scholarly journals Easy Access to Coumarin Derivatives Using Alumina Sulfuric Acid as an Efficient and Reusable Catalyst under Solvent-Free Conditions

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Ali Amoozadeh ◽  
Majid Ahmadzadeh ◽  
Eskandar Kolvari
Keyword(s):  
Sulfuric Acid ◽  
Condensation Reaction ◽  
Solvent Free ◽  
Easy Access ◽  
Reusable Catalyst ◽  
Coumarin Derivatives ◽  
Free Condition ◽  
Pechmann Condensation ◽  
Solvent Free Condition ◽  
Solvent Free Conditions

A new and efficient condition for the use of alumina sulfuric acid (ASA) as a heterogeneous catalyst in the Pechmann condensation reaction in solvent-free condition for the formation of coumarins has been reported.

scholarly journals Barium Dichloride as a Powerful and Inexpensive Catalyst for the Pechmann Condensation without Using Solvent

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Saeed Khodabakhshi
Keyword(s):  
Green Chemistry ◽  
Organic Solvents ◽  
Condensation Reaction ◽  
Reaction Times ◽  
Solvent Free ◽  
Coumarin Derivatives ◽  
Inexpensive Method ◽  
Keto Esters ◽  
Pechmann Condensation ◽  
Solvent Free Conditions

Various coumarin derivatives have been efficiently synthesized via barium dichloride-catalyzed Pechmann condensation reaction of various phenols and β-keto esters under solvent-free conditions. This novel and inexpensive method has advantages such as short reaction times, excellent product yields, and avoidance of organic solvents in agreement with green chemistry principles.

scholarly journals p-Sulfonic Acid Calix[4]arene as an Efficient Catalyst for One-Pot Synthesis of Pharmaceutically Significant Coumarin Derivatives under Solvent-Free Condition

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Hamed Tashakkorian ◽  
Moslem Mansour Lakouraj ◽  
Mona Rouhi
Keyword(s):  
Organic Compounds ◽  
Sulfonic Acid ◽  
Solvent Free ◽  
Environmentally Benign ◽  
Coumarin Derivatives ◽  
One Pot ◽  
Efficient Catalyst ◽  
Free Condition ◽  
Solvent Free Condition ◽  
Solvent Free Conditions

One-pot and efficient protocol for preparation of some potent pharmaceutically valuable coumarin derivatives under solvent-free condition via direct coupling using biologically nontoxic organocatalyst, calix[4]arene tetrasulfonic acid (CSA), was introduced. Calix[4]arene sulfonic acid has been incorporated lately as a magnificent and recyclable organocatalyst for the synthesis of some organic compounds. Nontoxicity, solvent-free conditions, good-to-excellent yields for pharmaceutically significant structures, and especially ease of catalyst recovery make this procedure valuable and environmentally benign.

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