CONSTITUTION OF AN ARABINOGALACTOMANNAN FROM HONEY
An arabinogalactomannan isolated from honey consisted of D-mannose, L-arabinose, and D-galactose in molar proportions of 1.0:2.04:4.04 respectively. Electrophoretic and sedimentation results indicated that the arabinogalactomannan was homogeneous. Methylation studies showed a highly branched structure. Hydrolysis of the methylated polysaccharide gave 2,3,4,6-tetra-O-methyl-D-mannose (3 molecular proportions); 2,3,4,6-tetra-O-methyl-D-galactose (2 molecular proportions); 2,3,5-tri-O-methyl-L-arabinose (1 molecular proportion); 2,3,4-tri-O-methyl-D-galactose (6 molecular proportions); 2,3-di-O-methyl-L-arabinose (4 molecular proportions); 2,5-di-O-methyl-L-arabinose (1 molecular proportion); 2,4-di-O-methyl-D-galactose (5 molecular proportions). The general structural features of the arabinogalactomannan are discussed.