scholarly journals (ECS 236th) Particle Size and Morphology of Carbon Dioxide Reduction Electrocatalysts Fabricated by Pulse/Pulse-Reverse Electrodeposition

2020 ◽  
Author(s):  
Brian Skinn ◽  
McLain Leonard ◽  
DAN WANG ◽  
Fikile R. Brushett
Keyword(s):  
Carbon Dioxide ◽  
Particle Size ◽  
Formic Acid ◽  
Carbon Dioxide Emissions ◽  
Aqueous Media ◽  
Value Added ◽  
Particle Morphology ◽  
Gas Diffusion ◽  
Metal Catalyst ◽  
Pulse Reverse

A variety of techniques for management of carbon dioxide emissions from power generation facilities and other industrial sites have been under active investigation for decades, in an effort to mitigate the environmental impacts of these releases. Once such approach is electrochemical reduction, which treats the waste CO2 as a source material for the production of value-added materials. Currently, the most promising form factor for this electrocatalytic application appears to be a stack-based system, where catalyst is immobilized on porous media that is interfaced with a liquid or solid electrolyte, and the reactant carbon dioxide is delivered to the active region by gaseous diffusion, which is orders of magnitude faster that diffusion though aqueous media. Various carbonaceous reduction products can be created depending on the composition, size, and microstructure of the catalyst particles, including formic acid/formate, carbon monoxide, alcohols, and hydrocarbons. In general, smaller catalyst particles, ideally in the nanoparticulate (<< 1 μm) range, tend to yield superior catalytic performance, due to a combination of factors such as a higher density of exposed grain boundaries and a higher fraction of exposed crystalline facets that are uncommon in particles of micron size or larger.This talk will survey recent work illustrating the ability of pulse/pulse-reverse electrodeposition processes to tune the size of particles applied to gas-diffusion electrode substrates, with a primary focus on two single-metal catalyst materials relevant to carbon dioxide electroreduction: tin and copper. The former is a catalyst primarily for formic acid production, while the latter is unique among single-metal catalysts as the only element known to date to produce significant amounts of hydrocarbons and/or alcohols. Particle morphology and representative particle size will be discussed as a function of pulsed electrodeposition waveform parameters, with the goal of highlighting overarching trends across the waveform space.

scholarly journals ENERGY-RELATED CARBON DIOXIDE EMISSIONS AND ENVIRONMENTAL EFFICIENCY IN THE EUROPEAN UNION AGRICULTURE: COMPARISON OF DIFFERENT BENCHMARKING TECHNIQUES

2016 ◽  
Vol 38 (3) ◽  
pp. 192-206 ◽  
Author(s):  
Tomas Baležentis ◽  
Daiva Makutėnienė
Keyword(s):  
Carbon Dioxide ◽  
European Union ◽  
Carbon Dioxide Emissions ◽  
Carbon Dioxide Emission ◽  
Value Added ◽  
The European Union ◽  
Undesirable Output ◽  
Energy Technologies ◽  
Desirable Output ◽  
Low Performance

The literature suggests different approaches towards modelling of the environmental impact caused by the production processes. The present paper attempts to establish a framework for multicriteria comparison of agricultural sectors of the European Union Member States and identify the performance gaps in terms of energy-related carbon dioxide emission. The research relies on the two approaches, viz. the by-production approach and the multi-criteria decision making approach. The environmental performance indicators were evaluated in regards to the desirable output (gross value added), inputs, and the undesirable output (carbon dioxide emission). The results indicate that Slovakia, Estonia, Lithuania, and Hungary should attempt to improve their carbon factors by implementing cleaner energy technologies. The combinations of by-production sub-indices suggest that productivity gains are more important for Sweden, Belgium, Poland, and France. Czech Republic, Latvia, and Finland are specific with low performance in terms of both the intended production and the undesirable output. The MCDM approach identified similar trends in performance as suggested by country ranking and correlation analysis.

