Synthesis and Electrochemical Properties of CuC2O4·xH2O and CuC2O4·xH2O/Carbon Nanotubes (CNTs) Anodes for Lithium-Ion Batteries

2020 ◽  
Vol 20 (3) ◽  
pp. 1740-1748
Author(s):  
Yi-Ni Hu ◽  
Zi-Han Lin ◽  
Fei-Xia Min ◽  
Fei Teng ◽  
Hui-Min Wu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Hydrothermal Process ◽  
Lithium Ion ◽  
X Ray Diffraction ◽  
Promising Candidate ◽  
X Ray ◽  
Discharge Capacities ◽  
A Current

Pure CuC2O4·xH2O and CuC2O4·xH2O/carbon nanotubes (CNTs) composites are synthesized by a low-temperature hydrothermal process. The structure and morphology of the products are analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TG) and Raman spectrum. The results demonstrate that the as-prepared CuC2O4·xH2O takes on a microsphere-like morphology, all CuC2O4·xH2O/CNTs nanocomposites are constructed by the intertwining of tabular CuC2O4·xH2O nanoparticles (NPs) and CNTs to form a tanglesome net. When evaluated as an anode materials for lithium ion batteries (LIBs), all CuC2O4·xH2O/CNTs electrodes possess higher reversible discharge capacities (more than 1000 mAh g-1) than the pure CuC2O4·xH2O, up to 200th cycle at a current density of 100 mA g-1. The results illustrate that the addition of CNTs can enhance the electrochemical performance of CuC2O4·xH2O. Overall, CuC2O4·xH2O/CNTs composite can be a promising candidate used as a promising anode for LIBs.

scholarly journals Fabrication of MoS2 Nanoflakes Supported on Carbon Nanotubes for High Performance Anode in Lithium-Ion Batteries (LIBs)

2019 ◽  
Vol 2019 ◽  
pp. 1-7
Author(s):  
T. Minh Nguyet Nguyen ◽  
Vinh-Dat Vuong ◽  
Mai Thanh Phong ◽  
Thang Van Le
Keyword(s):  
Carbon Nanotubes ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Lithium Ion ◽  
Interlayer Spacing ◽  
X Ray Diffraction ◽  
Multiwalled Carbon ◽  
X Ray ◽  
Functionalized Multiwalled Carbon Nanotubes ◽  
20 Nm

Molybdenum disulfide (MoS2), an inorganic-layered material similar to structure of graphite, was randomly dispersed onto the surface of functionalized multiwalled carbon nanotubes to synthesized nanocomposite MoS2/CNT. The as-obtained product was characterized via SEM, TEM, TGA, X-ray diffraction, and Raman spectroscopies. It was confirmed from XRD that MoS2 layers with interlayer spacing of 0.614 nm were successfully produced. TEM images and Raman spectra indicated a random distribution of 20 nm sized nanoflake MoS2 on the surface of MWNTs. The electrochemical performance of materials are expected to pave the way for the utilized anode material for lithium-ion batteries.

In-situ X-ray diffraction study on the structural evolutions of oxidized fluorophosphates as anode materials for lithium-ion batteries

2014 ◽  
Vol 40 (7) ◽  
pp. 9107-9120 ◽  
Author(s):  
Xiaoting Lin ◽  
Rui Ma ◽  
Lianyi Shao ◽  
Miao Shui ◽  
Kaiqiang Wu ◽  
...  
Keyword(s):  
Diffraction Study ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Lithium Ion ◽  
X Ray Diffraction ◽  
X Ray

Fabrication of Electrospun Si/Carbon Composite Nanofibers as Anodes Materials for Lithium-Ion Batteries

2012 ◽  
Vol 532-533 ◽  
pp. 92-96 ◽  
Author(s):  
Hui Min Huang ◽  
Zhu Chi Chen ◽  
Jie Yu
Keyword(s):  
Lithium Ion Batteries ◽  
Carbon Nanofibers ◽  
Anode Materials ◽  
Composite Nanofibers ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Carbon Composite ◽  
X Ray Diffraction ◽  
X Ray ◽  
Surface Oxides

Si/carbon nanofibers (Si/CNFs) composite used as the anode materials of lithium-ion battery have been prepared via electrospinning and calcinations treatment. Hydrofluoric acid is used to remove surface oxides of Si particles. SEM observation indicates that silicon particles are uniformly embedded in the carbon nanofibers. X-ray diffraction (XRD), energy dispersive x-ray spectroscopy (EDX) and Raman scattering have been used to analysis the composition and phase of the composite materials. The first reversible capacity of the Si/CNFs composite is 1004 mAh/g, and 390 mAh/g has been remained after 100 cycles. Such Si/CNFs composite could be a promising anode material in lithium ion batteries.

