scholarly journals Inhibition Effect of Substituted Thiadiazoles on Corrosion Activity of N80 Steel in HCl Solution

2013 ◽  
Vol 2013 ◽  
pp. 1-14 ◽  
Author(s):  
M. Yadav ◽  
Sumit Kumar ◽  
Debasis Behera
Keyword(s):  
Weight Loss ◽  
Active Sites ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Effect Of Temperature ◽  
Inhibition Effect ◽  
N80 Steel ◽  
Weight Loss Method ◽  
Thiadiazole Derivatives

The inhibition effect of some prepared compounds, namely, thiadiazole derivatives, on N80 steel corrosion in 15% HCl solutions has been studied by using the weight loss, electrochemical polarization, and electrochemical impedance spectroscopy techniques. It was found that the inhibition efficiency of the thiadiazole derivatives, namely, 2-amino-5-(4-methoxyphenyl)-1,3,4-thiazole (AMPT), 2-amino-5-phenyl-1,3,4-thiazole (APT), and 2-amino-5-(4-chlorophenyl)-1,3,4-thiazole (ACPT), increases with the increase in concentration. Inhibition efficiency follows the order AMPT > APT > ACPT. The effect of temperature on the corrosion was investigated by the weight loss method, and some thermodynamic parameters were calculated. The inhibitive action may be attributed to the adsorption of inhibitor molecules on the active sites of the metal surface following Langmuir adsorption isotherm. Polarization measurements indicated that thiadiazole derivatives act as mixed-type corrosion inhibitor. The adsorption of thiadiazole derivatives on N80 surface exposed to inhibitor-containing solutions was confirmed using SEM and FT-IR spectra.

scholarly journals Some Thiophene Derivatives as Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid

2014 ◽  
Vol 2014 ◽  
pp. 1-15 ◽  
Author(s):  
A. S. Fouda ◽  
A. A. Attia ◽  
A. A. Negm
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Potentiodynamic Polarization ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Effect Of Temperature ◽  
Carbon Steel Surface ◽  
Weight Loss Method ◽  
Thiophene Derivatives

Corrosion inhibitive performance of some thiophene derivatives during the acidic corrosion of carbon steel surface in 1 M HCl was investigated by chemical technique (weight loss) and electrochemical techniques (potentiodynamic polarization, electrochemical frequency modulation, and electrochemical impedance spectroscopy). The effect of temperature on the corrosion rate was investigated by the weight loss method, and some thermodynamic parameters for corrosion and adsorption processes were determined and discussed. The results show that the inhibition efficiency increased with the increase in inhibitor concentration and temperature. The adsorption of thiophene derivatives on the carbon steel surface obeys Langmuir adsorption isotherm. The obtained results indicated that the investigated compounds are chemically adsorbed on the steel surface. Potentiodynamic polarization studies showed that these compounds are mixed-type inhibitors and the results obtained from the techniques are in good agreement.

Inhibition effect of E and Z conformations of 2-pyridinealdazine on mild steel corrosion in phosphoric acid

2017 ◽  
Vol 64 (1) ◽  
pp. 23-35 ◽  
Author(s):  
Mohammed Elalaoui Belghiti ◽  
Ayssar Nahlé ◽  
Abdeslam Ansari ◽  
Yasser Karzazi ◽  
S. Tighadouini ◽  
...  
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Content Type ◽  
Inhibition Effect ◽  
Tafel Polarization ◽  
Mild Steel Corrosion

Purpose This paper aims to study the inhibition effect of 2-pyridinealdazine on the corrosion of mild steel in an acidic medium. The inhibition effect was studied using weight loss, electrochemical impedance spectroscopy, and Tafel polarization measurements. Design/methodology/approach Weight loss measurements, potentiodynamic tests, electrochemical impedance spectroscopy, X-ray diffraction and spectral and conformational isomers analysis of A (E-PAA) and B (Z-PAA) were performed were investigated. Findings 2-pyridinealdazine (PAA) acts as a good inhibitor for the corrosion of steel in 2.0 M H3PO4. The inhibition efficiency increases with an increase in inhibitor concentration but decreases with an increase in temperature. Originality/value This paper is intended to be added to the family of azines which are highly efficient inhibitors and can be used in the area of corrosion prevention and control.

