The Application of Radioisotope Nondispersive X-Ray Spectrometry to the Analysis of Molybdenum

1967 ◽  
Vol 11 ◽  
pp. 275-286
Author(s):  
A. P. Langheinrich ◽  
J. W. Forster
Keyword(s):  
Solid State ◽  
Analytical Data ◽  
Pulse Height ◽  
Industrial Applications ◽  
X Ray ◽  
Pulse Height Analysis ◽  
State Detection ◽  
Plant Control

AbstractRadioisotope excitation, solid-state detection, and multichannel pulse-height analysis have been applied successfully to the determination of molybdenum in copper and molybdenum-process intermediates. Analytical data are presented, and comparisons are made with the conventional X-ray fluorescence approach. The equipment performed satisfactorily in molybdenum plant control and shows promise for other industrial applications with the development of suitable isotope sources.

A new soft x-ray pulse height analysis array in the HL-2A tokamak

2009 ◽  
Vol 80 (12) ◽  
pp. 126104 ◽  
Author(s):  
Y. P. Zhang ◽  
Yi Liu ◽  
J. W. Yang ◽  
X. Y. Song ◽  
M. Liao ◽  
...  
Keyword(s):  
Pulse Height ◽  
X Ray ◽  
Pulse Height Analysis

scholarly journals Chemical Bonding and the Sulfur K X-Ray Spectrum

1965 ◽  
Vol 9 ◽  
pp. 354-364 ◽  
Author(s):  
D. W. Wilbur ◽  
J. W. Gofman
Keyword(s):  
Electronic Structure ◽  
Single Crystal ◽  
Organic Compounds ◽  
Sulfur Atom ◽  
Chemical Bonding ◽  
Proportional Counter ◽  
Pulse Height ◽  
X Ray ◽  
Pulse Height Analysis ◽  
Chemical States

AbstractAn investigation has been made of the relative Kβ intensities in different chemical states of the sulfur atom using the Kα lines, with appropriate corrections, to provide the intensity standards. Both inorganic and organic compounds were included in the study. The data for each compound appear to be reliable to about ± 0.5%, while the whole series of compounds shows a variation greater than 20% in the corrected Kβ/Kα ratios. Energies were also measured, particularly the Kα energies, and their shifts were studied relative to the Kβ, intensity shifts. The work was done with a plane, single-crystal, helium-path spectrometer with proportional counter and pulse-height analysis for detection. The results are indicative of the usefulness of the method both in clarifying an uncertain chemical state and in studying the electronic structure of the bonded atom.

Pulse-Height Selection in X-Ray Fluorescence

1960 ◽  
Vol 4 ◽  
pp. 370-381
Author(s):  
Kurt F.J. Heinrich
Keyword(s):  
Energy Levels ◽  
Pulse Height ◽  
Fluorescence Analysis ◽  
Higher Order ◽  
Pulse Height Analyzer ◽  
X Ray ◽  
Qualitative And Quantitative ◽  
Systematic Application ◽  
Pulse Height Analysis ◽  
Qualitative Work

AbstractPulse-height analysis is a valuable tool in X-ray fluorescence analysis, both for qualitative and quantitative purposes. The elimination of higher order interferences permits determinations that would otherwise be very difficult or impossible, The systematic application of pulse-height analysis in qualitative work greatly simplifies the interpretation of complex spectra. In certain cases one can apply nondispersive analysis, relying on the pulse-height analyzer alone for separating energy levels of X-ray photons. Technique and limitations of pulse-height analysis will be discussed.

Structural Properties of a Dimeric Phenylcyanamidocopper(I) Complex, [{Cu(PPh3)2(C6H5NCN)}2]

2000 ◽  
Vol 53 (12) ◽  
pp. 971 ◽  
Author(s):  
Eric W. Ainscough ◽  
Andrew M. Brodie ◽  
Peter C. Healy ◽  
Joyce M. Waters
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Structural Properties ◽  
Structure Determination ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Cross Polarization ◽  
X Ray ◽  
Angle Spinning

The X-ray crystal structure determination of bis[-(phenylcyanamido)bis(triphenylphosphine)copper(I)], [{Cu(PPh3)2(C6H5NCN)}2], (1) is reported. The complex has a centrosymmetric dimeric structure with the phenylcyanamide ligands bridging the copper atoms in a -1,3-fashion. The structure is compared with that of the 4-methylphenylcyanamido complex, [{Cu(PPh3)2(4-MeC6H4NCN)}2] (2), and the differences observed in the Cu–P bond lengths compared with changes in the solid state 31P cross-polarization magic-angle spinning (CPMAS) spectra of the two complexes.

