Review of fundamentals and applications of polyester nanocomposites filled with carbonaceous nanofillers

2018 ◽  
Vol 35 (1) ◽  
pp. 22-44 ◽  
Author(s):  
Ayesha Kausar

Polyester is a versatile commercially significant polymer (thermoplastic/thermoset) well-known for its biodegradability and excellent thermal, mechanical, and chemical properties. Synthetic aromatic polyester resins usually have better moisture resistance, nonflammability, liquid crystal, strength, thermal, and environmental features compared with natural/aliphatic polyesters. Nanofillers can reinforce these important polymers to further enhance the final nanocomposite structural and physical characteristics. This review presents research devoted to polyester nanocomposites with essential nanofillers such as; nanodiamond, fullerene, carbon nanotube, graphene, and graphene oxide. High-performance polyester/nanocomposites have been developed based on modified polyester design, nanofiller functionality, and optimized interaction between matrix and nanofiller. This article also presents state-of-the-art technological development in the field of polyester/nanocomposites predominantly in supercapacitors, fuel cells, shape memory materials, electromagnetic shielding materials, textiles, and biomedical appliances. Furthermore, future scenarios in scientific development of these nanocomposites are discussed.

2011 ◽  
Vol 411 ◽  
pp. 427-431 ◽  
Author(s):  
Miao Miao Tan ◽  
Zi Yi Zhang ◽  
Lin Hui Zhao ◽  
Jian Cheng Zhang

With the development of nano materials, a novel research field of NEMS forms by combining nano materials, nano-structures and nano fabrication with MEMS. Carbon nanotube (CNT) is a kind of one-dimensional nano structures which has unique mechanical, electrical and chemical properties. Using CNTs, new nano-devices with new principle or high performance would be developed. This paper reviews the assembly methods of one dimensional nanostructure and analyzes the characteristics of various methods, which provides reference for the device manufacturing methods using nanotubes/nanowires.


RSC Advances ◽  
2020 ◽  
Vol 10 (72) ◽  
pp. 44453-44469
Author(s):  
Edigar Muchuweni ◽  
Bice S. Martincigh ◽  
Vincent O. Nyamori

Graphene-based materials can produce high performance and sustainable DSSCs, through tuning of their excellent optoelectronic, mechanical, thermal and chemical properties for use as photoanodes, photosensitizers, electrolytes and counter electrodes.


2014 ◽  
Vol 93 ◽  
pp. 82-89 ◽  
Author(s):  
Aryan Azad ◽  
Eul Noh ◽  
Kang Seop Yun ◽  
Hee June Jeong ◽  
Sang Chul Jung ◽  
...  

Hydrogen has unique physical and chemical properties which present benefits and challenges to its successful widespread adoption as a fuel. The photoelectrochemical (PEC) water splitting process with semiconductor metal oxides can be a promising solution to the global energy problem. Although amongst metal oxides Fe2O3 by 2.2 eV bang gap energy is more applicable, for reducing the recombination of electron and hole, Fe was doped into TiO2. In this study Fe2O3/Fe doped TiO2 photocatalysts were compared with Fe-doped TiO2 and TiO2 structures by using layer by layer-self-assemble (LBL-SA) method and dipping process on FTO glass. According to our results the Fe2O3 coated on Fe doped TiO2 /FTO has had best results.


2021 ◽  
Vol 11 (21) ◽  
pp. 10340
Author(s):  
Heonseok Lee ◽  
Hyeonwook Cheon ◽  
Yonghak Kang ◽  
Seungjun Roh ◽  
Woosuk Kim

In the past few decades, there have been numerous attempts to add plastic aggregates composed of polymeric materials to cementitious composites, either as an alternative to using natural aggregates or as fillers and fibers. However, the addition of plastic aggregates often results in cementitious composites with lower mechanical performance. In this paper, we attempt to address this issue by applying gamma irradiation technology to restore the mechanical performance. We aimed to determine the optimal gamma irradiation and mixing combinations by comparing the experimental results with information summarizing the recent literature related to the use of gamma-irradiated plastic aggregates within cementitious composites. To this end, the effects of changes in the physical and chemical properties of plastics due to irradiation with gamma irradiation on the strength of cementitious composites were evaluated using irradiation doses of 25, 50, 75, and 100 kGy and various plastic materials as key parameters. In the compressive strength test, it was found that adding gamma-irradiated plastic increased the compressive strength of the cementitious composites compared to the nonirradiated plastic. This suggests that the irradiation of plastic aggregates with gamma rays is an effective method to recover some of the strength lost when plastic aggregates are added to cementitious composites. In addition, modifications in the microstructure and chemical properties of the gamma-irradiated plastic were analyzed through SEM and FT-IR analysis, which allowed the determination of the strength enhancement mechanism. The results of this study show the possibility of the state-of-the-art performance improvement method for using plastic aggregate as a substitute for natural aggregate, going further from the plastic performance improvement technology for limited materials and radiation dose presented in previous studies.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Boban S. Djordjevic ◽  
Dejan B. Djurovic ◽  
Gordan D. Zec ◽  
Mekjell O. Meland ◽  
Milica M. Fotiric Aksic

