The NEGATOR as a Basic Building Block for Quantum Circuits

2013 ◽  
Vol 20 (01) ◽  
pp. 1350004 ◽  
Author(s):  
Alexis De Vos ◽  
Stijn De Baerdemacker
Keyword(s):  
Quantum Computation ◽  
Building Block ◽  
Building Blocks ◽  
Quantum Circuits ◽  
Square Root ◽  
Basic Building Block ◽  
Unitary Matrices ◽  
Reversible Computation

Between (classical) reversible computation and quantum computation there exists an intermediate computational world, represented by unitary matrices that have all line sums equal to 1. All of these quantum circuits can be synthesized with the help of merely two building blocks: the NEGATOR and the singly controlled square root of NOT.

Thienopyrrolocarbazoles: New Building Blocks for Functional Organic Materials

2019 ◽  
Author(s):  
Dorian Bader ◽  
Johannes Fröhlich ◽  
Paul Kautny
Keyword(s):  
Building Block ◽  
Organic Materials ◽  
Building Blocks ◽  
Molecular Properties ◽  
The Family ◽  
Facile Preparation

The facile preparation of three regioisomeric thienopyrrolocarbazoles applying a convenient C-H activation approach is presented. Derived from indolo[3,2,1-<i>jk</i>]carbazole, the incorporation of thiophene into the triarylamine framework significantly impacted the molecular properties of the parent scaffold. The developed thienopyrrolocarbazoles enrich the family of triarylamine donors and constitute a novel building block for functional organic materials.

Thienopyrrolocarbazoles: New Building Blocks for Functional Organic Materials

2019 ◽  
Author(s):  
Dorian Bader ◽  
Johannes Fröhlich ◽  
Paul Kautny
Keyword(s):  
Building Block ◽  
Organic Materials ◽  
Building Blocks ◽  
Molecular Properties ◽  
The Family ◽  
Facile Preparation

The facile preparation of three regioisomeric thienopyrrolocarbazoles applying a convenient C-H activation approach is presented. Derived from indolo[3,2,1-<i>jk</i>]carbazole, the incorporation of thiophene into the triarylamine framework significantly impacted the molecular properties of the parent scaffold. The developed thienopyrrolocarbazoles enrich the family of triarylamine donors and constitute a novel building block for functional organic materials.

scholarly journals PyroMEMS as Future Technological Building Blocks for Advanced Microenergetic Systems

Micromachines ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 118
Author(s):  
Jean-Laurent Pouchairet ◽  
Carole Rossi
Keyword(s):  
Building Block ◽  
Building Blocks ◽  
Small Scale ◽  
Technological Evolution ◽  
Research Groups ◽  
Function Block ◽  
The Past ◽  
New Methods ◽  
Safety And Reliability ◽  
Electronically Controllable

For the past two decades, many research groups have investigated new methods for reducing the size and cost of safe and arm-fire systems, while also improving their safety and reliability, through batch processing. Simultaneously, micro- and nanotechnology advancements regarding nanothermite materials have enabled the production of a key technological building block: pyrotechnical microsystems (pyroMEMS). This building block simply consists of microscale electric initiators with a thin thermite layer as the ignition charge. This microscale to millimeter-scale addressable pyroMEMS enables the integration of intelligence into centimeter-scale pyrotechnical systems. To illustrate this technological evolution, we hereby present the development of a smart infrared (IR) electronically controllable flare consisting of three distinct components: (1) a controllable pyrotechnical ejection block comprising three independently addressable small-scale propellers, all integrated into a one-piece molded and interconnected device, (2) a terminal function block comprising a structured IR pyrotechnical loaf coupled with a microinitiation stage integrating low-energy addressable pyroMEMS, and (3) a connected, autonomous, STANAG 4187 compliant, electronic sensor arming and firing block.

scholarly journals Connectivity matrix model of quantum circuits and its application to distributed quantum circuit optimization

2021 ◽  
Vol 20 (7) ◽  
Author(s):  
Ismail Ghodsollahee ◽  
Zohreh Davarzani ◽  
Mariam Zomorodi ◽  
Paweł Pławiak ◽  
Monireh Houshmand ◽  
...  
Keyword(s):  
Quantum Computation ◽  
Quantum Computer ◽  
Quantum Circuit ◽  
Quantum Circuits ◽  
Connectivity Matrix ◽  
Circuit Optimization ◽  
Novel Approach ◽  
The Matrix ◽  
Minimum Number ◽  
Two Phases

