scholarly journals Ion-Imprinted Polymer-Based Receptors for Sensitive and Selective Detection of Mercury Ions in Aqueous Environment

2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Maimoona Yasinzai ◽  
Ghulam Mustafa ◽  
Nazia Asghar ◽  
Ikram Ullah ◽  
Muhammad Zahid ◽  
...  
Keyword(s):  
Detection Limit ◽  
Metal Ions ◽  
Recognition System ◽  
Aqueous Environment ◽  
Mercury Ions ◽  
Polymeric Systems ◽  
Interdigital Electrodes ◽  
Ion Imprinted ◽  
Ion Imprinted Polymers ◽  
Efficient Recognition

Interdigital electrodes (IDE) coated with ion-imprinted polymers (IIP) as recognition materials have been tested for screening and ion quantification. For screening of receptors, three polymer systems based on styrene (Sty), N-vinylpyrrolidone (NVP), and Sty-co-NVP were examined to identify an efficient recognition system for mercury ions in an aqueous environment. Results showed that all these polymeric systems can detect analyte even in very low concentration, that is, 10 ppm. Ion-imprinted polystyrene system proved to be an ideal receptor for detecting mercury ions in solution with a detection limit of 2 ppm. The sensitivity of ion-imprinted copolymeric system was further enhanced by making its composite with graphene oxide, and estimated detection limit of composite system was around 1 ppm. Ion- imprinted Sty-co-NVP graphene composite-based sensor system exhibits 2 to 5 times higher sensor response towards templated analyte in comparison to other polymer-based sensor systems. Moreover, the composite-based sensor shows very low or negligible response to competing metal ions with similar or different oxidation states such as Zn, Mg, Na, and As metal ions.

scholarly journals Recent developments in materials used for the removal of metal ions from acid mine drainage

2021 ◽  
Vol 11 (2) ◽  
Author(s):  
Tebogo M. Mokgehle ◽  
Nikita T. Tavengwa
Keyword(s):  
Heavy Metal ◽  
Surface Water ◽  
Acid Mine Drainage ◽  
Metal Ions ◽  
Mine Drainage ◽  
Acid Mine ◽  
Adsorption Capacities ◽  
Ion Imprinted ◽  
Wide Range ◽  
Ion Imprinted Polymers

AbstractAcid mine drainage is the reaction of surface water with sub-surface water located on sulfur bearing rocks, resulting in sulfuric acid. These highly acidic conditions result in leaching of non-biodegradeable heavy metals from rock which then accumulate in flora, posing a significant environmental hazard. Hence, reliable, cost effective remediation techniques are continuously sought after by researchers. A range of materials were examined as adsorbents in the extraction of heavy metal ions from acid mine drainage (AMD). However, these materials generally have moderate to poor adsorption capacities. To address this problem, researchers have recently turned to nano-sized materials to enhance the surface area of the adsorbent when in contact with the heavy metal solution. Lately, there have been developments in studying the surface chemistry of nano-engineered materials during adsorption, which involved alterations in the physical and chemical make-up of nanomaterials. The resultant surface engineered nanomaterials have been proven to show rapid adsorption rates and remarkable adsorption capacities for removal of a wide range of heavy metal contaminants in AMD compared to the unmodified nanomaterials. A brief overview of zeolites as adsorbents and the developent of nanosorbents to modernly applied magnetic sorbents and ion imprinted polymers will be discussed. This work provides researchers with thorough insight into the adsorption mechanism and performance of nanosorbents, and finds common ground between the past, present and future of these versatile materials.

scholarly journals Sintesis dan Karakterisasi Poly (Anthranilic Acid-Co-Formaldehyde) untuk Adsorpsi Ion Pb(II)

ALCHEMY ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 15-25
Author(s):  
Siska Ela Kartika ◽  
Muhammad Bachri Amran
Keyword(s):  
United States ◽  
Metal Ions ◽  
Environmental Protection Agency ◽  
Anthranilic Acid ◽  
Protection Agency ◽  
Imprinted Polymers ◽  
Ion Imprinted ◽  
Ion Imprinted Polymers ◽  
The Matrix ◽  
Us Epa

