scholarly journals Grating Spectrometry and Spatial Heterodyne Fourier Transform Spectrometry: Comparative Noise Analysis for Raman Measurements

2020 ◽  
pp. 000370282095731
Author(s):  
Luca Ciaffoni ◽  
Pavel Matousek ◽  
William Parker ◽  
Elin A. McCormack ◽  
Hugh Mortimer

The desire for portable Raman spectrometers is continuously driving the development of novel spectrometer architectures where miniaturisation can be achieved without the penalty of a poorer detection performance. Spatial heterodyne spectrometers are emerging as potential candidates for challenging the dominance of traditional grating spectrometers, thanks to their larger etendue and greater potential for miniaturisation. This paper provides a generic analytical model for estimating and comparing the detection performance of Raman spectrometers based on grating spectrometer and spatial heterodyne spectrometer designs by deriving the analytical expressions for the performance estimator (signal-to-noise ratio, SNR) for both types of spectrometers. The analysis shows that, depending on the spectral characteristics of the Raman light and on the values of some instrument-specific parameters, the ratio of the SNR estimates for the two spectrometers ([Formula: see text]) can vary as much as by two orders of magnitude. Limit cases of these equations are presented for a subset of spectral regimes which are of practical importance in real-life applications of Raman spectroscopy. In particular, under the experimental conditions where the background signal is comparable or larger than the target Raman line and shot noise is the dominant noise contribution, the value of [Formula: see text] is, to a first order of approximation, dependent solely on the relative values of each spectrometer’s etendue and on the number of row pixels in the detector array. For typical values of the key instrument-specific parameters (e.g., etendue, number of pixels, spectral bandwidth), the analysis shows that spatial heterodyne spectrometer-based Raman spectrometers have the potential to compete with compact grating spectrometer designs for delivering in a much smaller footprint (10–30 times) levels of detection performance that are approximately only five to ten times poorer.

Author(s):  
M. Iwatsuki ◽  
Y. Kokubo ◽  
Y. Harada

On accout of its high brightness, small optical source size, and minimal energy spread, the field emission gun (FEG) has the advantage that it provides the conventional transmission electron microscope (TEM) with a highly coherent illumination system and directly improves the resolving power and signal-to-noise ratio of the scanning electron microscope (SEM). The FEG is generally classified into two types; the cold field emission (C-FEG) and thermal field emission gun (T-FEG). The former, in which a field emitter is used at the room temperature, was successfully developed as an electron source for the SEM. The latter, in which the emitter is heated to the temperature range of 1000-1800°K, was also proved to be very suited as an electron source for the TEM, as well as for the SEM. Some characteristics of the two types of the FEG have been studied and reported by many authors. However, the results of the respective types have been obtained separately under different experimental conditions.


2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Gaetano Frascella ◽  
Sascha Agne ◽  
Farid Ya. Khalili ◽  
Maria V. Chekhova

AbstractAmong the known resources of quantum metrology, one of the most practical and efficient is squeezing. Squeezed states of atoms and light improve the sensing of the phase, magnetic field, polarization, mechanical displacement. They promise to considerably increase signal-to-noise ratio in imaging and spectroscopy, and are already used in real-life gravitational-wave detectors. But despite being more robust than other states, they are still very fragile, which narrows the scope of their application. In particular, squeezed states are useless in measurements where the detection is inefficient or the noise is high. Here, we experimentally demonstrate a remedy against loss and noise: strong noiseless amplification before detection. This way, we achieve loss-tolerant operation of an interferometer fed with squeezed and coherent light. With only 50% detection efficiency and with noise exceeding the level of squeezed light more than 50 times, we overcome the shot-noise limit by 6 dB. Sub-shot-noise phase sensitivity survives up to 87% loss. Application of this technique to other types of optical sensing and imaging promises a full use of quantum resources in these fields.


Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 282
Author(s):  
Darya Urupina ◽  
Manolis N. Romanias ◽  
Frederic Thevenet

The experimental investigation of heterogeneous atmospheric processes involving mineral aerosols is extensively performed in the literature using proxy materials. In this work we questioned the validity of using proxies such as Fe2O3, FeOOH, Al2O3, MgO, CaO, TiO2, MnO2, SiO2, and CaCO3 to represent the behavior of complex mixtures of minerals, such as natural desert and volcanic dusts. Five volcanic dusts and three desert dusts were compared to a number of metal oxides, commonly used in the literature to mimic the behavior of desert dusts in the ability to form sulfites and sulfates on the surface exposed to SO2 gas. First, all samples were aged at room temperature, atmospheric pressure, under controlled experimental conditions of 175 ppm SO2 for 1 h under 30% of relative humidity. Second, they were extracted with 1% formalin and analyzed by High-Performance Liquid Chromatography (HPLC) to quantify and compare the amount of sulfites and sulfates formed on their surfaces. It was evidenced that under the experimental conditions of this study neither one selected pure oxide nor a mixture of oxides can adequately typify the behavior of complex mixtures of natural minerals. Therefore, to evaluate the real-life impact of natural dust on atmospheric processes it is of vital importance to work directly with the natural samples, both to observe the real effects of desert and volcanic dusts and to evaluate the relevancy of proposed proxies.


Geophysics ◽  
1988 ◽  
Vol 53 (3) ◽  
pp. 346-358 ◽  
Author(s):  
Greg Beresford‐Smith ◽  
Rolf N. Rango

Strongly dispersive noise from surface waves can be attenuated on seismic records by Flexfil, a new prestack process which uses wavelet spreading rather than velocity as the criterion for noise discrimination. The process comprises three steps: trace‐by‐trace compression to collapse the noise to a narrow fan in time‐offset (t-x) space; muting of the noise in this narrow fan; and inverse compression to recompress the reflection signals. The process will work on spatially undersampled data. The compression is accomplished by a frequency‐domain, linear operator which is independent of trace offset. This operator is the basis of a robust method of dispersion estimation. A flexural ice wave occurs on data recorded on floating ice in the near offshore of the North Slope of Alaska. It is both highly dispersed and of broad frequency bandwidth. Application of Flexfil to these data can increase the signal‐to‐noise ratio up to 20 dB. A noise analysis obtained from a microspread record is ideal to use for dispersion estimation. Production seismic records can also be used for dispersion estimation, with less accurate results. The method applied to field data examples from Alaska demonstrates significant improvement in data quality, especially in the shallow section.


Drones ◽  
2020 ◽  
Vol 5 (1) ◽  
pp. 2
Author(s):  
Georgios Amponis ◽  
Thomas Lagkas ◽  
Panagiotis Sarigiannidis ◽  
Vasileios Vitsas ◽  
Panagiotis Fouliras

With the development of more advanced and efficient control algorithms and communication architectures, UAVs and networks thereof (swarms) now find applications in nearly all possible environments and scenarios. There exist numerous schemes which accommodate routing for such networks, many of which are specifically designed for distinct use-cases. Validation and evaluation of routing schemes is implemented for the most part using simulation software. This approach is however incapable of considering real-life noise, radio propagation models, channel bit error rate and signal-to-noise ratio. Most importantly, existing frameworks or simulation software cannot sense physical-layer related information regarding power consumption which an increasing number of routing protocols utilize as a metric. The work presented in this paper contributes to the analysis of already existing routing scheme evaluation frameworks and testbeds and proposes an efficient, universal and standardized hardware testbed. Additionally, three interface modes aimed at evaluation under different scenarios are provided.


1992 ◽  
Vol 71 (3_suppl) ◽  
pp. 811-813 ◽  
Author(s):  
F. Schäfer ◽  
S.J. Raven ◽  
T.A. Parr

A major criterion for assessing the value of any experimental model in scientific research is the degree of correspondence between its results and data from the real-life process it is designed to model. Intra-oral models aimed at predicting the anti-caries efficacy of toothpastes or other topical treatments should therefore be calibrated against treatments proven to be effective in a caries clinical trial. For this to be achieved, it is necessary that a model with high sensitivity be designed, while at the same time retaining relevance to the process to be modeled. This means that the effects of the various experimental conditions and parameters of the model on its performance must be understood. The purpose of this paper was to assess the influence of two specific factors on the performance of an in situ enamel remineralization model, which is based on human enamel slabs attached to partial dentures. The two factors are initial lesion severity and origin of enamel sample. The results indicated that initial lesion size affected whether net remineralization or net demineralization occurred during in situ treatment. Samples with an initial range of from 1500 to 2500 (ΔZ) tended more toward demineralization than did samples with ΔZ > 3500. This means that treatment groups must be well-balanced with respect to initial lesion size. Differences in initial demineralization severity between different tooth locations must also be considered so that systematic treatment bias can be avoided. The solution used in the model discussed here is based on a balanced experimental design, which allows this effect to be taken into account in the data analysis.


