Copper(I)-catalyzed cross-dehydrocoupling reactions of silanes and amines
Keyword(s):
In the presence of cuprous chloride, hydrosilanes and primary amines react to give silazanes. Methylphenylsilane reacts with (R)-(+)-α-methylbenzylamine to give the two diastereomeric monosilazanes as the only products. Aniline and benzylamine react with methylphenyl- and diphenylsilanes to give primarily the monosilazane, disilazane, or diazasilane as the main product, depending on the reactant ratios. Phenylsilane gives higher oligomers with aniline, mainly the trisilatriazane and trisiladiazanes, but no high molecular weight material. Keywords: silanes, amines, silazanes, cuprous chloride, dehydrocoupling, catalysis.
2001 ◽
Vol 49
(4)
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pp. 1773-1782
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1977 ◽
1961 ◽
Vol 34
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pp. 101-118
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1981 ◽
1967 ◽
Vol 141
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pp. 533-539
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1944 ◽
Vol 09
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pp. 102-112
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