Carbon Dioxide (CO2) Capture in Alkanolamines Impregnated Activated Carbon Developed from Date Stones

2021 ◽  
Vol 13 (1) ◽  
pp. 98-104
Author(s):  
Ayyaz Muhammad ◽  
Sami Ullah Rather ◽  
Muhammad Umar ◽  
Hisham Bamufleh ◽  
Arshid Mahmood Ali ◽  
...  

The concern to reduce global carbon emissions has significantly improved the development of efficient solid sorbents such as activated carbon (AC). In this study, AC is developed from date stones which is one of the abundantly found agricultural waste material in gulf region. The AC was completely characterized in terms of pore volume, surface area, stability test, volatile carbon and fixed carbon contents. Impregnation of AC was performed by three different alkanolamines, namely Diethylene triamine (DETA), Pentaethylene hexamine (PEHA) and Di-ethanol amine (DEA). The alkanolamine impregnated sorbents were utilized for CO2adsorption at temperatures of 25, 30, 40, 50, 60, 70 and 100 °C and carbon dioxide (CO2) concentrations of 10, 30, 50, 70 and 92% in helium. The adsorption phenomenon was evaluated by Langmuir isotherms for all the studied adsorbents. The AC developed from date stones provided high adsorption loading capacity of CO2 i.e., 89.79 mg/g of AC at 25 °C. Thermodynamic parameters showed that the adsorption was endothermic and spontaneous in nature. Moreover, desorption profiles reveal that DETA-AC samples provided most favorable characteristics with respect to the value of desorption constant.

2016 ◽  
Author(s):  
C. Frankenberg ◽  
S. S. Kulawik ◽  
S. Wofsy ◽  
F. Chevallier ◽  
B. Daube ◽  
...  

Abstract. In recent years, space-borne observations of atmospheric carbon-dioxide (CO2) have become increasingly used in global carbon-cycle studies. In order to obtain added value from space-borne measurements, they have to suffice stringent accuracy and precision requirements, with the latter being less crucial as it can be reduced by just enhanced sample size. Validation of CO2 column averaged dry air mole fractions (XCO2) heavily relies on measurements of the Total Carbon Column Observing Network TCCON. Owing to the sparseness of the network and the requirements imposed on space-based measurements, independent additional validation is highly valuable. Here, we use observations from the HIAPER Pole-to-Pole Observations (HIPPO) flights from January 2009 through September 2011 to validate CO2 measurements from satellites (GOSAT, TES, AIRS) and atmospheric inversion models (CarbonTracker CT2013B, MACC v13r1). We find that the atmospheric models capture the XCO2 variability observed in HIPPO flights very well, with correlation coefficients (r2) of 0.93 and 0.95 for CT2013B and MACC, respectively. Some larger discrepancies can be observed in profile comparisons at higher latitudes, esp. at 300 hPa during the peaks of either carbon uptake or release. These deviations can be up to 4 ppm and hint at misrepresentation of vertical transport. Comparisons with the GOSAT satellite are of comparable quality, with an r2 of 0.85, a mean bias μ of −0.06 ppm and a standard deviation σ of 0.45 ppm. TES exhibits an r2 of 0.75, μ of 0.34 ppm and σ of 1.13 ppm. For AIRS, we find an r2 of 0.37, μ of 1.11 ppm and σ of 1.46 ppm, with latitude-dependent biases. For these comparisons at least 6, 20 and 50 atmospheric soundings have been averaged for GOSAT, TES and AIRS, respectively. Overall, we find that GOSAT soundings over the remote pacific ocean mostly meet the stringent accuracy requirements of about 0.5 ppm for space-based CO2 observations.


2018 ◽  
Vol 190 (7) ◽  
pp. 1259-1282 ◽  
Author(s):  
Umi Fazara Md Ali ◽  
Nur Hidayah Azmi ◽  
Khairuddin Md Isa ◽  
Mohamed Kheireddine Aroua ◽  
Tan Ru Shien ◽  
...  