AbstractAs quantum computation grows, the number of qubits involved in a given quantum computer increases. But due to the physical limitations in the number of qubits of a single quantum device, the computation should be performed in a distributed system. In this paper, a new model of quantum computation based on the matrix representation of quantum circuits is proposed. Then, using this model, we propose a novel approach for reducing the number of teleportations in a distributed quantum circuit. The proposed method consists of two phases: the pre-processing phase and the optimization phase. In the pre-processing phase, it considers the bi-partitioning of quantum circuits by Non-Dominated Sorting Genetic Algorithm (NSGA-III) to minimize the number of global gates and to distribute the quantum circuit into two balanced parts with equal number of qubits and minimum number of global gates. In the optimization phase, two heuristics named Heuristic I and Heuristic II are proposed to optimize the number of teleportations according to the partitioning obtained from the pre-processing phase. Finally, the proposed approach is evaluated on many benchmark quantum circuits. The results of these evaluations show an average of 22.16% improvement in the teleportation cost of the proposed approach compared to the existing works in the literature.

scholarly journals Lipase Catalyzed Synthesis of Enantiopure Precursors and Derivatives for β-Blockers Practolol, Pindolol and Carteolol

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 503
Author(s):  
Morten Gundersen ◽  
Guro Austli ◽  
Sigrid Løvland ◽  
Mari Hansen ◽  
Mari Rødseth ◽  
...  
Keyword(s):  
Building Block ◽  
Kinetic Resolution ◽  
Enantiomeric Excess ◽  
Catalytic Amount ◽  
Building Blocks ◽  
Β Blocker ◽  
Β Blockers ◽  
Optical Rotations ◽  
Reported Data ◽  
By Products

Sustainable methods for producing enantiopure drugs have been developed. Chlorohydrins as building blocks for several β-blockers have been synthesized in high enantiomeric purity by chemo-enzymatic methods. The yield of the chlorohydrins increased by the use of catalytic amount of base. The reason for this was found to be the reduced formation of the dimeric by-products compared to the use of higher concentration of the base. An overall reduction of reagents and reaction time was also obtained compared to our previously reported data of similar compounds. The enantiomers of the chlorohydrin building blocks were obtained by kinetic resolution of the racemate in transesterification reactions catalyzed by Candida antarctica Lipase B (CALB). Optical rotations confirmed the absolute configuration of the enantiopure drugs. The β-blocker (S)-practolol ((S)-N-(4-(2-hydroxy-3-(isopropylamino)propoxy)phenyl)acetamide) was synthesized with 96% enantiomeric excess (ee) from the chlorohydrin (R)-N-(4-(3-chloro-2 hydroxypropoxy)phenyl)acetamide, which was produced in 97% ee and with 27% yield. Racemic building block 1-((1H-indol-4-yl)oxy)-3-chloropropan-2-ol for the β-blocker pindolol was produced in 53% yield and (R)-1-((1H-indol-4-yl)oxy)-3-chloropropan-2-ol was produced in 92% ee. The chlorohydrin 7-(3-chloro-2-hydroxypropoxy)-3,4-dihydroquinolin-2(1H)-one, a building block for a derivative of carteolol was produced in 77% yield. (R)-7-(3-Chloro-2-hydroxypropoxy)-3,4-dihydroquinolin-2(1H)-one was obtained in 96% ee. The S-enantiomer of this carteolol derivative was produced in 97% ee in 87% yield. Racemic building block 5-(3-chloro-2-hydroxypropoxy)-3,4-dihydroquinolin-2(1H)-one, building block for the drug carteolol, was also produced in 53% yield, with 96% ee of the R-chlorohydrin (R)-5-(3-chloro-2-hydroxypropoxy)-3,4-dihydroquinolin-2(1H)-one. (S)-Carteolol was produced in 96% ee with low yield, which easily can be improved.

scholarly journals Dimerization and oligomerization of DNA-assembled building blocks for controlled multi-motion in high-order architectures

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Ling Xin ◽  
Xiaoyang Duan ◽  
Na Liu
Keyword(s):  
Building Block ◽  
Degrees Of Freedom ◽  
Building Blocks ◽  
Single Type ◽  
Hierarchical Assembly ◽  
Optical Responses ◽  
Self Association ◽  
Living Organisms ◽  
Order Structures ◽  
Chiral System

AbstractIn living organisms, proteins are organized prevalently through a self-association mechanism to form dimers and oligomers, which often confer new functions at the intermolecular interfaces. Despite the progress on DNA-assembled artificial systems, endeavors have been largely paid to achieve monomeric nanostructures that mimic motor proteins for a single type of motion. Here, we demonstrate a DNA-assembled building block with rotary and walking modules, which can introduce new motion through dimerization and oligomerization. The building block is a chiral system, comprising two interacting gold nanorods to perform rotation and walking, respectively. Through dimerization, two building blocks can form a dimer to yield coordinated sliding. Further oligomerization leads to higher-order structures, containing alternating rotation and sliding dimer interfaces to impose structural twisting. Our hierarchical assembly scheme offers a design blueprint to construct DNA-assembled advanced architectures with high degrees of freedom to tailor the optical responses and regulate multi-motion on the nanoscale.

scholarly journals Bioelectrocatalytic hydrogels from electron-conducting metallopolypeptides coassembled with bifunctional enzymatic building blocks