NMR Spectroscopy of Tetra(propyn- 1-yl)silane in the Solid State and in Solution

2003 ◽  
Vol 58 (8) ◽  
pp. 809-812 ◽  
Author(s):  
Bernd Wrackmeyer ◽  
Oleg L. Tok ◽  
Amin Badshah
Keyword(s):  
Solid State ◽  
Bulk Material ◽  
Point Group ◽  
Coupling Constants ◽  
Data Set ◽  
Tin Compounds ◽  
X Ray ◽  
Nmr Data ◽  
Solid State Structures

The crystal structure of tetra(propyn-1-yl)silane, Si(C≡CMe)4 1, has revealed a completely asymmetric molecule (point group C1). Since this finding concerns a single crystal, the bulk material of 1 was studied by solid-state 29Si and 13C MAS NMR. This confirmed the result of the X-ray analysis, and by comparison with previous NMR measurements of the tin analogue 1(Sn) it is concluded that 1 and 1(Sn) must have very similar solid-state structures which are in contrast to those known for other tetra(alkyn-1-yl)silicon and -tin compounds. The NMR data set of 1 in solution was completed by determination of the magnitude of coupling constants 1J(13C,13C).

scholarly journals Exploiting the Synergy of Powder X-ray Diffraction and Solid-State NMR Spectroscopy in Structure Determination of Organic Molecular Solids

2013 ◽  
Vol 117 (23) ◽  
pp. 12258-12265 ◽  
Author(s):  
Dmytro V. Dudenko ◽  
P. Andrew Williams ◽  
Colan E. Hughes ◽  
Oleg N. Antzutkin ◽  
Sitaram P. Velaga ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Structure Determination ◽  
Solid State Nmr ◽  
Molecular Solids ◽  
X Ray Diffraction ◽  
X Ray ◽  
Solid State Nmr Spectroscopy

scholarly journals Metallation of Isatin (2,3-Indolinedione). X-Ray Structure and Solution Behavior of Bis(Isatinato)Mercury(II)

1995 ◽  
Vol 2 (2) ◽  
pp. 81-90 ◽  
Author(s):  
Angel Garcia-Raso ◽  
Juan J. Fiol ◽  
Elies Molins ◽  
Antonia M. Calafat ◽  
Patricia A. Marzilli ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Metal Complex ◽  
Bond Length ◽  
Spectral Data ◽  
Structure Determination ◽  
Monoclinic System ◽  
Heterocyclic Nitrogen ◽  
X Ray

The first X-ray structure of an isatin (2,3-indolinedione, isaH) metal complex, bis(isatinato)memury(II) (C16H8N2O4Hg) (1), was determined. (1) was obtained from the reaction of isaH with mercury(II) acetate in methanol. Analogously, treatment of sodium saccharinate and mercury(II) acetate in methanol yielded Hg(saccharinato)2•0.5CH3OH (3). (1) crystallizes in the monoclinic system, space group P21/a with a = 7.299(1) Å, b = 8.192(1) Å, c = 11.601(1) Å , β = 105.82(1)°, V = 667.4 Å3, Z = 2, Dcalc = 2.452 g cm−3, MoKα radiation(λ = 0.71073 Å), μ = 115.5 cm-1, F(000) = 460, 21(1) °C. The structure was refined on the basis of 2023 observed reflections to R= 0.044. The two deprotonated, non coplanar isa ligands are trans to each other in a head to tail orientation and bound to the Hg through the nitrogen in a linear N-Hg-N arrangement. The Hg atom is at the center of symmetry of the complex and displaced by 0.62 Å from the two planes of the isa ligands (τ Hg-N1-C2-O2= -16°). The Hg-N bond length is 2.015 Å. Noπ-aryl-memury(ll)-π-aryl stacking interaction was observed either in the solid state or in the solution state. The IR, electronic, and H1 and C13NMR spectral data of (1) and (3) suggest binding of the memury to the heterocyclic nitrogen, in agreement with the crystal structure determination of (1).

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