz tube. The spectrum consists of a single sequence Δν = 0. The 0–0 and 1–1 bands have been photographed at high dispersion. A rotational analysis of these bands shows that they involve a 3Σ–3II transition and not a 1Σ–3Π transition as reported earlier. The following rotational constants were determined:[Formula: see text]

Spectrum of azulene. IV. Rotational analysis of the 0-0 band of the 3500 Ǻ transition

1968 ◽  
Vol 21 (12) ◽  
pp. 2835 ◽  
Author(s):  
AJ McHugh ◽  
DA Ramsay ◽  
IG Ross
Keyword(s):  
Fine Structure ◽  
Excited State ◽  
Type A ◽  
Resolving Power ◽  
Rotational Analysis ◽  
Type B ◽  
Rotational Constants ◽  
Multiple Line ◽  
Asymmetric Top ◽  
Low K

The bands of the 3500 Ǻ transition of azulene-do and azulene-ds show two unequal peaks 2.3 cm-l apart, followed by closely spaced fine structure. These bands have been analysed as type A bands of a planar, prolate asymmetric top. Rotational constants for both molecules in the excited state have been determined. The fine structure is due to multiple line coincidences in the high-J, low-K region of the qP branch. To each multiple line can be attributed a running number n = J+m, where m = J-K-1. Given sufficient resolving power, such "lines" should be rather commonly observed in type A and type B bands of large, planar, prolate molecules.

A new electronic transition C2πr–A2πi, of AlO

1982 ◽  
Vol 60 (12) ◽  
pp. 1730-1742 ◽  
Author(s):  
M. Singh ◽  
M. D. Saksena
Keyword(s):  
High Resolution ◽  
Electronic Transition ◽  
High Frequency ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
High Frequency Discharge

Several weak bands of AlO, degraded to the violet and occurring as wide doublets 200 cm−1 apart, have been observed in the region 3300–4000 Å, in emission from a high frequency discharge through a flowing mixture of AlCl3 vapour, oxygen, and argon. These bands have been identified as due to a new electronic transition C2πr–A2πi of AlO. This has been confirmed from a detailed rotational analysis of the 1–0 and 0–1 bands (heads, respectively, at 3481.92, 3506.09 Å and 3683.30, 3710.98 Å) from high resolution spectra. Numerous rotational perturbations have been found in both the C2π3/2 and C2π1/2 substates. Effective rotational constants have been determined for these substates. Λ-doubling has been observed even in the substate C2π3/2.

Rotational analysis of bands at the long-wavelength end of the electronic transition of ClO2

1981 ◽  
Vol 86 (2) ◽  
pp. 499-525 ◽  
Author(s):  
Y. Hamada ◽  
A.J. Merer ◽  
S. Michielsen ◽  
S.A. Rice
Keyword(s):  
Electronic Transition ◽  
Rotational Analysis ◽  
Long Wavelength

Spectre d'émission du radical P2 : étude de la transition b′3Σu−–X1Σg+

1974 ◽  
Vol 52 (21) ◽  
pp. 2143-2149 ◽  
Author(s):  
J. Brion ◽  
J. Malicet ◽  
H. Guenebaut
Keyword(s):  
High Resolution ◽  
Emission Spectrum ◽  
Electronic Transition ◽  
Spin Splitting ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Vibrational Levels

The emission spectrum of the b′3Σu−–X1Σg+ system between 3540–4375 Å and ascribed previously by Mrozowski and Santaram to the a3Σu+–X1Σg+ transition of the P2 molecule, has been photographed under high resolution. The rotational analysis of 7 bands has been carried out and allowed us to determine the rotational constants of the vibrational levels ν′ = 0, 1, and 2 as well as the spin splitting constants λ′ and γ′. The nature of the upper state has been identified as a 3Σu− state, the electronic transition being analogous to the Ogawa–Tanaka–Wilkinson system of N2.

scholarly journals The λ3400 bands of PH and PD

1939 ◽  
Vol 173 (953) ◽  
pp. 265-277 ◽  
Keyword(s):  
Band Structure ◽  
Discharge Tube ◽  
Electronic Transition ◽  
Theoretical Work ◽  
Rotational Structure ◽  
High Dispersion ◽  
Rotational Constants ◽  
Type Of Transition

The phosphorus hydride band at λ3400 was first reported by Geuter (1907) in an account of an investigation of the spectra associated with phosphorus. It was obtained with a discharge tube containing phosphorus in addition to hydrogen. Pearse (1930) photographed the band with high dispersion, showed that the electronic transition involved was of the type 3 Π i → 3 Σ , and attributed the band to the molecule PH. Since this analysis further theoretical work on this type of transition has been published by Hebb (1936), and calculations of the rotational constants for the 3 Π state of PH have been made by Gilbert (1936) and Budo (1936). A study of the distribution of intensity in the rotational structure has been made by Noland and Jenkins (1936). The present paper is devoted to a study of the changes produced in the band structure by replacing the hydrogen in the molecule by deuterium.

STRUCTURE OF THE BAND SPECTRUM OF THE CuI MOLECULE: I. ROTATIONAL STRUCTURE OF THE E SYSTEM OF 63Cu127I

1966 ◽  
Vol 44 (10) ◽  
pp. 2241-2245 ◽  
Author(s):  
P. Ramakoteswara Rao ◽  
K. V. S. R. Apparao
Keyword(s):  
High Resolution ◽  
Electronic Transition ◽  
Band System ◽  
Rotational Structure ◽  
Band Spectrum ◽  
Rotational Analysis ◽  
Rotational Constants

The E band system of 63Cu127I, lying in the region 3 700 to 4 700 Å, has been photographed in emission under high resolution. Rotational analysis of the (0–4), (0–3), (0–2), (0–1), (0–0), (1–1), (1–0), (2–0), and (3–2) bands has been made. The electronic transition involved is found to be 1Σ (E1Σ)–1Σ(X1Σ). The rotational constants obtained are as follows:[Formula: see text]

ROTATIONAL ANALYSIS OF THE β BANDS OF PHOSPHORUS MONOXIDE

1959 ◽  
Vol 37 (2) ◽  
pp. 136-143 ◽  
Author(s):  
Nand Lal Singh
Keyword(s):  
Ground State ◽  
Band System ◽  
Electronic States ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Fine Structures ◽  
Π State

The fine structures of three of the β bands of PO which occur near 3200 Å have been analyzed. The analysis shows that the upper state of this band system is a 2Σ and not a 2Π state as previously believed. The rotational constants of both electronic states have been determined and it is found that the ground state constants, previously determined from the γ bands, are incorrect.

Sign in / Sign up

Export Citation Format

Share Document