scholarly journals Capture, Storage and Utilization of Carbon Dioxide by Microalgae and Production of Biomaterials

2021 ◽  
Vol 25 (1) ◽  
pp. 574-586
Author(s):  
Marta Bertolini ◽  
Fosca Conti
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Emissions ◽  
Carbon Capture ◽  
Extracellular Polymeric Substances ◽  
Incubation Temperature ◽  
Carbon Capture And Storage ◽  
Value Added ◽  
Culture Conditions ◽  
Transportation Systems ◽  
Operative Strategies

Abstract Carbon dioxide emissions are strongly related to climate change and increase of global temperature. Whilst a complete change in producing materials and energy and in traffic and transportation systems is already in progress and circular economy concepts are on working, Carbon Capture and Storage (CCS) and Carbon Capture and Utilisation (CCU) represent technically practicable operative strategies. Both technologies have main challenges related to high costs, so that further advanced research is required to obtain feasible options. In this article, the focus is mainly on CCU using microalgae that are able to use CO2 as building block for value-added products such as biofuels, EPS (Extracellular Polymeric Substances), biomaterials and electricity. The results of three strains (UTEX 90, CC 2656, and CC 1010) of the microalgal organism Chlamydomonas reinhardtii are discussed. The results about ideal culture conditions suggest incubation temperature of 30 °C, pH between 6.5 and 7.0, concentrations of acetate between 1.6 and 2.3 g L–1 and of ammonium chloride between 0.1 and 0.5 g L–1, the addition of glucose This green microalga is a valid model system to optimize the production of biomass, carbohydrates and lipids.

Social Impacts Due to Carbon Dioxide (CO2) Emissions. Evidence From Sub-Sahara African Countries (SSA) Compared to Southeast Asian Countries (ASEAN).

2021 ◽  
Author(s):  
Jean Baptiste Aboyitungiye ◽  
Suryanto Suryanto ◽  
Evi Gravitiani
Keyword(s):  
Carbon Dioxide ◽  
Co2 Emissions ◽  
Carbon Emissions ◽  
Carbon Dioxide Emissions ◽  
Explanatory Power ◽  
Value Added ◽  
Southeast Asian ◽  
Asian Countries ◽  
Asean Countries ◽  
Southeast Asian Countries

Abstract The recent climatic phenomena observed in developing countries since the 2000s have raised concerns, fears, and debates within the international community and economists. Human activities are largely responsible for atmospheric warming through their emissions of CO2 and polluting substances with dramatic consequences and numerous losses of human life in some countries. Using panel data covering the 2000-2016 period, this study investigated the social vulnerability due to the CO2 emissions through an empirical study of CO2’s determinants in selected countries of sub-Sahara African and Southeast Asian countries. The STIRPAT model gave out the result that; explanatories causes of carbon dioxide emissions are different in the two regions: the agriculture-forestry and fishing value-added, and human development index have a strong explanatory power on CO2 emissions in the ASEAN countries, the per-capita domestic product has a positive and significant influence on carbon emissions in the SSA countries, ceteris paribus, but was statistically insignificant in the ASEAN countries. The growing population decreases carbon emissions in the SSA selected countries while is not statically significant in the ASEAN countries. There is therefore a kind of double penalty: those who suffer, and will suffer the most from the impacts of climate change due to CO2 emissions, are those who contribute the least to the problem. These results provide insight into future strategies for the mitigation of climatic hazards already present in some places and potential for others which will be felt on different scales across the regions. Some of the inevitable redistributive effects of those risks can be corrected by providing financial support to the poorest populations hardest hit by natural disasters.

scholarly journals Synthesis of Sustainable Carbon Negative Eco-Industrial Parks

2021 ◽  
Vol 9 ◽  
Author(s):  
Elizabeth J. Abraham ◽  
Farah Ramadan ◽  
Dhabia M. Al-Mohannadi
Keyword(s):  
Carbon Dioxide ◽  
Circular Economy ◽  
Carbon Dioxide Emissions ◽  
Carbon Capture ◽  
Carbon Dioxide Emission ◽  
Value Added ◽  
Mixed Integer ◽  
Industrial Parks ◽  
And Storage

