Theoretical Relation between Polytype Energetics and Effective Atomistic Interaction Based on Interlayer Partial Energy Model

2021 ◽  
Vol MA2021-02 (58) ◽  
pp. 1721-1721
Author(s):  
Shinya Ogane ◽  
Riku Sato ◽  
Taku Miyakawa ◽  
Yuta Tanaka ◽  
Kazumasa Tsutsui ◽  
...  
Keyword(s):  
Energy Model ◽  
Theoretical Relation ◽  
Partial Energy

Hydrogen Atom Transfer Reaction Free Energy as a Predictor of Abiotic Nitroaromatic Reduction Rate Constants: A Comprehensive Analysis

2019 ◽  
Author(s):  
Dominic Di Toro ◽  
Kevin P. Hickey ◽  
Herbert E. Allen ◽  
Richard F. Carbonaro ◽  
Pei C. Chiu
Keyword(s):  
Free Energy ◽  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Energy Model ◽  
Second Order ◽  
Transfer Model ◽  
Atom Transfer ◽  
Order Rate ◽  
Linear Free Energy ◽  
Free Energy Model

<div>A linear free energy model is presented that predicts the second order rate constant for the abiotic reduction of nitroaromatic compounds (NACs). For this situation previously presented models use the one electron reduction potential of the NAC reaction. If such value is not available, it has been has been proposed that it could be computed directly or estimated from the electron affinity (EA). The model proposed herein uses the Gibbs free energy of the hydrogen atom transfer (HAT) as the parameter in the linear free energy model. Both models employ quantum chemical computations for the required thermodynamic parameters. The available and proposed models are compared using second order rate constants obtained from five investigations reported in the literature in which a variety of NACs were exposed to a variety of reductants. A comprehensive analysis utilizing all the NACs and reductants demonstrate that the computed hydrogen atom transfer model and the experimental one electron reduction potential model have similar root mean square errors and residual error probability distributions. In contrast, the model using the computed electron affinity has a more variable residual error distribution with a significant number of outliers. The results suggest that a linear free energy model utilizing computed hydrogen transfer reaction free energy produces a more reliable prediction of the NAC abiotic reduction second order rate constant than previously available methods. The advantages of the proposed hydrogen atom transfer model and its mechanistic implications are discussed as well.</div>

Mass transfer into the liquid in turbulent flow at high Schmidt numbers. Dissolution of benzoic acid into aqueous solutions of glycerol from internal surface of the pipe

1981 ◽  
Vol 46 (7) ◽  
pp. 1566-1576
Author(s):  
František Vašák ◽  
Václav Kolář ◽  
Zdeněk Brož
Keyword(s):  
Mass Transfer ◽  
Benzoic Acid ◽  
Aqueous Solutions ◽  
Cross Section ◽  
Circular Cross Section ◽  
Internal Surface ◽  
Theoretical Relation ◽  
Acid Dissolution ◽  
Schmidt Numbers ◽  
Unified Description

Theoretical relation derived in the last study for calculation of the mass transfer coefficient in the region of not fully developed concentration profile at high Schmidt numbers has been verified experimentally. This experimental study has been devoted to measurements of the rate of benzoic acid dissolution into aqueous solutions of glycerol from the internal surface of the pipe of circular cross section in the range 933 ⪬ Sc ⪬ 225 000 and 5 000 ⪬ Re ⪬ 50 000. It has been possible to explain on basis of the theoretical model, the differences between the data of various authors and to obtain a unified description of the phenomena.

scholarly journals Flyback Converter for Solid-State Lighting Applications with Partial Energy Processing

Electronics ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 60
Author(s):  
Mario Ponce-Silva ◽  
Daniel Salazar-Pérez ◽  
Oscar Miguel Rodríguez-Benítez ◽  
Luis Gerardo Vela-Valdés ◽  
Abraham Claudio-Sánchez ◽  
...  
Keyword(s):  
Solid State ◽  
Power Supply ◽  
Design Methodology ◽  
Low Frequency ◽  
Solid State Lighting ◽  
Voltage Source ◽  
Flyback Converter ◽  
Partial Energy ◽  
In Series ◽  
Energy Processing

