Synthesis of Direct Z-Scheme MnWO4/g-C3N4 Photocatalyst with Enhanced Visible Light Photocatalytic Activity

NANO ◽  
2017 ◽  
Vol 12 (10) ◽  
pp. 1750129 ◽  
Author(s):  
Kuili Liu ◽  
Jinlin Li ◽  
Xu Yan ◽  
Weidong Shi
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Environmental Remediation ◽  
Carbon Nitride ◽  
Active Species ◽  
Electron Hole ◽  
Facile Hydrothermal Method ◽  
Strong Light ◽  
Spin Resonance ◽  
Visible Light Photocatalytic

In this study, direct Z-scheme MnWO4/g-C3N4 photocatalyst was fabricated via facile hydrothermal method. Compared with pristine graphitic carbon nitride (g-C3N4) and manganous tungstate (MnWO4), the prepared MnWO4/g-C3N4 photocatalyst showed obviously enhanced photocatalytic activity for Rhodamine B (RhB) degradation under visible light irradiation. The MnWO4/g-C3N4 photocatalyst prepared with 10% MnWO4 (MC10%) showed the highest photocatalytic activity among all samples, which is about 2.3 and 12.7 times than that of pristine g-C3N4 and MnWO4, respectively. This enhancement is due to the strong light absorption and efficient electron–hole separation of direct Z-scheme MnWO4/g-C3N4 photocatalyst. Electron spin resonance (ESR) experiments and active species trapping experiments revealed that [Formula: see text]OH and [Formula: see text] are the main active species in the photocatalytic process. This work may be beneficial for designing MnWO4-based Z-scheme photocatalyst for application in environmental remediation.

scholarly journals A metal-free 3C-SiC/g-C3N4 composite with enhanced visible light photocatalytic activity

RSC Advances ◽  
2017 ◽  
Vol 7 (63) ◽  
pp. 40028-40033 ◽  
Author(s):  
Hao Xu ◽  
Zhixing Gan ◽  
Weiping Zhou ◽  
Zuoming Ding ◽  
Xiaowei Zhang
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Light Absorption ◽  
Carbon Nitride ◽  
Photocatalytic Performance ◽  
Photogenerated Electron ◽  
Electron Hole ◽  
Visible Light Absorption ◽  
Metal Free ◽  
Visible Light Photocatalytic

Insufficient visible light absorption and fast recombination of the photogenerated electron–hole pairs have seriously hampered the photocatalytic performance of graphitic carbon nitride (g-C3N4) up to now.

Enhanced visible light photocatalytic activity of AgI/TiO2 composite fabricated by a grinding method

2019 ◽  
Vol 54 (3) ◽  
pp. 257-264
Author(s):  
Jin Xu ◽  
Dasheng Gao ◽  
Shuang Cui ◽  
Xiaohua Wang ◽  
Ningning Liu
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Active Sites ◽  
Photocatalytic Performance ◽  
Photogenerated Electron ◽  
Active Species ◽  
Electron Hole ◽  
Grinding Method ◽  
The Stability ◽  
Visible Light Photocatalytic

Abstract Through a simple grinding method, AgI/TiO2 composites were successfully synthesized. The as-prepared AgI/TiO2 composites were used as photocatalysts for Rhodamine B (RhB) degradation under visible light irradiation and exhibited excellent photocatalytic performance. In the presence of composites, almost 100% RhB was decomposed after 60 min. The photocatalytic activity of AgI/TiO2-0.5 composite was optimal, which was 9.5 times higher than that of pristine TiO2, and 15.6 times higher than that of AgI. Moreover, experimental results revealed that the improved photocatalytic activity was not only ascribed to the loading AgI but also resulted from the method that enabled the exposure of more active sites in the composites. In addition, the intimate interfacial contact obtained by this method could also promote the efficient separation of photogenerated electron-hole pairs. Moreover, the possible photocatalytic active species and the stability of the photocatalyst were investigated in detail.

scholarly journals Facile Synthesis of Metal Doped Graphite Carbon Nitride for Photocatalytic Degradation of Tetracycline Under Visible Light Irradiation