Study on the Bionic Preparation and Properties of TiO2 as Three-Dimensional Anode Materials for Lithium-Ion Batteries

2014 ◽  
Vol 875-877 ◽  
pp. 1507-1510
Author(s):  
Yi Ping Tang ◽  
Liang Hong ◽  
Yuan Chao Jin ◽  
Huan Le Zhang ◽  
Guo Qu Zheng
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
3D Structure ◽  
Three Dimensional ◽  
Lithium Ion ◽  
The Novel ◽  
X Ray Diffraction ◽  
X Ray ◽  
Butterfly Wings

In this paper, a novel bionic preparation of anode materials for lithium-ion batteries was reported. Butterfly wings were used as a template to prepare three-dimensional (3D) TiO2 anode materials. The final product of TiO2 anode materials maintained the 3D structure of butterfly wings perfectly. The morphology and crystal structure were studied by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM). The electrochemical performance was evaluated by galvanostatic chargedischarge tests. The results showed that the novel 3D porous structure is benefit to the high electrochemical performance

Ball-Milled Graphite-Tin Composite Anode Materials for Lithium-Ion Battery

2012 ◽  
Vol 736 ◽  
pp. 127-132
Author(s):  
Kuldeep Rana ◽  
Anjan Sil ◽  
Subrata Ray
Keyword(s):  
Lithium Ion Battery ◽  
Anode Materials ◽  
High Capacity ◽  
Lithium Ion ◽  
Composite Anode ◽  
X Ray Diffraction ◽  
Promising Alternative ◽  
X Ray ◽  
Initial Discharge ◽  
Lithium Ion Cell

Lithium alloying compounds as an anode materials have been a focused for high capacity lithium ion battery due to their highenergy capacity and safety characteristics. Here we report on the preparation of graphite-tin composite by using ball-milling in liquid media. The composite material has been characterized by scanning electron microscope, energy depressive X-ray spectroscopy, X-ray diffraction and Raman spectra. The lithium-ion cell made from graphite-tin composite presented initial discharge capacity of 1065 mAh/g and charge capacity 538 mAh/g, which becomes 528 mAh/g in the second cycle. The composite of graphite-tin with higher capacity compared to pristine graphite is a promising alternative anode material for lithium-ion battery.

Cu2O Nanoparticles and Multi-Branched Nanowires as Anodes for Lithium-Ion Batteries

NANO ◽  
2018 ◽  
Vol 13 (09) ◽  
pp. 1850103 ◽  
Author(s):  
Xu Chen ◽  
Chunxin Yu ◽  
Xiaojiao Guo ◽  
Qinsong Bi ◽  
Muhammad Sajjad ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Hydrothermal Process ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Discharge Process ◽  
Electrochemical Cycling ◽  
One Step ◽  
Cu2o Nanoparticles ◽  
Enhanced Electrochemical Performance

Novelty Cu2O multi-branched nanowires and nanoparticles with size ranging from [Formula: see text]15[Formula: see text]nm to [Formula: see text]60[Formula: see text]nm have been synthesized by one-step hydrothermal process. These Cu2O nanostructures when used as anode materials for lithium-ion batteries exhibit the excellent electrochemical cycling stability and reduced polarization during the repeated charge/discharge process. The specific capacity of the Cu2O nanoparticles, multi-branched nanowires and microscale are maintained at 201.2[Formula: see text]mAh/g, 259.6[Formula: see text]mAh/g and 127.4[Formula: see text]mAh/g, respectively, under the current density of 0.1[Formula: see text]A/g after 50 cycles. The enhanced electrochemical performance of the Cu2O nanostructures compared with microscale counterpart can be attributed to the larger contact area between active Cu2O nanostructures/electrolyte interface, shorter diffusion length of Li[Formula: see text] within nanostructures and the improved stress release upon lithiation/delithiation.

scholarly journals Shear-structure MoNb6O18 as New Anode for Lithium Ion Batteries