 Besides having a positive impact, rapid industrial development also gives a negative impact in the form of industrial waste causing environmental pollution. Lead is one of the heavy metal ions that become a primary indicator of pollution according to the United States Environmental Protection Agency (US EPA). The determination of lead directly in environmental samples is often difficult because of the very low concentration of metal ions and the matrix interferences. Therefore, preconcentration techniques that can simplify the matrix are required. Ionic exchange resins, functionalized chelating resins, and ion imprinted polymers are mostly used to preconcentrate the trace elements. Poly (anthranilic acid-co-formaldehyde) is polymer synthesized by mixing anthranilic acid, formaldehyde, and HCl. The poly (anthranilic acid-co-formaldehyde) was characterized by FTIR and SEM analysis. Characterization results indicate that polymerization reaction has been formed indicated by the vibration of the CH2 bridge. Poly (anthranilic acid-co-formaldehyde) has a relatively smooth surface with pores. The batch method was applied. The maximum adsorption for Pb(II) ions was 16.37 mg/g at pH 5 with a contact time of 10 minutes. Keywords: poly (anthranilic acid-co-formaldehyde), adsorption, lead Selain memberikan dampak positif, perkembangan industri yang pesat juga dapat memberikan dampak negatif berupa limbah industri penyebab pencemaran lingkungan. Timbal merupakan salah satu ion logam berat yang menjadi indikator primer pencemaran menurut United States Environmental Protection Agency (US EPA). Penentuan konsentrasi timbal secara langsung dalam sampel lingkungan seringkali sulit dilakukan karena terdapat pada konsentrasi renik dengan matriks yang rumit. Oleh karena itu, teknik prakonsentrasi yang dapat menyederhanakan matriks sangat diperlukan. Resin penukar ion, resin pengkhelat, dan ion imprinted polymers banyak digunakan untuk prakonsentrasi unsur renik. Poly (anthranilic acid-co-formaldehyde) merupakan polimer yang disintesis dengan cara mencampurkan asam anthranilat, formaldehida, dan HCl. Karakterisasi poly (anthranilic acid-co-formaldehyde) telah dilakukan menggunakan FTIR dan SEM. Hasil karakterisasi mengindikasikan bahwa reaksi polimerisasi telah terbentuk yang ditunjukkan dengan adanya vibrasi CH2 bridge. Poly (anthranilic acid-co-formaldehyde) memiliki morfologi permukaan yang relatif halus dan berpori. Metode yang digunakan untuk mempelajari kemampuan adsorpsi adalah metode batch. Kapasitas adsorpsi poly (anthranilic acid-co-formaldehyde) terhadap ion Pb(II) adalah 16,37 mg/g pada pH 5 dengan waktu kontak 10 menit. Kata kunci: poly (anthranilic acid-co-formaldehyde), adsorpsi, timbal

scholarly journals Synthesis of Azobenzene-Based Ion-Imprinted Polymers for Selective Removal of Cobalt and Copper Ions from a Mixture of Metal Ions

2020 ◽  
Vol 6 (2) ◽  
pp. 190009-190009
Author(s):  
Tapan Kumar Biswas ◽  
Tapan Kumar Biswas ◽  
Mashitah Mohd Yusoff ◽  
Mohd Sani Sarjadi ◽  
Sazmal E ◽  
...  
Keyword(s):  
Metal Ions ◽  
Copper Ions ◽  
Selective Removal ◽  
Imprinted Polymers ◽  
Ion Imprinted ◽  
Ion Imprinted Polymers

Systematic study on the synthesis of novel ion-imprinted polymers based on rhodizonate for the highly selective removal of Pb(II)

2021 ◽  
Vol 159 ◽  
pp. 104805
Author(s):  
Flor de Liss Meza López ◽  
Sabir Khan ◽  
Matheus Augusto da Silva ◽  
José Anchieta Gomes Neto ◽  
Gino Picasso ◽  
...  
Keyword(s):  
Systematic Study ◽  
Selective Removal ◽  
Imprinted Polymers ◽  
Ion Imprinted ◽  
Ion Imprinted Polymers