2008 ◽  
Vol 105 (40) ◽  
pp. 15275-15280 ◽  
Author(s):  
Ian R. Wheeldon ◽  
Joshua W. Gallaway ◽  
Scott Calabrese Barton ◽  
Scott Banta
Keyword(s):  
Polyphenol Oxidase ◽  
Building Block ◽  
Leucine Zipper ◽  
Electrical Contact ◽  
Building Blocks ◽  
Coiled Coils ◽  
Biofuel Cell ◽  
Random Coil ◽  
Catalytic Current ◽  
And Function

Here, we present two bifunctional protein building blocks that coassemble to form a bioelectrocatalytic hydrogel that catalyzes the reduction of dioxygen to water. One building block, a metallopolypeptide based on a previously designed triblock polypeptide, is electron-conducting. A second building block is a chimera of artificial α-helical leucine zipper and random coil domains fused to a polyphenol oxidase, small laccase (SLAC). The metallopolypeptide has a helix–random-helix secondary structure and forms a hydrogel via tetrameric coiled coils. The helical and random domains are identical to those fused to the polyphenol oxidase. Electron-conducting functionality is derived from the divalent attachment of an osmium bis-bipyrdine complex to histidine residues within the peptide. Attachment of the osmium moiety is demonstrated by mass spectroscopy (MS-MALDI-TOF) and cyclic voltammetry. The structure and function of the α-helical domains are confirmed by circular dichroism spectroscopy and by rheological measurements. The metallopolypeptide shows the ability to make electrical contact to a solid-state electrode and to the redox centers of modified SLAC. Neat samples of the modified SLAC form hydrogels, indicating that the fused α-helical domain functions as a physical cross-linker. The fusion does not disrupt dimer formation, a necessity for catalytic activity. Mixtures of the two building blocks coassemble to form a continuous supramolecular hydrogel that, when polarized, generates a catalytic current in the presence of oxygen. The specific application of the system is a biofuel cell cathode, but this protein-engineering approach to advanced functional hydrogel design is general and broadly applicable to biocatalytic, biosensing, and tissue-engineering applications.

scholarly journals MEASUREMENT-BASED QUANTUM COMPUTATION WITH CLUSTER STATES

2009 ◽  
Vol 07 (06) ◽  
pp. 1053-1203 ◽  
Author(s):  
ROBERT RAUßENDORF
Keyword(s):  
Computational Model ◽  
Quantum Computation ◽  
Quantum Logic ◽  
Network Model ◽  
Quantum Computer ◽  
Fault Tolerant ◽  
Cluster State ◽  
Building Blocks ◽  
Network Simulator ◽  
Classical Level

In this thesis, we describe the one-way quantum computer [Formula: see text], a scheme of universal quantum computation that consists entirely of one-qubit measurements on a highly entangled multiparticle state, i.e. the cluster state. We prove the universality of the [Formula: see text], describe the underlying computational model and demonstrate that the [Formula: see text] can be operated fault-tolerantly. In Sec. 2, we show that the [Formula: see text] can be regarded as a simulator of quantum logic networks. In this way, we prove the universality and establish the link to the network model — the common model of quantum computation. We also indicate that the description of the [Formula: see text] as a network simulator is not adequate in every respect. In Sec. 3, we derive the computational model underlying the [Formula: see text], which is very different from the quantum logic network model. The [Formula: see text] has no quantum input, no quantum output and no quantum register, and the unitary gates from some universal set are not the elementary building blocks of [Formula: see text] quantum algorithms. Further, all information that is processed with the [Formula: see text] is the outcomes of one-qubit measurements and thus processing of information exists only at the classical level. The [Formula: see text] is nevertheless quantum-mechanical, as it uses a highly entangled cluster state as the central physical resource. In Sec. 4, we show that there exist nonzero error thresholds for fault-tolerant quantum computation with the [Formula: see text]. Further, we outline the concept of checksums in the context of the [Formula: see text], which may become an element in future practical and adequate methods for fault-tolerant [Formula: see text] computation.

Fe@B6H6 Aggregates: From Simple Building Blocks to Graphene Analogue

2021 ◽  
Author(s):  
Chao Wang ◽  
Jianhua Hou ◽  
Qian Duan
Keyword(s):  
Building Block ◽  
Building Blocks ◽  
Electron Structure ◽  
Chemical Doping ◽  
Hole Density ◽  
Hexagonal Hole

Abstract We suggest the possibility to build graphene analogue with the planar hexacoordinate wheel-type Fe@B6H6 cluster as the building block through studying theoretically the geometry, stability and electron structure of its dimer and trimer as well as the dimerization of the two trimers. Employing the dehydrogenation route to polymerization, we can obtain the hexagonal boron sheet that are partly and uniformly filled by Fe atoms in the center of the holes, achieving uniform chemical doping and a very large hexagonal-hole-density. Thus, we may offer a novel cluster-assembled material for experimental chemists to construct graphene analogue.

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