Effect of Structural Deficiencies on Bi-Ferroic Behaviors of Lead-Free Bi0.5 Na0.40K0.10TiO3 Films

2021 ◽  
Vol 21 (11) ◽  
pp. 5653-5658
Author(s):  
Ngo Due Quan ◽  
Nguyen Due Minh ◽  
Hoang Viet Hung
Keyword(s):  
Magnetic Properties ◽  
Annealing Time ◽  
Spin Coating ◽  
Applied Electric Field ◽  
Remnant Polarization ◽  
Oxygen Vacancies ◽  
Sol Gel ◽  
Lead Free ◽  
Ferroelectric Films ◽  
Si Substrates

Lead-free Bi0.5Na0.4K0.1TiO3 (BNKT) ferroelectric films on Pt/TI/SIO2/Si substrates were prepared via a sol-gel spin coating routine. The microstructures and multiferroic behaviors of the films were examined intimately as a function of the annealing time. A rise of annealing time enhanced the crystallization of the films via the perovskite structure. The multiferroic behavior, including simultaneously the magnetic and ferroelectric orders, was observed altogether the films. When the annealing time rose, ferroelectric and magnetic properties were found significantly increased. The remnant polarization (Pr), also as maximum polarization (Pm) respectively increased to the very best values of 11.5 µC/cm2 and 40.0 µC/cm2 under an applied electric field of 500 kV/cm. The saturated magnetization (Ms) of films increased to 2.3 emu/cm3 for the annealing time of 60 minutes. Oxygen vacancies, originating from the evaporation of metal ions during annealing at high temperatures are attributed to the explanation for ferromagnetism within the BNKT films.

Electrical Properties Optimization of Ba0.9Sr0.1TiO3 Thin Films Deposited by Sol-Gel

2011 ◽  
Vol 277 ◽  
pp. 1-10 ◽  
Author(s):  
D. Fasquelle ◽  
M. Mascot ◽  
J.C. Carru
Keyword(s):  
Thin Films ◽  
Dielectric Constant ◽  
Electrical Properties ◽  
Annealing Time ◽  
Remnant Polarization ◽  
Sol Gel ◽  
Si Substrates ◽  
Annealing Temperatures ◽  
Annealing Conditions ◽  
Average Size

This paper reports a study of Ba0.9Sr0.1TiO3films deposited on Pt/Ti/SiO2/Si substrates. The annealing temperatures were 750°C, 850°C and 950°C. An increase of the average size of grains was observed, from 60 nm at 750°C to 110 nm at 950°C, as well as an increase of the dielectric constant, remnant polarization and tunability. When the annealing time was decreased from 1 hour to 15 min, the dielectric constant and remnant polarization values have been increased. The optimized annealing conditions (950°C for 15 min) give the following results: εr= 780 and tgδ = 0.01 at 100 kHz, Pr = 13 µC/cm², Ec = 63 kV/cm and a tunability of 55%.

scholarly journals Oxygen Defect-Mediated Magnetism in Fe-C Codoped TiO2

2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Zhaorui Zou ◽  
Zhongpo Zhou ◽  
Haiying Wang ◽  
Meng Du
Keyword(s):  
Magnetic Properties ◽  
First Principles ◽  
Spin Coating ◽  
Room Temperature ◽  
Oxygen Vacancies ◽  
Room Temperature Ferromagnetism ◽  
Sol Gel ◽  
Experimental Results ◽  
Oxygen Defect ◽  
First Principles Calculations

The magnetic properties of the C doped and C-Fe codoped TiO2films fabricated by sol-gel and spin coating have been investigated combining experiments and first-principles calculations. All the samples exhibit the anatase crystal phase and the room temperature ferromagnetism. The values of the saturation magnetizations are in the order of Fe-C codoped TiO2> Fe-C codoped TiO2(annealed in O2) > C doped TiO2> C doped TiO2(annealed in O2). The calculated net moment values are in the order of Fe-C codoped TiO2> C doped TiO2with oxygen vacancies existing, in accord with the experimental results. The hybridization of Fe 3d, C 2p,and O 2p(nearest to the Fe defect) led to the spin split of Fe 3d, C 2p,and O 2pwhich contributed to the ferromagnetism.

