scholarly journals Characteristics and Applications of Sewage Sludge Biochar Modified by Ferrous Sulfate for Remediating Cr(VI)-Contaminated Soils

2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Yuan-Yuan Li ◽  
Ting-Ting Zhang ◽  
Zhi Ning ◽  
Jin-Hong Chen ◽  
Kirk Hatfield

Background. Soil contamination by hexavalent chromium is becoming a main environmental concern in China. This study developed a sewage sludge biochar modified by FeSO4 (CHBC) as a new reductant for Cr(VI)-contaminated soil. The effectiveness of CHBC-stabilized Cr(VI)-contaminated soil was investigated. Methods. Typical industrial Cr(VI)-contaminated soil in China was chosen as the medium. The total and Cr(VI) contents of the contaminated soil were 1014.6 and 973.5 mg/kg, respectively. The effectiveness of the Cr(VI)-contaminated soil stabilized by CHBC was investigated by the leaching test (US EPA method 1312), the simplified bioaccessibility extraction test (US EPA 2007 protocol and British Geological Survey), alkaline digestion (US EPA method 3060A), sequential extraction (BCR sequential extraction procedure), X-ray diffraction, and the risk assessment code test. Results. Results show that CHBC substantially reduced the leachability and Cr(VI) content of the contaminated soil. The leachability and content of Cr(VI) were lower than the thresholds of the Environmental Quality Standards of Soil in China for civil reuse and the China Environmental Quality Standards of surface water for civil use when the soil was stabilized with 10% dosage of CHBC. Conclusion. CHBC is highly efficient in stabilizing Cr(VI) and can effectively reduce the leachability and bioavailability of Cr in contaminated soil and thus feasible for stabilizing Cr(VI)-contaminated soil and shows potential for application in the field.

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Chen-Yao Chu ◽  
Tzu-Hsing Ko

Heavy metal-contaminated soils were leached with various acid reagents, and a series of treatments was assessed to understand soil fertility after acid leaching. Aqua regia digestion and a five-step sequential extraction procedure were applied to determine heavy metal distribution. The average total concentrations of Zn, Cd, Cu, and Pb for contaminated soil were 1334, 25, 263, and 525 mg·kg−1 based on the ICP/AES quantitative analysis. Other than Pb extracted by H2SO4, over 50% removal efficiency of other heavy metals was achieved. A five-step sequential extraction revealed that the bound-to-carbonate and bound-to-Fe-Mn oxides were the major forms of the heavy metals in the soil. The addition of organic manure considerably promoted soil fertility and increased soil pH after acid leaching. Seed germination experiments demonstrated that after acid leaching, the soil distinctly inhibited plant growth and the addition of manure enhanced seed germination rate from 35% to 84%. Furthermore, the procedure of soil turnover after acid leaching and manure addition greatly increased seed germination rate by 61% and shortened the initial germination time. Seed germination in untreated soil was superior to that in acid-leached soil, illustrating that the phytotoxic effect of acid leaching is more serious than that of heavy metals.


2012 ◽  
Vol 550-553 ◽  
pp. 2194-2197 ◽  
Author(s):  
Lian Bi Zhou ◽  
Qiang Wu ◽  
Guo Long Gao

For lead-zinc contaminated soil, the principles, characteristics and application of traditional soil remediation were summarized, such as solidification/stabilization, electromotive method, phytoremediation and biological methods. The feasibility of tartaric acid washing of soil contaminated by Pb and Zn was studied. It demonstrated that it is feasible to remediate the soil contaminated by Pb and Zn by tartaric acid washing. The content of Pb and Zn in the residual soil achieved the National Soil Environmental Quality Standards.


2010 ◽  
Vol 58 (spe3) ◽  
pp. 49-56
Author(s):  
Patrícia Ferreira Silvério ◽  
Cristina Gonçalves ◽  
Satie Taniguchi ◽  
Sylvia Niemeyer Pinheiro Lima

Technical evaluation of analytical data is of extreme relevance considering it can be used for comparisons with environmental quality standards and decision-making as related to the management of disposal of dredged sediments and the evaluation of salt and brackish water quality in accordance with CONAMA 357/05 Resolution. It is, therefore, essential that the project manager discusses the environmental agency's technical requirements with the laboratory contracted for the follow-up of the analysis underway and even with a view to possible re-analysis when anomalous data are identified. The main technical requirements are: (1) method quantitation limits (QLs) should fall below environmental standards; (2) analyses should be carried out in laboratories whose analytical scope is accredited by the National Institute of Metrology (INMETRO) or qualified or accepted by a licensing agency; (3) chain of custody should be provided in order to ensure sample traceability; (4) control charts should be provided to prove method performance; (5) certified reference material analysis or, if that is not available, matrix spike analysis, should be undertaken and (6) chromatograms should be included in the analytical report. Within this context and with a view to helping environmental managers in analytical report evaluation, this work has as objectives the discussion of the limitations of the application of SW 846 US EPA methods to marine samples, the consequences of having data based on method detection limits (MDL) and not sample quantitation limits (SQL), and present possible modifications of the principal method applied by laboratories in order to comply with environmental quality standards.


Biomolecules ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 448
Author(s):  
Mahrous Awad ◽  
Zhongzhen Liu ◽  
Milan Skalicky ◽  
Eldessoky S. Dessoky ◽  
Marian Brestic ◽  
...  

