INFLUENCE OF CaF2–4LiF ADDITIVE ON SINTERING AND ENERGY STORAGE PERFORMANCE OF SrTiO3 CERAMICS

2011 ◽  
Vol 01 (02) ◽  
pp. 191-195
Author(s):  
YIQIU LI ◽  
HANXING LIU ◽  
GUANGHUI ZHAO ◽  
JING XU ◽  
YUNJIANG CUI ◽  
...  

The CaF2–4LiF additive was added into SrTiO3 ceramics in order to decrease the sintering temperature for compact pulse power application. The crystalline structure, microstructure and energy storage performance of sintered ceramics were studied. Incorporating CaF2–4LiF additive to SrTiO3 ceramics contributes to a notably enhancement of the energy storage density. The great enhancement in energy storage density occurred due to the notable increase in breakdown strength and the refinement of microstructure. With 2 at% additive, the samples exhibited an average breakdown strength of 31.8 kV/mm, and an energy storage density of 1.212 J/cm3 which is about 1.4 times higher than pure SrTiO3 .

2010 ◽  
Vol 654-656 ◽  
pp. 2045-2048 ◽  
Author(s):  
Yi Qiu Li ◽  
Han Xing Liu ◽  
Zhong Hua Yao ◽  
Jing Xu ◽  
Yun Jiang Cui ◽  
...  

The energy storage density of (1-x) BaTiO3 – x Ba(Mg1/3Nb2/3)O3 (x = 0, 0.1, 0.2, 0.3) ceramics was investigated. The microstructure of samples was characterized by scanning electron microscopy (SEM). The energy storage density was calculated from the P-E hysteresis loops measured at room temperature. Experimental results show that the energy storage density of 0.9 BaTiO3 – 0.1 Ba(Mg1/3Nb2/3)O3 ceramics is highest among all compositions. At 15.8kV/mm electric field, the energy storage density of the sample can reach up to 1.07J/cm3, which is about 1.5 times higher than pure BaTiO3. The improvement of the energy density can be due to two factors: one is the improved breakdown strength caused by the optimized microstructure, the other is the decreased remnant polarization. This result indicates that bulk 0.9 BaTiO3 – 0.1 Ba(Mg1/3Nb2/3)O3 ceramic has advantages compared with pure BaTiO3 ceramic for energy storage applications, and with further improvements in microstructure and reduction of sintering temperature, could be a good candidate for energy storage capacitors.


2020 ◽  
Vol 842 ◽  
pp. 153-159
Author(s):  
Lei Cao ◽  
Ying Yuan ◽  
En Zhu Li ◽  
Shu Ren Zhang

In this work, a series of (1-x)Sr0.7Ba0.3Nb2O6-xSr0.7Bi0.2TiO3 ceramics were formulated by a phase-mixed sintering, the microstructure and energy storage performance were studied. The introduction of SBT induces the formation of equiaxed crystals leading to the denser microstructure, thus improving the dielectric breakdown strength. In addition, the enhancement of relaxor behavior improves the energy storage performance. For 0.94Sr0.7Ba0.3Nb2O6-0.06Sr0.7Bi0.2TiO3, an energy storage density of 0.49J/cm3 and an efficiency of 94.2% were achieved.


Author(s):  
Muhammad Qusyairie Saari ◽  
Julie Juliewatty Mohamed ◽  
Muhammad Azwadi Sulaiman ◽  
Mohd Fariz Abd Rahman ◽  
Zainal Arifin Ahmad ◽  
...  

2021 ◽  
pp. 2100116
Author(s):  
Qi‐Kun Feng ◽  
Jiang‐Bo Ping ◽  
Jing Zhu ◽  
Jia‐Yao Pei ◽  
Lei Huang ◽  
...  

2020 ◽  
pp. 002199832095188
Author(s):  
Xiaobao Zhang ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu

Overcoming sticky problems of large dielectric loss and poor breakdown strength ( Eb) is prerequisite of actual applications for high dielectric constant polymer composites. Herein, three kinds of multi-layer structure composites with different spatial structures (2MP-CE/CNT, CE/CNT-2MP-CE/CNT, MP-CE/CNT-MP) were prepared based on carbon nanotubes (CNTs), cyanate ester (CE) resin and mica paper (MP). Compared with traditional single-layer CE/CNT composite, multi-layer CE/CNT-2MP-CE/CNT composites, of which the middle layer is two pieces of MPs with a thickness of 60 µm, while both bottom and top layers are CE/CNT composite, simultaneously achieve 105 reduction in dielectric loss and 18.1 times increase in energy storage density ( Ue). Through modulating two sheets of MPs and CE/CNT as top and bottom layer, respectively, 2MP-CE/CNT composite with 60 μm MPs has the largest breakdown strength ( Eb), its Eb and Ue are severally about 7.1 and 19.5 times of those of CE/CNT composite. The relationship and mechanism between spatial structure and integrated performance such as dielectric properties, Eb and Ue of composites were systematically investigated. The attractive integrated performances of CE/CNT-2MP-CE/CNT and 2MP-CE/CNT composites are attributed to their unique composition and spatial structures, which bring special micro-capacitance and interfacial polarization, and thus leading to outstanding performances. Therefore, this investigation provides a strategy for getting desirable performances through building composites with specific spatial structure.


2019 ◽  
Vol 7 (39) ◽  
pp. 12127-12138 ◽  
Author(s):  
Feng Li ◽  
Xu Hou ◽  
Tianyu Li ◽  
Renjun Si ◽  
Chunchang Wang ◽  
...  

Fine-grain induced ultrahigh energy storage density and fast discharge speed in novel Bi0.5K0.5TiO3–Ba(Mg1/3Nb2/3)O3 ceramics via a hot-pressing strategy.


2017 ◽  
Vol 7 (1) ◽  
Author(s):  
Dou Zhang ◽  
Xuefan Zhou ◽  
James Roscow ◽  
Kechao Zhou ◽  
Lu Wang ◽  
...  

Abstract There is a growing need for high energy density capacitors in modern electric power supplies. The creation of nanocomposite systems based on one-dimensional nanofibers has shown great potential in achieving a high energy density since they can optimize the energy density by exploiting both the high permittivity of ceramic fillers and the high breakdown strength of the polymer matrix. In this paper, BaTiO3 nanofibers (NFs) with different aspect ratio were synthesized by a two-step hydrothermal method and the permittivity and energy storage of the P(VDF-HFP) nanocomposites were investigated. It is found that as the BaTiO3 NF aspect ratio and volume fraction increased the permittivity and maximum electric displacement of the nanocomposites increased, while the breakdown strength decreased. The nanocomposites with the highest aspect ratio BaTiO3 NFs exhibited the highest energy storage density at the same electric field. However, the nanocomposites with the lowest aspect ratio BaTiO3 NFs achieved the maximal energy storage density of 15.48 J/cm3 due to its higher breakdown strength. This contribution provides a potential route to prepare and tailor the properties of high energy density capacitor nanocomposites.


2017 ◽  
Vol 5 (12) ◽  
pp. 5920-5926 ◽  
Author(s):  
Hao Pan ◽  
Yi Zeng ◽  
Yang Shen ◽  
Yuan-Hua Lin ◽  
Jing Ma ◽  
...  

We report ultrahigh energy storage density of 51 J cm−3 and good fatigue & thermal stability of BiFeO3-based lead-free dielectric films.


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