Great enhancement of energy storage density and power density in BNBT/xBFO multilayer thin film hetero-structures

2018 ◽  
Vol 5 (9) ◽  
pp. 2300-2305 ◽  
Author(s):  
Pan Chen ◽  
Shuanghao Wu ◽  
Peng Li ◽  
Jiwei Zhai ◽  
Bo Shen
Keyword(s):  
Thin Film ◽  
Energy Storage ◽  
Spin Coating ◽  
Sol Gel ◽  
Lead Free ◽  
Energy Storage Density ◽  
Multilayer Thin Film ◽  
Storage Density ◽  
Si Substrates ◽  
Coating Method

Lead-free 0.94(Bi0.5Na0.5)0.94TiO3-0.06BaTiO3/BiFeO3 (abbreviated as BNBT/xBFO) multilayer thin film hetero-structures were deposited on Pt(111)/Ti/SiO2/Si substrates using a sol–gel/spin coating method.

Effects of Sputter-Deposited LaNiO3 Electrode on the Deposition and Properties of Ferroelectric Thin Films

1996 ◽  
Vol 433 ◽  
Author(s):  
T. B. Wu ◽  
J. M. Wu ◽  
C. M. Wu ◽  
M. J. Shyu ◽  
M. S. Chen ◽  
...  
Keyword(s):  
Thin Films ◽  
Magnetron Sputtering ◽  
Perovskite Phase ◽  
Sol Gel ◽  
Processing Condition ◽  
Fatigue Property ◽  
Rf Magnetron Sputtering ◽  
Ferroelectric Films ◽  
Si Substrates ◽  
Sputter Deposited

AbstractHighly (100)-textured thin film of metallic LaNiO3 (LNO) was grown on the Pt/Ti/SiO2/Si substrates by rf magnetron sputtering at ˜300°C, which was used as a bottom electrode to prepare highly (100)-textured ferroelectric films. Examples on the deposition of PbTiO3, (Pbl−xLax)TiO3, Pb(Zr0.53Ti0.47)O3, Pb[(Mg1/3Nb2/3)1−xTix]O3, and (Ba1−xSrx)TiO3 thin films by rf magnetron sputtering or sol-gel method are shown. A reduction of temperature for perovskite phase formation can be achieved, especially for those difficult to crystallize. The surface roughness of the ferroelectric films is also improved as compared to that of films deposited on conventional Pt electrode. Although the electrical properties of the ferroelectric films are affected by the out-diffusion of LNO when a higher temperature was used in the preparation of the films, under an appropriate processing condition, the highly (100)-textured films can have satisfactory electrical characteristics for application. Moreover, the polarization-fatigue property can be also improved by the use of LNO electrode.

Influence of Excess Potassium on Structural and Ferroelectric Properties of Lead-Free Bi0.5K0.5TiO3 Thin Films

2021 ◽  
Vol 21 (4) ◽  
pp. 2681-2686
Author(s):  
Nguyen Ngoc Minh ◽  
Bui Van Dan ◽  
Nguyen Duc Minh ◽  
Guus Rijnders ◽  
Ngo Duc Quan
Keyword(s):  
Thin Films ◽  
Chemical Solution Deposition ◽  
Single Phase ◽  
Ferroelectric Properties ◽  
Lead Free ◽  
Chemical Solution ◽  
Ferroelectric Films ◽  
Solution Deposition ◽  
Si Substrates ◽  
Excess Amount

Lead-free Bi0.5K0.5TiO3 (BKT) ferroelectric films were synthesized on Pt/Ti/SiO2/Si substrates via the chemical solution deposition. The influence of the excess potassium on the microstructures and the ferroelectric properties of the films was investigated in detail. The results showed that the BKT films have reached the well-crystallized state in the single-phase perovskite structure with 20 mol.% excess amount of potassium. For this film, the ferroelectric properties of the films were significantly enhanced. The remnant polarization (Pr) and maximum polarization (Pm) reached the highest values of 9.4 μC/cm2 and 32.2 μC/cm2, respectively, under the electric field of 400 kV/cm.