Electronics ◽  
2021 ◽  
Vol 10 (22) ◽  
pp. 2742
Author(s):  
Yuwei Ge ◽  
Tao Zhang ◽  
Haihua Liang ◽  
Qingfeng Jiang ◽  
Dan Wang

Image steganalysis is a technique for detecting the presence of hidden information in images, which has profound significance for maintaining cyberspace security. In recent years, various deep steganalysis networks have been proposed in academia, and have achieved good detection performance. Although convolutional neural networks (CNNs) can effectively extract the features describing the image content, the difficulty lies in extracting the subtle features that describe the existence of hidden information. Considering this concern, this paper introduces separable convolution and adversarial mechanism, and proposes a new network structure that effectively solves the problem. The separable convolution maximizes the residual information by utilizing its channel correlation. The adversarial mechanism makes the generator extract more content features to mislead the discriminator, thus separating more steganographic features. We conducted experiments on BOSSBase1.01 and BOWS2 to detect various adaptive steganography algorithms. The experimental results demonstrate that our method extracts the steganographic features effectively. The separable convolution increases the signal-to-noise ratio, maximizes the channel correlation of residuals, and improves efficiency. The adversarial mechanism can separate more steganographic features, effectively improving the performance. Compared with the traditional steganalysis methods based on deep learning, our method shows obvious improvements in both detection performance and training efficiency.


2014 ◽  
Vol 12 (1) ◽  
pp. 29-38
Author(s):  
Silvanus Teneng Kiyang ◽  
Robert Van Zyl

Purpose – The purpose of this work is to assess the influence of ambient noise on the performance of wireless sensor networks (WSNs) empirically and, based on these findings, develop a mathematical tool to assist technicians to determine the maximum inter-node separation before deploying a new WSN. Design/methodology/approach – A WSN test platform is set up in an electromagnetically shielded environment (RF chamber) to accurately control and quantify the ambient noise level. The test platform is subsequently placed in an operational laboratory to record network performance in typical unshielded spaces. Results from the RF chamber and the real-life environments are analysed. Findings – A minimum signal-to-noise ratio (SNR) at which the network still functions was found to be of the order 30 dB. In the real-life scenarios (machines, telecommunications and computer laboratories), the measured SNR exceeded this minimum value by more than 20 dB. This is due to the low ambient industrial noise levels observed in the 2.4 GHz ISM band for typical environments found at academic institutions. It, therefore, suggests that WSNs are less prone to industrial interferences than anticipated. Originality/value – A predictive mathematical tool is developed that can be used by technicians to determine the maximum inter-node separation before the WSN is deployed. The tool yields reliable results and promises to save installation time.


2017 ◽  
Vol 121 (3) ◽  
pp. 527-547 ◽  
Author(s):  
João Carlos Centurion Cabral ◽  
Patrice de Souza Tavares ◽  
Gibson Juliano Weydmann ◽  
Vera Torres das Neves ◽  
Rosa Maria Martins de Almeida

Although audio-visual stimuli are among the most frequently used methods to elicit emotional reactions in experimental conditions, real-life manipulations have increasingly been used in different countries. However, the applicability of such protocols has not yet been tested in Brazilian Portuguese speakers. Thus, we conducted two experiments to investigate the effectiveness of both methods. In the first experiment, we used film clips to induce negative emotions (i.e., anger, fear, or sadness) or an emotionally neutral condition in 321 undergraduate students. After watching one of the online videos, volunteers completed an emotional assessment. As expected, there were significant differences in all groups. Our results corroborate the relatively discrete patterns in emotion elicitation using films. In the second experiment, anger was elicited in 18 male undergraduates through a hostile social interaction with a confederate and measured by the corrugator muscle activity and cortisol responses. Indeed, there was an increase in corrugator activity in the group exposed to anger induction, even after a few minutes from the end of the experimental manipulation. Implications for experiments on the negative emotions are discussed.


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