Cation transport in gaseous nitrogen: density and temperature effects
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The density-normalized mobility of nμ of cations in nitrogen gas at densities up to nc = 6.7 × 1027 molecules/m3 increases with temperature. At n ≤ 5.7 × 1025 molecules/m3 and T > 250 K, the dominating ion is N4+. At lower temperatures and higher densities, relatively loosely bound clusters N4+(N2), N4+(N2)2, … form. Momentum transfer cross sections for N4+–N2 are governed at low energies by the polarization potential, and at high energies by the hard body potential. The cross section for N2+–N2 at high energies is larger than that for N4+–N2.
2016 ◽
Vol 31
(10)
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pp. 1650066
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1968 ◽
Vol 23
(12)
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pp. 2084-2090
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2001 ◽
Vol 16
(37)
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pp. 2387-2397
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