AbstractThe aim of this study was to examine the influence of shoot age on biological and chemical properties of 11 red currant cultivars (‘Jonkheer van Tets’, ‘Junifer’, ‘London Market’, ‘Makosta’, ‘Mirana’, ‘Redpoll’, ‘Rolan’, ‘Rondom’, ‘Rovada’, ‘Slovakia’ and ‘Stanza’) with different origins and ripening times. Phenological observations and pomological characteristics were studied and chemical analysis was conducted from 2013 to 2018 at experimental fields near Belgrade, Serbia. The total contents of phenols and anthocyanin were estimated spectrophotometrically, while quantitative analysis of anthocyanin aglycones was done using high-performance liquid chromatography. Three-year-old shoots had an earlier start of all examined phenological stages, better generative potential, higher yields, as well as higher total phenol and vitamin C contents in the fruits, compared with 2-year-old shoots, for all cultivars. The contents of total anthocyanins were higher in berries on younger shoots of early-ripening cultivars, while late-ripening cultivars had higher contents of total soluble solids and cyanidin in the berries on 3-year-old shoots. Principal component analysis demonstrated that the most important variables that distinguished 2-year-old shoots from 3-year-old shoots were those related to phenological data, cluster traits, total acids and yields. According to the obtained results, ‘Junifer’ (with the highest number of clusters), ‘Mirana’ (with the highest sugar content and sugar/acid ratio), ‘Redpoll’ (with the highest physical traits of cluster and berry), ‘Slovakia’ (with the highest yield and yield efficiency) and ‘Rovada’ (with the highest level of secondary metabolites) are recommended as the most promising cultivars for growing in the temperate region of Serbia.


2021 ◽  
Vol 111 (06) ◽  
pp. 419-429
Author(s):  
Jörg Hartig ◽  
Benjamin Kirsch ◽  
Jan C. Aurich

Das Aufbringen von Beschichtungen bei Werkzeugen mit geometrisch bestimmter Schneide gehört seit vielen Jahren zum Stand der Technik. Die Hartstoffschichten werden häufig mittels PVD-Technik auf dem Substrat abgeschieden. Die Schichten zeichnen sich durch eine hohe Härte und Verschleißbeständigkeit, sowie gute tribologische und chemische Eigenschaften aus. Dieses Eigenschaftsprofil bietet somit auch großes Potenzial zur Standzeitverbesserung von thermisch und mechanisch hochbeanspruchten Schleifwerkzeugen bei der Bearbeitung von Superlegierungen. In diesem Beitrag werden unterschiedliche Schichtsysteme auf ihre Anwendbarkeit auf galvanisch gebundene cBN-Schleifwerkzeuge untersucht und diskutiert.   The application of coatings to cutting tools with geometrically defined cutting edge has been state of the art for many years. The coatings are often deposited on the substrate using PVD technology. The coatings are characterized by high hardness and wear resistance as well as good tribological and chemical properties. Therefore, this property profile also offers great potential for improving the tool life of grinding wheels that are subject to high thermal and mechanical stress, especially during grinding difficult to machine materials. In the following article, different coatings are examined and discussed for their applicability to electroplated cBN grinding tools.


RSC Advances ◽  
2015 ◽  
Vol 5 (99) ◽  
pp. 81707-81712 ◽  
Author(s):  
Sung Ho Song ◽  
Jung Mo Kim ◽  
Kwang Hyun Park ◽  
Dong Ju Lee ◽  
O.-Seok Kwon ◽  
...  

Nano-fillers have provided a big advantage for enhancing the performance of rubber composites through leading the synergy effects in the physical and chemical properties.


2014 ◽  
Vol 30 (6) ◽  
Author(s):  
Shipra Jaswal ◽  
Bharti Gaur

AbstractVinyl ester resins (VERs) are high-performance unsaturated resins derived by the addition reaction of various epoxide resins with α-β unsaturated carboxylic acids. These resins have always been classified under unsaturated polyester resins. However, VERs have remarkable corrosion resistance and superior physical properties as compared with these conventional polyester resins, which make VERs a class of their own and hallmark of today’s resin industries. Hence, there is a need to review the available literature on this important class of thermosetting resins separately. In this article, an attempt is made to review the state of the art of VERs, including synthesis, characterization, curing, thermal, chemical, oxidative properties, and applications. The main focus is on the latest developments in this area.


Nanoscale ◽  
2021 ◽  
Author(s):  
Xianyu Chu ◽  
Fanling Meng ◽  
Ting Deng ◽  
Wei Zhang

Designing and synthesizing new materials with special physical and chemical properties are the key steps to assembling high performance supercapacitors. Metal organic framework (MOF) derived porous carbon material has drawn...


RSC Advances ◽  
2018 ◽  
Vol 8 (22) ◽  
pp. 12300-12309 ◽  
Author(s):  
Babak Ashourirad ◽  
Muslum Demir ◽  
Ryon A. Smith ◽  
Ram B. Gupta ◽  
Hani M. El-Kaderi

Zinc chloride activated benzimidazole derived carbons (ZBIDCs) with optimal textural and chemical properties exhibit remarkable and stable performance in supercapacitor applications.


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