scholarly journals Vapor Pressure of Saturated Aqueous Solutions of Potassium Sulfate from 310 K to 345 K

2011 ◽  
Vol 2011 ◽  
pp. 1-4 ◽  
Author(s):  
Matias O. Maggiolo ◽  
Francisco J. Passamonti ◽  
Abel C. Chialvo

The experimental evaluation of the vapor pressure of saturated aqueous solutions of potassium sulfate was carried out in the range of temperatures 310 K≤T≤345 K. The experimental data were used to determine the corresponding values of the water activity in such solutions. The analytical expressions as a function of temperature of both, vapor pressure and water activity, were obtained from the correlation of the experimental results. The vapor pressure expression was also extrapolated to a different temperature range in order to make a comparison with the results obtained by other authors.

2011 ◽  
Vol 694 ◽  
pp. 309-314 ◽  
Author(s):  
Jiang Feng Lou ◽  
Rui Xiang Wang ◽  
Min Zhang

The saturated vapor pressures of R22 uniformly mixed with refrigeration oil and nano- refrigeration-oil were measured experimentally at a temperature range from 263 to 333K and mass fractions from 1 to 5%. The experimental results showed that the saturated vapor pressure of R22/KT56 mixture was lower than that of pure R22; the pressure deviation between them increased with a raising mass fraction of refrigeration oil and temperature. After adding nano-NiFe2O4 and nano-fullerene into KT56, the pressure deviation increased at the same mass fraction and temperature. A saturated vapor pressure correlation for R22 and refrigeration oil/nano-refrigeration-oil mixture was proposed, and the calculated values agreed with the experimental data within the deviation of ± 0.77%.


2017 ◽  
Vol 17 (3) ◽  
pp. 500 ◽  
Author(s):  
Rendra Panca Anugraha ◽  
Zul Akbar Andi Picunang ◽  
Annas Wiguno ◽  
Rizky Tetrisyanda ◽  
Kuswandi Kuswandi ◽  
...  

In this work, vapor pressure of binary systems for isooctane + ethanol, isooctane + n-butanol and ethanol + n-butanol and ternary system for isooctane + ethanol + n-butanol were measured in the temperature range from 313.15 to 318.15 K using the inclined ebulliometer. The experimental results showed that the existence of n-butanol in isooctane decreases the vapor pressure of mixture, while increasing n-butanol fraction in ternary isooctane-ethanol-n-butanol mixture decreased vapor pressure of mixture. Experimental data for binary systems studied were correlated with Wilson, NRTL and UNIQUAC models with average relative deviation (ARD) of 3.5%. The optimized binary parameter pairs obtained in this work were used to estimate the ternary system. The Wilson model gave the best performance for estimation of ternary system with ARD of 5.4%. All systems studied showed non-ideal solution with positive deviation from Raoult’s law.


1996 ◽  
Vol 61 (11) ◽  
pp. 1549-1562 ◽  
Author(s):  
Jan Balej

Up to now, there exist a quite wide temperature interval between 70 or 80 and 150 °C with no sufficiently reliable experimental data of mean activity coefficients for aqueous NaOH as well as KOH solutions. In order to fill this gap, it was tried to derive suitable correlation equations for this quantity in dependence on the molality (for NaOH in the range mNaOH = 2-25 mol kg-1, for KOH in the range mKOH = 2-18 mol kg-1) and temperature (in the range 0-200 °C for both kinds of solutions) on the basis of the available data of this quantity and with the use of the previously derived correlation equations for the water activity in aqueous solutions of NaOH and KOH under the same conditions. The comparison between the calculated and experimental data was discussed.


1983 ◽  
Vol 61 (2) ◽  
pp. 267-268 ◽  
Author(s):  
Victor Hugo Acevedo ◽  
Juana Albarracín De Morán ◽  
Leopoldo Armando Sales

The specific conductivities and pH values of copper sulphate solutions in water were measured in the temperature range from 10 °C to 50 °C. The data, previously corrected by hydrolysis, were analyzed by means of the Lee Wheaton theory.This fit, for the evaluation of Λ0, R, and KA parameters, is quite satisfactory up to a maximum concentration of 25 × 10−4 moldm−3 and the agreement between experimental data and the literature value for 25 °C is acceptable.


2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Viorel Feroiu ◽  
Dan Geana ◽  
Catinca Secuianu

Vapour � liquid equilibrium, thermodynamic and volumetric properties were predicted for three pure hydrofluorocarbons: difluoromethane (R32), pentafluoroethane (R125) and 1,1,1,2 � tetrafluoroethane (R134a) as well as for binary and ternary mixtures of these refrigerants. Three cubic equations of state GEOS3C, SRK (Soave � Redlich � Kwong) and PR (Peng � Robinson) were used. A wide comparison with literature experimental data was made. For the refrigerant mixtures, classical van der Waals mixing rules without interaction parameters were used. The GEOS3C equation, with three parameters estimated by matching several points on the saturation curve (vapor pressure and corresponding liquid volumes), compares favorably to other equations in literature, being simple enough for applications.


1993 ◽  
Vol 58 (8) ◽  
pp. 1848-1854 ◽  
Author(s):  
Miroslav Karel ◽  
Jaroslav Nývlt

The kinetics of the crystallization of potassium sulfate has been determined using the MSMPR technique. Values of the nucleation and crystal growth rates evaluated from the experimental data are compared with the corresponding literature data.


Sensors ◽  
2021 ◽  
Vol 21 (5) ◽  
pp. 1700
Author(s):  
Anca Mihaela Vasile (Dragan) ◽  
Alina Negut ◽  
Adrian Tache ◽  
Gheorghe Brezeanu

An EEPROM (electrically erasable programmable read-only memory) reprogrammable fuse for trimming a digital temperature sensor is designed in a 0.18-µm CMOS EEPROM. The fuse uses EEPROM memory cells, which allow multiple programming cycles by modifying the stored data on the digital trim codes applied to the thermal sensor. By reprogramming the fuse, the temperature sensor can be adjusted with an increased trim variation in order to achieve higher accuracy. Experimental results for the trimmed digital sensor showed a +1.5/−1.0 ℃ inaccuracy in the temperature range of −20 to 125 ℃ for 25 trimmed DTS samples at 1.8 V by one-point calibration. Furthermore, an average mean of 0.40 ℃ and a standard deviation of 0.70 ℃ temperature error were obtained in the same temperature range for power supply voltages from 1.7 to 1.9 V. Thus, the digital sensor exhibits similar performances for the entire power supply range of 1.7 to 3.6 V.


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