Synthesis of N2, N6-bis(5-methylthiazol-2-yl)pyridine-2,6-dicarboxamide fluoroscent sensor for detection of Cu2+ and Ni2+ Ions

Drug Research ◽  
2021 ◽  
Author(s):  
Anuroop Kumar ◽  
Netrapal Singh ◽  
Mordhwaj Kumar ◽  
Uma Agarwal
Keyword(s):  
Spectral Analysis ◽  
Detection Limit ◽  
Metal Ions ◽  
1H Nmr Spectroscopy ◽  
Stoichiometric Ratio ◽  
Selective Detection ◽  
Ft Ir ◽  
Uv Visible ◽  
Complexes With Metal Ions ◽  
Competitive Ions

AbstractThis article reports an amide based Chemosensor used for selective detection of divalent Cu+2 and Ni+2 ions via Fluorescence turn off. The selective sensing ability of Chemosensor was investigated in presence of different metal ions Mg2+, Ag+, Fe2+, K+, Cu2+, Ni2+, Hg2+, Pb2+, Mn2+, Pd2+, Cd2+ and Mn3+ as competitive ions. The receptor i. e. Chemosensor formed complexes with metal ions in 1:1 stoichiometric ratio. The detection limit and binding constant calculated as 1.92×10–4 and 1.4×10–4 M and 2.16×103 M−1 and 3.09×103 M−1 for Cu2+ and Ni2+ions respectively. The complexes were characterized by UV/visible, FT-IR, 13C NMR and 1H NMR spectroscopy. Further the structure and Crystallinity were calculated by P-XRD spectral analysis. The crystallinity found to be 65.27 and 67.87% respectively

Selective Detection of Mercury Ions Based on Tin Oxide Quantum Dots: Performance and Fluorescence Enhancement Model

2021 ◽  
Author(s):  
Jianqiao Liu ◽  
Yu Bai ◽  
Jingcheng Shi ◽  
Qing Yu ◽  
Jifei Liu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Metal Ions ◽  
Tin Oxide ◽  
Fluorescent Probes ◽  
Fluorescence Enhancement ◽  
Selective Detection ◽  
Mercury Ions ◽  
Metal Ions Detection

The superiority of fluorescence-based method in the metal ions detection are well developed, however, the current quantum dots (QDs) fluorescent probes for mercury ions (Hg2+) still have many limitations, such...

scholarly journals Molecularly Imprinted Polymers for Removal of Metal Ions: An Alternative Treatment Method

Biomimetics ◽  
2018 ◽  
Vol 3 (4) ◽  
pp. 38 ◽  
Author(s):  
Özgecan Erdem ◽  
Yeşeren Saylan ◽  
Müge Andaç ◽  
Adil Denizli
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Membrane Filtration ◽  
Polymeric Materials ◽  
Treatment Method ◽  
Terrestrial Environment ◽  
Molecularly Imprinted ◽  
Metal Ion Removal ◽  
Ion Imprinted ◽  
Removal Of Metal Ions

Aquatic and terrestrial environment and human health have been seriously threatened with the release of metal-containing wastewater by the rapid growth in the industry. There are various methods which have been used for removal of ions from the environment, such as membrane filtration, ion exchange, membrane assisted liquid extraction and adsorption. As a sort of special innovation, a polymerization technique, namely molecular imprinting is carried out by specific identification for the target by mixing it with a functional monomer. After the polymerization occurred, the target ion can be removed with suitable methods. At the end of this process, specific cavities, namely binding sites, are able to recognize target ions selectively. However, the selectivity of the molecularly imprinted polymer is variable not only because of the type of ligand but also charge, size coordination number, and geometry of the target ion. In this review, metal ion-imprinted polymeric materials that can be applied for metal ion removal from different sources are discussed and exemplified briefly with different metal ions.

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