Iron Disulfide Cathode Material Incorporated in Highly Ordered Mesoporous Carbon for Rechargeable Lithium Ion Batteries

2020 ◽  
Vol 12 (9) ◽  
pp. 1265-1270
Author(s):  
Ying Liu ◽  
Jungwon Heo ◽  
Xueying Li ◽  
Yuanzheng Sun ◽  
Younki Lee ◽  
...  

A highly ordered mesoporous carbon@iron disulfide (CMK-5@FeS2) composite was prepared via an in-situ impregnation and sulfurization method. The CMK-5 matrix with excellent conductivity and high surface area not only formed a continuous conductive network to improve the performance of the CMK-5@FeS2 composite, but also provided sufficient space to buffer the volume changes during cycling. The CMK-5@FeS2 cell exhibited excellent electrochemical performance. After 80 cycles, the CMK-5@FeS2 cell showed the discharge capacities of 650 and 380 mAh g–1 at 2 C and 5 C, respectively. The excellent results show that CMK-5 with unique mesoporous structure can contribute to accelerating ion transfer in the electrode due to the easy accessibility of the electrolyte, which implies CMK-5@FeS2 composite could be a promising cathode active material for rechargeable lithium ion (Li-ion) batteries.

2014 ◽  
Vol 602-603 ◽  
pp. 300-303 ◽  
Author(s):  
Shu Ya Geng ◽  
Li Min Dong ◽  
Chen Wang ◽  
Tong Xiang Liang

Highly ordered mesoporous carbon (CMK-3) was fabricated for the adsorption of cobalt from aqueous solutions. With the high surface area of1112.7m2/g and pore size of 17.2 nm, its abundant mesopores were benefit for providing channels for liquid propagate. In order to improve the adsorption properties,CMK-3 was modified by hydroxylation and amination. Fourier transform infrared (FTIR) spectroscopy can be seen that the amino group was successfully grafted onto the CMK-3 with highly ordered mesoporous structure. The functionalized ordered mesoporous carbon (CMK-3-EDA) ,CMK-3 and CMK-3-OX were used as absents for the adsorption of Co (II) from aqueous solution. The results showed that CMK-3-EDA were more twice effective in adsorption of Co (II) compared to CMK-3, which indicated that CMK-3-EDA had great potential for the adsorption of Co (II).


2018 ◽  
Vol 268 ◽  
pp. 162-169 ◽  
Author(s):  
Yan Xiong ◽  
Dong Gu ◽  
Xiaohui Deng ◽  
Harun Tüysüz ◽  
Maurice van Gastel ◽  
...  

2013 ◽  
Vol 48 (22) ◽  
pp. 8003-8013 ◽  
Author(s):  
Pranav K. Tripathi ◽  
Mingxian Liu ◽  
Lihua Gan ◽  
Jiasheng Qian ◽  
Zijie Xu ◽  
...  

2016 ◽  
Vol 52 (41) ◽  
pp. 6829-6832 ◽  
Author(s):  
Juan Zheng ◽  
Kun Wang ◽  
Yeru Liang ◽  
Fang Zhu ◽  
Dingcai Wu ◽  
...  

High-surface-area ordered mesoporous carbon-coated fiber exhibits a large adsorption amount, fast mass transport and high sensitivity, presenting an attractive potential candidate for pollution enrichment and detection in environmental samples.


2020 ◽  
Vol 10 (7) ◽  
pp. 2057-2068 ◽  
Author(s):  
René Sachse ◽  
Denis Bernsmeier ◽  
Roman Schmack ◽  
Ines Häusler ◽  
Andreas Hertwig ◽  
...  

Ordered mesoporous carbon films with high surface area, good electrical conductivity and an improved distribution of NPs with tunable composition show high electrocatalytic activity in HER.


2013 ◽  
Vol 683 ◽  
pp. 484-487 ◽  
Author(s):  
Xiang Jing Zhang ◽  
Yuan Yuan Wang ◽  
Cong Hao ◽  
Peng Tao Wu ◽  
Zi Chao Jiang

Sulfonated ordered mesoporous carbon (SOMC) has been used as a new catalytic material in heterogeneous reactions for it can replace many conventional homogeneous acid catalysts. At present, it was obtained mainly through sulfonating the surface of mesoporous carbon by post-processing method, which contained relatively complex process and rigorous condition. In this work, SOMC was prepared directly via pre-processing method. The structure and morphology of SOMC were characterized by means of FT-IR, XRD, TEM and BET, the catalytic performance was investigated by the acetalization reaction between benzaldehyde and n-butyl alcohol as a model reaction. The result showed that SOMC has excellent high surface area and uniform mesostructure when the mole ratio of phenolic resin: sulfuric acid: F127 was 1: 2: 0.0238 and carbonization temperature was 600°C. In the acetalization reaction, the yield of acetal of using SOMC material as catalyst was 87.1%, much higher than that of using HY zeolite, which shows that the SOMC has excellent catalytic property in the catalytic reaction of acetalization.


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