2021 ◽  
Author(s):  
yin zhao ◽  
hong qin ◽  
Qianlan luo ◽  
ziwei wang ◽  
han wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Carbon Nitride ◽  
High Efficiency ◽  
Active Species ◽  
Facile Synthesis ◽  
Electron Hole ◽  
Graphite Phase ◽  
Spin Resonance ◽  
Catalyst Dosage ◽  
Metal Doped

Abstract Using semiconductor photocatalysts for antibiotic contaminants degradation under visible light has become a hot topic in recent years. Herein, a novel cadmium doped graphite phase carbon nitride (Cd/g-C3N4) photocatalyst was successfully constructed via 60 °C oil bath method to degrade tetracycline. Experimental and characterization results revealed that cadmium was well doped at g-C3N4 surface and exhibited high intercontact with g-C3N4. Meanwhile, Cd/g-C3N4 presented excellent electrical conductivity and inhibited the recombination of electron-hole pairs. The introduction of cadmium significantly improved the photocatalytic activity and the degradation efficiency of 10 Cd/g-C3N4 reached to 89.09%, which was exceeded 2.0 times than pure g-C3N4 (43.99%). Additionally, the quenching experiments and electron spin-resonance tests exhibited holes (h+), hydroxyl radicals (•OH) and superoxide radicals (•O2−) were dominated active species in TC degradation. Furthermore, the effects of various conditions on the reaction process, such as different pH, initial TC concentrations and catalyst dosage, were also researched. This work gives a reasonable point to synthesize high-efficiency and economic photocatalysts.

scholarly journals Preparation of Graphite Phase Bismuth Carbon Nitride Vanadate Composites and Experimental Analysis of Free Radical Capture

2021 ◽  
Vol 898 (1) ◽  
pp. 012025
Author(s):  
Wei’e Wang ◽  
Bohong Wu ◽  
Zhiyang Gao ◽  
Yuguang Lv
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Carbon Nitride ◽  
Active Species ◽  
Photocatalytic Process ◽  
Pollutant Degradation ◽  
Graphite Phase ◽  
Visible Light Photocatalytic ◽  
Degradation Of Pollutants ◽  
Composite Samples

Abstract Photocatalysts are mainly divided into two categories: one is that they have good response to sunlight and visible light, such as BiVO4 and Fe2O3; One is that it has its own defects and can not make full use of the energy converted by visible light. In recent years, a class of oxides have attracted much attention because of their good performance of visible light photocatalytic degradation of pollutants. People also have a strong interest in the research of compound oxides in pollutant degradation. In order to further clarify the photocatalytic mechanism of GCB composite samples, different capture agents were added to determine the main active species in the photocatalytic process. Only through the method of modification, the synergistic effect can enhance its photocatalytic activity. 1% g-C3N4/BiVO4(GCB) sample, drhb = 90.4%, the photocatalytic activity did not change significantly after adding IPA. After adding EDTA and VC, the photocatalytic activity decreased, drhb = 32.6% and drhb = 51%. Therefore, the experiments show that h+ and ·O2- are active species of GCB catalytic system, O2 is more important for RHB degradation.

scholarly journals Enhanced Visible-Light Photocatalytic Performance of SAPO-5-Based g-C3N4 Composite for Rhodamine B (RhB) Degradation

Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3948
Author(s):  
Lingfang Qiu ◽  
Zhiwei Zhou ◽  
Mengfan Ma ◽  
Ping Li ◽  
Jinyong Lu ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Redox Reactions ◽  
Photocatalytic Performance ◽  
Dye Degradation ◽  
Thermal Polymerization ◽  
Light Illumination ◽  
Electron Hole ◽  
Visible Light Illumination ◽  
Visible Light Photocatalytic