scholarly journals Inhibitory Mechanism of Carbon Steel Corrosion in Sea Water by an Aqueous Extract of Henna Leaves

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
V. Johnsirani ◽  
J. Sathiyabama ◽  
Susai Rajendran ◽  
A. Suriya Prabha
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Metal Surface ◽  
Aqueous Extract ◽  
Inhibition Efficiency ◽  
Sea Water ◽  
Steel Corrosion ◽  
Protective Film ◽  
Weight Loss Method ◽  
Ac Impedance Spectra

The inhibition efficiency (IE) of an aqueous extract of henna leaves in controlling corrosion of carbon steel in seawater has been evaluated by weight-loss method. The weight loss study reveals that the formulation consisting of 8 mL of henna extract (HE) and 25 ppm of Zn2+ has 94% inhibition efficiency in controlling corrosion of carbon steel in sea water. Polarization study reveals that HE and Zn2+ system functions as mixed type inhibitor. AC impedance spectra reveal that protective film is formed on the metal surface. The nature of the metal surface has been analysed by FTIR spectra, SEM, and AFM analysis.

scholarly journals CHAETOMORPHA ANTENNIA EXTRACT AS A GREEN INHIBITOR FOR CORROSION OF BRASS IN 0.1 N PHOSPHORIC ACID SOLUTION

2015 ◽  
Vol 12 (1) ◽  
pp. 68-78 ◽  
Author(s):  
R Kumar ◽  
V Chandrasekaran
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Phosphoric Acid ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Weight Loss Method ◽  
Brass Surface ◽  
Loss Method ◽  
Spectroscopy Studies

The effect of marine algae Chaetomorpha antennia extract on corrosion inhibition of brass in phosphoric acid was investigated by weight-loss method, potentiodynamic polarization and electrochemical impedance spectroscopy studies. The inhibition efficiency is found to increase with increasing concentration of extract and decreases with rise in temperature. The activation energy, thermodynamic parameters (free energy, enthalpy and entropy change) and kinetic parameters (rate constant and half-life) for inhibition process were calculated. These thermodynamic and kinetic parameters indicate a strong interaction between the inhibitor and the brass surface. The inhibition is assumed to occur via adsorption of inhibitor molecules on the brass surface, which obeys Temkin adsorption isotherm. The adsorption of inhibitor on the brass surface is exothermic, physical, and spontaneous, follows first order kinetics. The polarization measurements showed that the inhibitor behaves as a mixed type inhibitor and the higher inhibition surface coverage on the brass was predicted. Inhibition efficiency values were found to show good trend with weight-loss method, potentiodynamic polarization and electrochemical impedance spectroscopy studies. SEM was carried out to ascertain the inhibitive nature of the algal extract on the brass surface.

The study of thiadiazole derivatives as potential corrosion inhibitors of low-carbon steel in hydrochloric acid

2021 ◽  
Vol 103 (3) ◽  
pp. 93-102
Author(s):  
M.D. Plotnikova ◽  
◽  
A.B. Shein ◽  
M.G. Shcherban` ◽  
A.D. Solovyev ◽  
...  
Keyword(s):  
Weight Loss ◽  
Acetic Acid ◽  
Corrosion Inhibitors ◽  
Acid Corrosion ◽  
Low Carbon Steel ◽  
Corrosion Current ◽  
Low Carbon ◽  
Inhibition Effect ◽  
Weight Loss Method ◽  
Thiadiazole Derivatives

The inhibition effect of series of thiadiazole derivatives against the corrosion of mild steel in 15 % HCl was studied by weight-loss method and electrochemical measurements. The experiments were performed on steel St3 at 293 K, the exposure time of the samples in solution for weight-loss measurements was 24 h. Potentiodynamic polarization curves were obtained in a typical three electrode cell with the help of electrochemical measuring complex SOLARTRON 1280 C. A scan rate was 1 mV⋅s-1 and a measurement point was taken every 0.2 s. 2-aminothiazole, 5-amino-1,3,4-thiadiazole-2-thiol, 2-amino-1,3,4-thiadiazole, 2-amino-5-(furan-2-yl)- 1,3,4-thiadiazole, 1,3,4-thiadiazole-2-ylamide of acetic acid were studied as potential inhibitors. The maximal inhibition efficiency was obtained at concentration 0.10-0.20 g⋅L−1. The best result was demonstrated by 5-amino-1,3,4-thiadiazole-2-thiol (inhibition effect was more than 90 %). The minimal inhibition effect had 1,3,4-thiadiazole-2-ylamide acetic acid. The corrosion inhibition effect calculated from data of the corrosion current density and from the weight-loss measurements were in sufficiently good agreement. The effective activation energy of the corrosion of St3 increased significantly due the presence of the inhibitors (from 3.3 to 94.8 kJ⋅mol-1). The results point to promising of investigating of series of thiadiazole derivatives and inhibitory compositions based on thiadiazole as potential acid corrosion inhibitors.