Growing climate change concerns in recent years have led to an increased need for carbon dioxide emission reduction. This can be achieved by implementing the concept of circular economy, which promotes the practice of resource conservation, emission minimization, and the maintenance of sustainable revenue streams. A considerable amount of carbon dioxide emissions is a consequence of stationary sources from industrial processes. These emissions can be reduced using carbon capture utilization and storage (CCUS) or reduced at source by using emission free renewable resources. The method developed within this work uses mixed integer linear programming (MILP) to design sustainable clusters that convert seawater (including waste brine), air, and waste carbon dioxide emissions to value-added products with sunlight as the main energy source. In this way, circular economy is employed to minimize fresh resource consumption and maximize material reuse. The potential of this work is demonstrated through a case study, which shows that an industrial park may be profitable while adhering to strict emission and material constraints.

scholarly journals Continuous Electrochemical Reduction of CO2 to Formate: Comparative Study of the Influence of the Electrode Configuration with Sn and Bi-Based Electrocatalysts

Molecules ◽  
2020 ◽  
Vol 25 (19) ◽  
pp. 4457 ◽  
Author(s):  
Guillermo Díaz-Sainz ◽  
Manuel Alvarez-Guerra ◽  
Angel Irabien
Keyword(s):  
Formic Acid ◽  
Raw Materials ◽  
Value Added ◽  
Gas Diffusion ◽  
Faradaic Efficiency ◽  
Co2 Electroreduction ◽  
Current Densities ◽  
Reduction Of Co2 ◽  
Value Added Products ◽  
Electrocatalytic Reduction Of Co2

Climate change has become one of the most important challenges in the 21st century, and the electroreduction of CO2 to value-added products has gained increasing importance in recent years. In this context, formic acid or formate are interesting products because they could be used as raw materials in several industries as well as promising fuels in fuel cells. Despite the great number of studies published in the field of the electrocatalytic reduction of CO2 to formic acid/formate working with electrocatalysts of different nature and electrode configurations, few of them are focused on the comparison of different electrocatalyst materials and electrode configurations. Therefore, this work aims at presenting a rigorous and comprehensive comparative assessment of different experimental data previously published after many years of research in different working electrode configurations and electrocatalysts in a continuous mode with a single pass of the inputs through the reactor. Thus, the behavior of the CO2 electroreduction to formate is compared operating with Sn and Bi-based materials under Gas Diffusion Electrodes (GDEs) and Catalyst Coated Membrane Electrodes (CCMEs) configurations. Considering the same electrocatalyst, the use of CCMEs improves the performance in terms of formate concentration and energy consumption. Nevertheless, higher formate rates can be achieved with GDEs because they allow operation at higher current densities of up to 300 mA·cm−2. Bi-based-GDEs outperformed Sn-GDEs in all the figures of merit considered. The comparison also highlights that in CCME configuration, the employ of Bi-based-electrodes enhanced the behavior of the process, increasing the formate concentration by 35% and the Faradaic efficiency by 11%.

Feedstock particle size and pyrolysis temperature regulate effects of biochar on soil nitrous oxide and carbon dioxide emissions

2021 ◽  
Vol 120 ◽  
pp. 33-40
Author(s):  
Bangliang Deng ◽  
Xi Yuan ◽  
Evan Siemann ◽  
Shuli Wang ◽  
Haifu Fang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Particle Size ◽  
Nitrous Oxide ◽  
Carbon Dioxide Emissions ◽  
Pyrolysis Temperature

scholarly journals (ECS 236th) Pulsed Electrodeposition of Carbon Dioxide Reduction Electrocatalysts for Space Applications