The main contribution of this paper is to show a new AC/DC converter based on the rearrangement of the flyback converter. The proposed circuit only manages part of the energy and the rest is delivered directly from the source to the load. Therefore, with the new topology, the efficiency is increased, and the stress of the components is reduced. The rearrangement consist of the secondary of the flyback is placed in parallel with the load, and this arrangement is connected in series with the primary side and the rectified voltage source. The re-arranged flyback is only a reductive topology and with no magnetic isolation. It was studied as a power supply for LEDs. A low frequency averaged analysis (LFAA) was used to determine the behavior of the proposed circuit and an equivalent circuit much easier to analyze was obtained. To validate the theoretical analysis, a design methodology was developed for the re-arranged flyback converter. The designed circuit was implemented in a 10 W prototype. Experimental results showed that the converter has a THDi = 21.7% and a PF = 0.9686.

scholarly journals A Time Series Sustainability Assessment of a Partial Energy Portfolio Transition

Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 141
Author(s):  
Jacob Hale ◽  
Suzanna Long
Keyword(s):  
Time Series ◽  
Electricity Generation ◽  
Sustainability Assessment ◽  
Moving Average ◽  
Time Series Prediction ◽  
State Level ◽  
Autoregressive Integrated Moving Average ◽  
Energy Transitions ◽  
Univariate Time Series ◽  
Partial Energy

Energy portfolios are overwhelmingly dependent on fossil fuel resources that perpetuate the consequences associated with climate change. Therefore, it is imperative to transition to more renewable alternatives to limit further harm to the environment. This study presents a univariate time series prediction model that evaluates sustainability outcomes of partial energy transitions. Future electricity generation at the state-level is predicted using exponential smoothing and autoregressive integrated moving average (ARIMA). The best prediction results are then used as an input for a sustainability assessment of a proposed transition by calculating carbon, water, land, and cost footprints. Missouri, USA was selected as a model testbed due to its dependence on coal. Of the time series methods, ARIMA exhibited the best performance and was used to predict annual electricity generation over a 10-year period. The proposed transition consisted of a one-percent annual decrease of coal’s portfolio share to be replaced with an equal share of solar and wind supply. The sustainability outcomes of the transition demonstrate decreases in carbon and water footprints but increases in land and cost footprints. Decision makers can use the results presented here to better inform strategic provisioning of critical resources in the context of proposed energy transitions.

scholarly journals Simulation of Self-Consumption Photovoltaic Installations: Profitability Thresholds

2021 ◽  
Vol 11 (14) ◽  
pp. 6517
Author(s):  
Marta Varo-Martínez ◽  
Luis Manuel Fernández-Ahumada ◽  
Rafael López-Luque ◽  
José Ramírez-Faz
Keyword(s):  
Systematic Study ◽  
Peak Power ◽  
Net Present Value ◽  
Energy Model ◽  
Present Value ◽  
Lower Power ◽  
Design Variables ◽  
Sunshine Hours ◽  
Optimal Value ◽  
Renewable Technology

PV self-consumption can contribute positively to the spread of PV and, therefore, to the progress of renewable energies as a key element in a decarbonized energy model. However, the policies of each country regarding the promotion of this type of renewable technology is fundamental for their growth. Despite the high number of sunshine hours registered in Spain, self-consumption in this country has not been authorized until recently. In this new context, this work presents a systematic study of the profitability limits of a self-consumption PV installation under different conditions of installed peak power, orientation and inclination of the PV panels and level of obstruction of the installation. It was proved that, for the case of study (Córdoba, Spain), the maximum profitability was achieved for PV panels oriented to the south and with an inclination of 15° whereas the most unfavourable conditions are those of PV panels with an orientation and inclination of 180° and 90°, respectively. Furthermore, when the level of obstruction increases the maximum of the Net Present Value of self-consumptions PV installations decreases and this optimal value is achieved for installations with lower power. Finally, empirical adjustment equations have been developed to estimate the profitability parameters of self-consumptions PV installations as a function of their design variables.

A Holistic Energy Model for Drones

2020 ◽  
Author(s):  
Umut Can Cabuk ◽  
Mustafa Tosun ◽  
Rune Hylsberg Jacobsen ◽  
Orhan Dagdeviren
Keyword(s):  
Energy Model
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