Novel visible-light responded aluminosilicophosphate-5 (SAPO-5)/g-C3N4 composite has been easily constructed by thermal polymerization for the mixture of SAPO-5, NH4Cl, and dicyandiamide. The photocatalytic activity of SAPO-5/g-C3N4 is evaluated by degrading RhB (30 mg/L) under visible light illumination (λ > 420 nm). The effects of SAPO-5 incorporation proportion and initial RhB concentration on the photocatalytic performance have been discussed in detail. The optimized SAPO-5/g-C3N4 composite shows promising degradation efficiency which is 40.6% higher than that of pure g-C3N4. The degradation rate improves from 0.007 min−1 to 0.022 min−1, which is a comparable photocatalytic performance compared with other g-C3N4-based heterojunctions for dye degradation. The migration of photo-induced electrons from g-C3N4 to the Al site of SAPO-5 should promote the photo-induced electron-hole pairs separation rate of g-C3N4 efficiently. Furthermore, the redox reactions for RhB degradation occur on the photo-induced holes in the g-C3N4 and Al sites in SAPO-5, respectively. This achievement not only improves the photocatalytic activity of g-C3N4 efficiently, but also broadens the application of SAPOs in the photocatalytic field.

Facile preparation of C, N co-modified Nb2O5 nanoneedles with enhanced visible light photocatalytic activity

2016 ◽  
Vol 45 (41) ◽  
pp. 16519-16525 ◽  
Author(s):  
Jiao Xue ◽  
Runwei Wang ◽  
Zongtao Zhang ◽  
Shilun Qiu
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Nitrogen Source ◽  
Hydrothermal Method ◽  
Niobium Pentoxide ◽  
Facile Hydrothermal Method ◽  
Carbon And Nitrogen ◽  
Niobium Chloride ◽  
Facile Preparation ◽  
Visible Light Photocatalytic

C, N co-modified niobium pentoxide (Nb2O5) nanoneedles have been successfully synthesized via a facile hydrothermal method with Niobium Chloride (NbCl5) as a precursor and triethylamine as both the carbon and nitrogen source.

scholarly journals Effects of the preparation method on the structure and the visible-light photocatalytic activity of Ag2CrO4

2014 ◽  
Vol 5 ◽  
pp. 658-666 ◽  
Author(s):  
Difa Xu ◽  
Shaowen Cao ◽  
Jinfeng Zhang ◽  
Bei Cheng ◽  
Jiaguo Yu
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Environmental Remediation ◽  
Preparation Method ◽  
Blue Shift ◽  
Preparation Methods ◽  
Visible Light Photocatalytic Activity ◽  
The Comparative Study ◽  
Hydrothermal Methods ◽  
Visible Light Photocatalytic

Silver chromate (Ag2CrO4) photocatalysts are prepared by microemulsion, precipitation, and hydrothermal methods, in order to investigate the effect of preparation methods on the structure and the visible-light photocatalytic activity. It is found that the photocatalytic activity of the prepared Ag2CrO4was highly dependent on the preparation methods. The sample prepared by microemulsion method exhibits the highest photocatalytic efficiency on the degradation of methylene blue (MB) under visible-light irradiation. The enhanced photocatalytic activity could be ascribed to the smaller particle size, higher surface area, relatively stronger light absorption, and blue-shift absorption edge, which result in the adsorption of more MB molecules, a shorter diffusion process of more photogenerated excitons, and a stronger oxidation ability of the photogenerated holes. Considering the universalities of microemulsion, precipitation, and hydrothermal methods, this work may also provide a prototype for the comparative study of semiconductor based photocatalysis for water purification and environmental remediation.

Graphite-like carbon nitride quantum dot (CNQD)-modified Bi2MoO6 heterostructure with high visible-light photocatalytic activity

2019 ◽  
Vol 43 (1) ◽  
pp. 162-167 ◽  
Author(s):  
Da Xu ◽  
Chang Liu ◽  
Hairui Wang ◽  
Limin Chang ◽  
Xue Lin
Keyword(s):  
Photocatalytic Activity ◽  
Quantum Dot ◽  
Visible Light ◽  
Carbon Nitride ◽  
Visible Light Photocatalytic Activity ◽  
Visible Light Photocatalytic

Here, g-C3N4 quantum dot (CNQDs)/Bi2MoO6 nanoheterostructures were successfully synthesized. The CNQDs/Bi2MoO6 nanocomposite exhibited enhanced photocatalytic activity.

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