EXPERIMENTAL AND QUANTUM STUDIES ON ADSORPTION AND CORROSION INHIBITION EFFECT OF IMIDAZOLE DERIVATIVES ON N80 STEEL IN HYDROCHLORIC ACID

2013 ◽  
Vol 20 (06) ◽  
pp. 1350057 ◽  
Author(s):  
M. YADAV ◽  
SUMIT KUMAR ◽  
DIPTI SHARMA ◽  
P. N. YADAV
Keyword(s):  
Weight Loss ◽  
Hydrochloric Acid ◽  
Molecular Orbital ◽  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Molecular Surface ◽  
Effect Of Temperature ◽  
Am1 Method ◽  
Inhibition Effect

The inhibition effect of synthesized N ′-(phenylmethylidene)-2-(2-methyl-1 H -benzimidazol-1-yl)acetohydrazides, N ′-(4-methylphenylmethylidene)-2-(2-methyl-1 H -benzimidazol-1-yl)acetohydrazides, and N ′-(4-methoxyphenylmethylidene)-2-(2-methyl-1 H -benzimidazol-1-yl)acetohydrazides on the corrosion behaviour of N 80 steel in 15% hydrochloric acid solution was investigated using weight loss, potentiostatic polarization and electrochemical impedance spectroscopy methods. The inhibition efficiency increased as the concentration of the inhibitors was increased. The effect of temperature on corrosion inhibition was investigated by weight loss method and thermodynamic parameters were calculated. Potentiodynamic polarization measurements show that all the three studied inhibitors act as mixed inhibitor. The adsorption of inhibitors on N 80 steel surface obeys Langmuir adsorption isotherm. The structure of inhibitors was optimized using semiemperical AM1 method. Theoretical parameters such as the highest occupied molecular orbital (E HOMO ), lowest unoccupied molecular orbital (E LUMO ) energy levels, energy gap (ΔE = E LUMO - E HOMO ), dipole moment (μ), global hardness (γ), softness (σ), binding energy, molecular surface area and the fraction of electrons transferred (ΔN) were calculated and the adsorption mechanism was discussed. Scanning electron microscopy was used to characterize the surface marphology of the N 80 steel.

Experimental and theoretical studies of hydralazine hydrochloride as corrosion inhibitor for mild steel in HCl acid medium

2015 ◽  
Vol 63 (1) ◽  
pp. 47-55 ◽  
Author(s):  
B.M. Prasanna ◽  
B.M. Praveen ◽  
Narayana Hebbar ◽  
T.V. Venkatesha
Keyword(s):  
Weight Loss ◽  
Adsorption Isotherm ◽  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Active Sites ◽  
Inhibition Efficiency ◽  
Content Type ◽  
Inhibition Effect ◽  
Different Temperatures ◽  
Hydralazine Hydrochloride

Purpose – The purpose of this paper is to investigate the inhibition effect of hydralazine hydrochloride as a corrosion inhibitor for mild steel in 1M HCl. The inhibition effect was studied at different temperatures, ranging from 303 to 333°K. Design/methodology/approach – The inhibition efficiency of hydralazine hydrochloride was analyzed using weight loss, Tafel polarization, electrochemical impedance spectroscopy and surface morphology methods. The effect of temperature on the corrosion behavior of mild steel in 1M HCl was studied and discussed using an adsorption isotherm and activation parameters. Findings – Weight loss, polarization and impedance showed that the inhibition efficiency increases with an increase in the concentration of hydralazine hydrochloride for mild steel in 1M HCl. The inhibitive action may be attributed to the adsorption of the inhibitor molecule on the active sites of the metal surface by the Langmuir adsorption isotherm. Polarization curves indicated that hydralazine hydrochloride acts as a mixed-type inhibitor. Scanning electron microscopy was performed on inhibited and uninhibited mild steel samples to characterize the surface. Thermodynamic parameter indicated that the adsorption of hydralazine hydrochloride is a spontaneous process and the adsorption occurs chemically. Originality/value – The inhibition effect of hydralazine hydrochloride for mild steel has been investigated at different temperatures, ranging from 303 to 333°K. Hydralazine hydrochloride was a good inhibitor at a higher temperature.