2020 ◽  
Author(s):  
Brian Skinn ◽  
Sujat Sen ◽  
McLain Leonard ◽  
DAN WANG ◽  
Fikile R. Brushett ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Formic Acid ◽  
Long Range ◽  
Life Support ◽  
Gas Diffusion ◽  
Space Applications ◽  
Co2 Electroreduction ◽  
Pulsed Electrodeposition

Space programs around the globe have begun to consider the logistical demands of missions beyond the orbital neighborhood of Earth. Unlike local installations such as the International Space Station, long-range missions will not have the option to resupply critical materials from Earth. Thus, the development of capabilities for what is often termed “In-Situ Resource Utilization” (ISRU) have been a continuing focus of research through NASA and other agencies. One particular long-range mission of interest is to place human astronauts on Mars; the major component of the thin Martian atmosphere is carbon dioxide, making CO2 a natural input to ISRU technologies for production of carbon-containing materials. Production of mission consumables from in-situ Mars resources will be critical to enabling human exploration of Mars, in part by minimizing the number and size of descent/ascent vehicles. Potential ISRU products from CO2 include that seem likely to provide significant mission benefits with minimal infrastructure required are propellants (e.g., hydrocarbons), fuel cell reactants (e.g., formic acid, methanol, carbon monoxide), and life support consumables (e.g., oxygen). The first portion of this talk will comprise a high-level overview of the chemical transformations that can be imparted to CO2 via electrocatalysis on gas-diffusion electrodes (GDEs), in the form of a summary of literature reports on the catalytic performance of a wide variety of single-metallic and metal-alloy systems. The remainder will encompass an exposition of the electrocatalytic performance of tin and copper single-metal GDE electrocatalysts prepared by pulsed electrodeposition. These metals are well known for their ability to reduce carbon dioxide to formic acid and hydrocarbons/carbon monoxide, respectively, and are under active development in numerous academic research groups and industrial entities to this end. These experimental results clearly demonstrate the power and flexibility of the pulse/pulse-reverse electrodeposition approach to catalyst fabrication, as evidenced by the appreciable effects of the pulsed-waveform electrodeposition parameters on CO2 electroreduction product distribution and total current density.

scholarly journals Analysis of the Nexus of CO2 Emissions, Economic Growth, Land under Cereal Crops and Agriculture Value-Added in Pakistan Using an ARDL Approach

Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4590 ◽  
Author(s):  
Ali ◽  
Liu ◽  
Shah ◽  
Tariq ◽  
Ali Chandio ◽  
...  
Keyword(s):  
Economic Growth ◽  
Carbon Dioxide ◽  
Gross Domestic Product ◽  
Carbon Dioxide Emissions ◽  
Value Added ◽  
Domestic Product ◽  
Series Data ◽  
Cereal Crops ◽  
Long Run ◽  
Integration Test

The present study attempts to explore the correlation between carbon dioxide emissions (CO2 e), gross domestic product (GDP), land under cereal crops (LCC) and agriculture value-added (AVA) in Pakistan. The study exploits time-series data from 1961 to 2014 and further applies descriptive statistical analysis, unit root test, Johansen co-integration test, autoregressive distributed lag (ARDL) model and pairwise Granger causality test. The study employes augmented Dickey–Fuller (ADF) and Phillips–Perron (PP) tests to check the stationarity of the variables. The results of the analysis reveal that there is both short- and long-run association between agricultural production, economic growth and carbon dioxide emissions in the country. The long-run results estimate that there is a positive and insignificant association between carbon dioxide emissions, land under cereal crops, and agriculture value-added. The results of the short-run analysis point out that there is a negative and statistically insignificant association between carbon dioxide emissions and gross domestic product. It is very important for the Government of Pakistan’s policymakers to build up agricultural policies, strategies and planning in order to reduce carbon dioxide emissions. Consequently, the country should promote environmentally friendly agricultural practices in order to strengthen its efforts to achieve sustainable agriculture.

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