2021 ◽  
Author(s):  
Mikkel Bennedsen

Abstract Following the Paris Agreement of 2015, most countries have agreed to reduce their carbon dioxide (CO2) emissions according to individually set Nationally Determined Contributions. However, national CO2 emissions are reported by individual countries and cannot be directly measured or verified by third parties. Inherent weaknesses in the reporting methodology may misrepresent, typically an under-reporting of, the total national emissions. This paper applies the theory of sequential testing to design a statistical monitoring procedure that can be used to detect systematic under-reportings of CO2 emissions. Using simulations, we investigate how the proposed sequential testing procedure can be expected to work in practice. We find that, if emissions are reported faithfully, the test is correctly sized, while, if emissions are under-reported, detection time can be sufficiently fast to help inform the 5 yearly global "stocktake" of the Paris Agreement. We recommend the monitoring procedure be applied going forward as part of a larger portfolio of methods designed to verify future global CO2 emissions.


2021 ◽  
pp. 1-5
Author(s):  
HUYEN THU THI NONG ◽  
YUWALEE UNPAPROM ◽  
CHUDAPAK CHAICHOMPOO ◽  
RAMESHPRABU RAMARAJ

This study aims to examine the perspective of feedstock for producing biomethane from invasive aquatic weed water primroses (Ludwigia Hyssopifolia). The methane yield and methane content of biogas were analyzed and studied. The calculating methods of theoretical methane yield based on the elemental application or the theoretical chemical oxygen demand (COD) number were showed. The percentage of element chemicals, carbon (C), hydrogen (H), oxygen (O), nitrogen (N), and sulfur (S) of raw materials were analyzed, and results were 40.2%, 5.03%, 22.13%, 1.8% and 0.24%, respectively. The plant biomass was contained moisture content, volatile carbon, fixed carbon and ash were 7.28%, 63.07%, 1.28% and 28.37%, respectively. From the water primroses calculated yield of methane (CH4), carbon dioxide (CO2) and ammonia (NH3) results were 54.90%, 41.40% and 3.70%, respectively. Therefore, the aquatic weed water primroses biomass are suitable feedstock for biogas production as well as future scale-up studies.


2018 ◽  
Vol 1 (2) ◽  
pp. 1-8
Author(s):  
Dody Hidayat

Kebakaran dapat terjadi dimana saja salah satunya dapat terjadi di alat transportasi air yakni kapal. Kebakaran selalu menyebabkan hal-hal yang tidak diinginkan baik kerugian material maupun ancaman keselamatan jiwa manusia. Seiring dari kejadian tersebut musibah kecelakaan kapal yang disebabkan oleh bahaya kebakaran sangatlah mungkin terjadi. Salah satu yang dapat mencegah kejadian kebakaran pada kapal haruslah dapat mendeteksi dini kebakaran tersebut. Untuk mendeteksi dini terjadinya kebakaran dikapal maka dirancanglah sebuah alat proteksi kebakaran otomatisberbasis adruino. Dimana Arduino merupakan board yang memiliki sebuah mikrokontroller sebagai  otak kendali sistem. Sistem otomatisasi atau controller tidak akan terlepas dengan apa yang disebut  dengan ‘sensor’. Sensor adalah sebuah alat untuk mendeteksi atau mengukut sesuatu yang digunakan untuk mengubah variasi mekanis, magnetis, panas, sinar dan kimia menjadi tegangan dan arus listrik. sistem yang dirancang ini dilengkapi dengan beberapa sensor diantaranya adalah sensor apiUV-Tron R2868, sensor asap MQ-2 dan kemudian sensor suhuDS18B20. Mikrokontroller sebagai pengendali akan merespon input yang berupa sensor tersebut ketika data yang dibaca oleh sensor mendeteksikebakaran diantaranya mendeteksi adanya asap, kemudian api dan suhu. Sebagai output dari sistem berupa racun api (fire extinguisher)dimana kandungan yang ada pada racun api tersebut berupa Dry Chemical Powder dan Carbon Dioxide (CO2) yang fungsinya digunakan untuk memadamkan api serta dilengkapi buzzer sebagai alarm peringatan jika terjadi kebakaran. 


2012 ◽  
Author(s):  
William R. Howard ◽  
Brian Wong ◽  
Michelle Okolica ◽  
Kimberly S. Bynum ◽  
R. A. James

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