Heavy metals (HMs) toxicity represents a global problem depending on the soil environment’s geochemical forms. Biochar addition safely reduces HMs mobile forms, thus, reducing their toxicity to plants. While several studies have shown that biochar could significantly stabilize HMs in contaminated soils, the study of the relationship of soil properties to potential mechanisms still needs further clarification; hence the importance of assessing a naturally contaminated soil amended, in this case with Paulownia biochar (PB) and Bamboo biochar (BB) to fractionate Pb, Cd, Zn, and Cu using short sequential fractionation plans. The relationship of soil pH and organic matter and its effect on the redistribution of these metals were estimated. The results indicated that the acid-soluble metals decreased while the fraction bound to organic matter increased compared to untreated pots. The increase in the organic matter metal-bound was mostly at the expense of the decrease in the acid extractable and Fe/Mn bound ones. The highest application of PB increased the organically bound fraction of Pb, Cd, Zn, and Cu (62, 61, 34, and 61%, respectively), while the BB increased them (61, 49, 42, and 22%, respectively) over the control. Meanwhile, Fe/Mn oxides bound represents the large portion associated with zinc and copper. Concerning soil organic matter (SOM) and soil pH, as potential tools to reduce the risk of the target metals, a significant positive correlation was observed with acid-soluble extractable metal, while a negative correlation was obtained with organic matter-bound metal. The principal component analysis (PCA) shows that the total variance represents 89.7% for the TCPL-extractable and HMs forms and their relation to pH and SOM, which confirms the positive effect of the pH and SOM under PB and BB treatments on reducing the risk of the studied metals. The mobility and bioavailability of these metals and their geochemical forms widely varied according to pH, soil organic matter, biochar types, and application rates. As an environmentally friendly and economical material, biochar emphasizes its importance as a tool that makes the soil more suitable for safe cultivation in the short term and its long-term sustainability. This study proves that it reduces the mobility of HMs, their environmental risks and contributes to food safety. It also confirms that performing more controlled experiments, such as a pot, is a disciplined and effective way to assess the suitability of different types of biochar as soil modifications to restore HMs contaminated soil via controlling the mobilization of these minerals.


2020 ◽  
Vol 6 (1) ◽  
pp. 96
Author(s):  
FX Anjar Tri Laksono ◽  
Indra Permanajati ◽  
Rahmat Mualim

In Mohoni Village, East Petasia District, North Morowali Regency there are nickel mining activities that are carried out by PT. Asiamax Mining Indonesia. Several locations were mine out status. Hence, reclamation programs are made to improve environmental conditions before mining. One of these stages is water quality tests to ensure that the reclamation area is worthy to be a habitat for animals and plants. The purpose of this study is to find out the water quality in the reclamation area of the ex-nickel mining in Mohoni Village. The storet method is used to analyze water quality whose test parameters include pH, total suspanded solid (TSS), concentrations of copper (Cu), cadmium (Cd), zinc (Zn), lead (Pb), nickel (Ni), chromium valence 6, iron (Fe), manganese (Mn), and cobalt (Co) once every three months for a year.The quality water check results are compared with the environmental quality standards in accordance with law number 32 of 2009. Based on the average monitoring results show that the water quality is classified as moderately polluted. The conclusion from this study is that reclamation land might be not used as habitat for animals and plants because the availability of water is not suitable for consumption


2018 ◽  
Vol 143 ◽  
pp. 632-641 ◽  
Author(s):  
Pau Gimeno ◽  
Jo Severyns ◽  
Vicenç Acuña ◽  
Joaquim Comas ◽  
Lluís Corominas

Science ◽  
1972 ◽  
Vol 175 (4024) ◽  
pp. 836-836
Author(s):  
Charles F. Wurster

2004 ◽  
Vol 8 (4) ◽  
pp. 636-650 ◽  
Author(s):  
D. L. Snook ◽  
P. G. Whitehead

Abstract. A regional overview of the water quality and ecology of the River Lee catchment is presented. Specifically, data describing the chemical, microbiological and macrobiological water quality and fisheries communities have been analysed, based on a division into river, sewage treatment works, fish-farm, lake and industrial samples. Nutrient enrichment and the highest concentrations of metals and micro-organics were found in the urbanised, lower reaches of the Lee and in the Lee Navigation. Average annual concentrations of metals were generally within environmental quality standards although, on many occasions, concentrations of cadmium, copper, lead, mercury and zinc were in excess of the standards. Various organic substances (used as herbicides, fungicides, insecticides, chlorination by-products and industrial solvents) were widely detected in the Lee system. Concentrations of ten micro-organic substances were observed in excess of their environmental quality standards, though not in terms of annual averages. Sewage treatment works were the principal point source input of nutrients, metals and micro-organic determinands to the catchment. Diffuse nitrogen sources contributed approximately 60% and 27% of the in-stream load in the upper and lower Lee respectively, whereas approximately 60% and 20% of the in-stream phosphorus load was derived from diffuse sources in the upper and lower Lee. For metals, the most significant source was the urban runoff from North London. In reaches less affected by effluent discharges, diffuse runoff from urban and agricultural areas dominated trends. High microbiological content, observed in the River Lee particularly in urbanised reaches, was far in excess of the EC Bathing Water Directive standards. Water quality issues and degraded habitat in the lower reaches of the Lee has led to impoverished aquatic fauna but, within the mid-catchment reaches and upper agricultural tributaries, less nutrient enrichment and channel alteration has permitted more diverse aquatic fauna. Keywords: River Lee, River Thames, water quality, nutrients, metals, ecology, hydrology, diffuse and point source pollution


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