Influence of Bi3.15Nd0.85Ti3O12 Buffer Layer on Structure and Electrical Properties of Bi0.94Ce0.06Fe0.97Ti0.03O3 Thin Films

2014 ◽  
Vol 703 ◽  
pp. 51-55
Author(s):  
Jia Zeng ◽  
Ming Hua Tang ◽  
Zhen Hua Tang ◽  
Yong Guang Xiao ◽  
Long Peng ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Properties ◽  
Buffer Layer ◽  
Current Density ◽  
Coercive Field ◽  
Remnant Polarization ◽  
Sol Gel ◽  
Hysteresis Loops ◽  
Si Substrates ◽  
Sol Gel Process

Bi0.94Ce0.06Fe0.97Ti0.03O3 and Bi0.94Ce0.06Fe0.97Ti0.03O3/Bi3.15Nd0.85Ti3O12 double-layered thin films were fabricated via sol-gel process on Pt/Ti/SiO2/Si substrates. The influence of Bi3.15Nd0.85Ti3O12 buffer layer on microstructure and electrical properties of Bi0.94Ce0.06Fe0.97Ti0.03O3 thin films were investigated in detail. Well-saturated P-E hysteresis loops can be obtained in Bi0.94Ce0.06Fe0.97Ti0.03O3 films with Bi3.15Nd0.85Ti3O12 buffer. The remnant polarization (2Pr) of the double-layered thin films is 112 μC/cm2. The coercive field (2Ec) of double-layered films is 672 kV/cm, which is much lower than that of the Bi0.94Ce0.06Fe0.97Ti0.03O3 thin films. The leakage current density of Bi0.94Ce0.06Fe0.97Ti0.03O3/Bi3.15Nd0.85Ti3O12 double-layered thin films is 4.12×10-5 A/cm2.

Structural, Electrical and Magnetic Properties of Modified Bi1/2Na1/2TiO3 - Modified CFO Based Magnetostrictive (Co0.6Zn0.4Fe1.7Mn0.3O4) Particulate Nanocomposite

2017 ◽  
Vol 886 ◽  
pp. 13-16
Author(s):  
Mintu Tyagi ◽  
Vinod Kumar ◽  
Gurpreet Kaur ◽  
Puneet Sharma
Keyword(s):  
Magnetic Properties ◽  
Magnetic Measurements ◽  
Ferroelectric Properties ◽  
Sol Gel ◽  
Hysteresis Loops ◽  
Lead Free ◽  
Great Opportunity ◽  
Electrical And Magnetic Properties ◽  
Device Applications ◽  
Two Phases

Lead free Multiferroic composites that comprise Co0.6Zn0.4Fe1.7Mn0.3O4 (CZFMO) and 72.5(Bi1/2Na1/2TiO3)-22.5(Bi1/2K1/2TiO3)-5(BiMg1/2Ti1/2O3) (BNT-BNT-BMgT) were synthesized using sol-gel method and it’s structural, ferroelectric and magnetic properties were studied. The X-ray diffraction displayed the single phase formation of parent phases and the presence of two phases in the composites. The samples showed a well saturated polarization-electric field hysteresis loops. The remnant polarization and saturation polarization values are decreased with increasing ferrite content. Room temperature (RT) magnetic measurements show that composites are soft magnetic. The composite with x = 0.2, showed the enhanced magnetic and ferroelectric properties. Moreover, these ME composites provide a great opportunity as potential lead free systems for multifuntional device applications.

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