2021 ◽  
Author(s):  
Jialin Cheng ◽  
Fengqi Lu ◽  
Xiaojun Kuang
Keyword(s):  
Lithium Ion Batteries ◽  
Structural Stability ◽  
Anode Materials ◽  
Lithium Ion ◽  
Structural Features ◽  
Ion Transfer ◽  
Promising Candidate ◽  
Shear Structure

Owing to their high theoretical capacities, safety operate voltage, unique tunnel structural features for fast lithium ion transfer and structural stability, niobium-based oxides are regarded as promising candidate anode materials...

scholarly journals Superionic Solid Electrolyte Li7La3Zr2O12 Synthesis and Thermodynamics for Application in All-Solid-State Lithium-Ion Batteries

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 281
Author(s):  
Daniil Aleksandrov ◽  
Pavel Novikov ◽  
Anatoliy Popovich ◽  
Qingsheng Wang
Keyword(s):  
Free Energy ◽  
Solid State ◽  
Lithium Ion Batteries ◽  
Gibbs Free Energy ◽  
Thermodynamic Characteristics ◽  
Lithium Ion ◽  
Standard Enthalpy Of Formation ◽  
X Ray Diffraction ◽  
X Ray ◽  
Binary Compounds

Solid-state reaction was used for Li7La3Zr2O12 material synthesis from Li2CO3, La2O3 and ZrO2 powders. Phase investigation of Li7La3Zr2O12 was carried out by x-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) methods. The thermodynamic characteristics were investigated by calorimetry measurements. The molar heat capacity (Cp,m), the standard enthalpy of formation from binary compounds (ΔoxHLLZO) and from elements (ΔfHLLZO), entropy (S0298), the Gibbs free energy of the Li7La3Zr2O12 formation (∆f G0298) and the Gibbs free energy of the LLZO reaction with metallic Li (∆rGLLZO/Li) were determined. The corresponding values are Cp,m = 518.135 + 0.599 × T − 8.339 × T−2, (temperature range is 298–800 K), ΔoxHLLZO = −186.4 kJ·mol−1, ΔfHLLZO = −9327.65 ± 7.9 kJ·mol−1, S0298 = 362.3 J·mol−1·K−1, ∆f G0298 = −9435.6 kJ·mol−1, and ∆rGLLZO/Li = 8.2 kJ·mol−1, respectively. Thermodynamic performance shows the possibility of Li7La3Zr2O12 usage in lithium-ion batteries.

scholarly journals Electrochemical Behavior of NH4F-Pretreated Li1.25Ni0.20Fe0.13Co0.33Mn0.33O2 Cathodes for Lithium-ion Batteries

2020 ◽  
Vol 10 (3) ◽  
pp. 1021
Author(s):  
Yonglei Zheng ◽  
Yikai Li ◽  
He Wang ◽  
Siheng Chen ◽  
Xiangxin Guo ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrochemical Impedance ◽  
Lithium Ion ◽  
X Ray Diffraction ◽  
Capacity Retention ◽  
Hierarchical Microspheres ◽  
Electrochemical Cycling ◽  
Novel Method ◽  
Diffraction Patterns ◽  
Discharge Capacities

We report a novel method to fabricate lithium-ion batteries cathodes with the NH4F pretreatment. In this study, NH4F-pretreated Li1.25Ni0.20Fe0.13Co0.33Mn0.33O2 hollow nano-micro hierarchical microspheres were synthesized for use as cathode materials. The X-ray diffraction patterns of NH4F-pretreated Li1.25Ni0.20Co0.33Fe0.13Mn0.33O2 were analyzed with the RIETAN-FP software program, and the results showed that the samples possess a layered α-NaFeO2 structure. The effects of pretreatment with NH4F on the electrochemical performance of the pristine material were evaluated through charge/discharge cycling, the rate performance, and electrochemical impedance spectroscopy (EIS). Pretreatment with NH4F significantly improved the discharge capacities and coulombic efficiencies of Li1.25Ni0.20Co0.33Fe0.13Mn0.33O2 in the first cycle and during subsequent electrochemical cycling. The sample pretreated with an appropriate amount of NH4F (NFCM 90) showed the highest discharge capacity (209.1 mA h g−1) and capacity retention (85.2% for 50 cycles at 0.1 C). The EIS results showed that the resistance of the NFCM 90 sample (76.32 Ω) is lower than that of the pristine one (206.2 Ω).

Sign in / Sign up

Export Citation Format

Share Document