Study of N-1L Corrosion of Carbon Steel in Acidic Desulfurizer Performance

2014 ◽  
Vol 670-671 ◽  
pp. 37-40 ◽  
Author(s):  
Shi Dong Wang ◽  
Qiang Wang ◽  
Jing Li ◽  
Shu Liang Zang
Keyword(s):  
Weight Loss ◽  
Ionic Liquid ◽  
Polyethylene Glycol ◽  
Carbon Steel ◽  
Steel Corrosion ◽  
Inhibition Rate ◽  
Inhibition Effect ◽  
Steel Material ◽  
Weight Loss Method ◽  
Loss Method

This paper uses a metal hung weight loss method, acidic ionic liquid desulfurizer as the media, by adding different inhibitor (Polyethylene Glycol, SDBS, Functional ionic liquids), contrast to carbon steel corrosion in the absence of inhibitor, understanding of their respective inhibition effect. In the experiment, the carbon steel material, different kinds and concentrations of the inhibitor in the medium, the corrosion rate measured by weight loss method. Contrast to the blank experiment the inhibition rate can be calculated. The experiment proved that the inhibition effect of several inhibitor at room temperature, and calculate their respective optimal concentration. The experiment also investigated the compound of several corrosion inhibition synergies, confirm the good corrosion inhibiting effect of polyethylene Glycol and SDBS complex, the inhibition rate reached 69.2%.Excellent inhibition effect of the ionic liquid corrosion inhibitor and the inhibition rate reached 88.3%, showing a clear advantage.

scholarly journals L-Proline as a Green Corrosion Inhibitor in Aqueous Solutions for Carbon Steel

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Nisreen Faraj ◽  
Kareima A. Abdelghani ◽  
A.A. Idress ◽  
Dalal. M. Ibrahim
Keyword(s):  
Weight Loss ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Steel Corrosion ◽  
Adsorption Properties ◽  
Green Corrosion Inhibitor ◽  
Chemical Technique ◽  
Weight Loss Method ◽  
Loss Method ◽  
Temkin Adsorption Isotherm

The chemical technique was used to investigate the inhibition and adsorption properties of L-proline for steel corrosion (weight loss method). As the concentration of L-proline increased, the inhibition efficiency increased, but decreased as the temperature increased, according to the findings. The inhibitor’s adsorption to the steel surface has been shown to be random, involving both electrostatic and chemisorptions. The Temkin adsorption isotherm governs the adsorption of L-proline to the steel surface. Thermodynamic parameters have been determined in some cases.

Synergistic Inhibition Effect of Sodium Silicte and Phytic Acid for Carbon Steel in Neutral Salt Water

2011 ◽  
Vol 194-196 ◽  
pp. 134-138 ◽  
Author(s):  
Hong Yun Ma ◽  
Shou Zhi Yi ◽  
Qin Zhang
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Phytic Acid ◽  
Sodium Silicate ◽  
Inhibition Efficiency ◽  
Neutral Salt ◽  
Inhibition Effect ◽  
Tafel Polarization ◽  
Weight Loss Method ◽  
Loss Method

The inhibition effects of sodium silicate, phytic acid and their mixtures in 5% NaCl solutions have been investigated using weight loss method and Tafel polarization techniques. The surface morphology of carbon steel was obtained using scanning electron microscopy (SEM). The results show that the co-addition of 70 mg∙1-1sodium silicate and 5 g∙1-1phytic acid has the optimum inhibition efficiency (84.15%) and the lowest corrosion rate (0.13 g∙m-2∙h-1). Compared with their individual inhibition effects, the optimum inhibition efficiency of sodium silicate is 62.17% at 90 mg∙1-1and phytic acid is 80.05% at 15 g∙1-1, respectively. The results obtained from weight loss method and Tafel polarization curves are in good agreement. The results show the enhanced inhibition effect by the inhibitors mixtures.

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