Enhanced production of magnesium silicates from strained magnesia

Author(s):  
W. F. Bush ◽  
W. O. Williamson

SummaryMechanically strained, in contrast to annealed, MgO produced greater yields of forsterite and protoenstatite by solid-state reaction with a quartz–cristobalite mixture at 1200–1400° C. The specific surfaces of the strained and of the annealed MgO were similar. The strained MgO was more hygroscopic and similarity of the surface free energies was thus unlikely. The difference in the amounts of silicates produced from the two types of MgO decreased as the temperatures of synthesis increased. This was ascribed to loss of strain energy by unavoidable annealing before and after these temperatures had been reached.Similar results were obtained when hydrated silica was substituted for the quartz-eristobalite mixture, but more forsterite was produced.

Author(s):  
S.R. Summerfelt ◽  
C.B. Carter

The wustite-spinel interface can be viewed as a model interface because the wustite and spinel can share a common f.c.c. oxygen sublattice such that only the cations distribution changes on crossing the interface. In this study, the interface has been formed by a solid state reaction involving either external or internal oxidation. In systems with very small lattice misfit, very large particles (>lμm) with coherent interfaces have been observed. Previously, the wustite-spinel interface had been observed to facet on {111} planes for MgFe2C4 and along {100} planes for MgAl2C4 and MgCr2O4, the spinel then grows preferentially in the <001> direction. Reasons for these experimental observations have been discussed by Henriksen and Kingery by considering the strain energy. The point-defect chemistry of such solid state reactions has been examined by Schmalzried. Although MgO has been the principal matrix material examined, others such as NiO have also been studied.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Jian Hui ◽  
Haiqian Ma ◽  
Zheyu Wu ◽  
Zhan Zhang ◽  
Yang Ren ◽  
...  

AbstractA high-throughput investigation of metallic glass formation via solid-state reaction was reported in this paper. Combinatorial multilayered thin-film chips covering the entire Ti–Ni–Cu ternary system were prepared using ion beam sputtering technique. Microbeam synchrotron X-ray diffraction (XRD) and X-ray fluorescence (XRF) measurements were conducted, with 1,325 data points collected from each chip, to map out the composition and the phase constitution before and after annealing at 373 K for 110 hours. The composition dependence of the crystal-to-glass transition by solid-state reaction was surveyed using this approach. The resulting composition–phase map is consistent with previously reported results. Time-of-flight secondary ion mass spectroscopy (ToF-SIMS) was performed on the representative compositions to determine the inter-diffusion between layers, the result shows that the diffusion of Ti is the key factor for the crystal-to-glass transition. In addition, both layer thickness and layer sequence play important roles as well. This work demonstrates that combinatorial chip technique is an efficient way for systematic and rapid study of crystal-to-glass transition for multi-component alloy systems.


2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
I. A. Kaurova ◽  
G. M. Kuz’micheva ◽  
V. B. Rybakov ◽  
A. Cousson ◽  
O. Zaharko ◽  
...  

Langanite (La3Ga5.5Nb0.5O14, growth atmosphere: 99% Ar + 1% O2) and kanigasite (Ca3NbGa3Si2O14, growth atmosphere: 100% Ar) crystals grown by the Czochralski technique in Ir crucibles along <0001> direction have been firstly investigated by neutron diffraction. The difference between the compositions of upper (La2.935(2)□0.065)(Ga0.450Nb0.550(3))Ga3(Ga1.965(4)□0.035)(O13.90(1)□0.10) and lower (La2.940(1)□0.060)(Ga0.590Nb0.410(2))Ga5(O13.82(1)□0.18) parts of orange langanite crystal was found. It was established that the colorless Ca3NbGa3Si2O14 crystal grown by using the single-crystal charge has the composition (Ca2.95□0.05(1))NbGa3Si2O14 and is less defective in comparison to the yellow one grown by using the charge prepared by conventional solid-state reaction. For Ca3NbGa3Si2O14 and La3Ga5.5Nb0.5O14 crystals the possibility of microtwin formation (two unit cells connected by the translation: 1/2 z) was revealed for the first time. It was found that the difference between the color of crystals is attributed to the qualitative differentiation of oxygen vacancies.


2019 ◽  
Vol 7 (2) ◽  
pp. T363-T372
Author(s):  
Cheng Huang ◽  
Chao Yang ◽  
Feng Shen

Rock brittleness and fracture toughness are important parameters for evaluating rock fracability. The stress-strain curves indicate that the lacustrine shale is strongly brittle. Brittle failure occurs rapidly when the stress of the lacustrine shale reaches its peak value. In addition, the lacustrine shale has different plastic strains before and after peak stress; this can relax the stress concentration of the crack tips. Therefore, the plastic strain that occurs before and after the peak stress can cause decreasing brittleness, which can be used to distinguish the brittleness and fracability in the formation of the lacustrine shale clearly. Moreover, this further enlarges the difference in the brittleness index. Based on the influence of plastic strain on brittleness, we have developed a new brittleness evaluation method that uses the ratio of linear elastic strain energy to the total strain energy before complete rock failure, which can indicate the difference of the lacustrine shale clearly. Fracture toughness is another important parameter that impacts the fracture extension and influences fracability. Based on the impact of brittleness and fracture toughness on the fracability, we have developed a new fracability evaluation method. The brittleness index increases with increases in the quartz content, and it decreases with increases in the albite feldspar and calcite contents. The fracture toughness decreases with increases in the quartz and clay contents, and it increases with increases in the siderite content. In addition, we established an empirical formula that can evaluate the brittleness index and the fracture toughness using mineral contents obtained from elemental logging. Using the new fracability evaluation method to optimize the fracturing stage, the preliminary field test indicates that the new approach was effective in the lacustrine shale formation.


1991 ◽  
Vol 235 ◽  
Author(s):  
B. X. Liu ◽  
J. R. Ding ◽  
D. Z. Che ◽  
H. B. Zhang

ABSTRACTWe report, in this paper, three different ways of producing amorphous alloys in the Al-Yb system, (i) Al80Yb20multilayered films were readily amorphized by 180 keV xenon ion mixing at room temperature(RT) to a dose of 3×1015 Xe/cm2. (ii) When the dose went up to 1×1016 Xe/cm2 or higher, a metastable phase of hcp structure was formed. Interestingly, the hcp phase turned into amorphous after annealing at 500°C for about 10 minutes. (iii) Amorphous alloys were also formed by steady state thermal annealing of the Al-Yb multilayered films at about 450 °C for 20 minutes. The optimum amorphization range was found out by experiments to be 17 to 30 Yb at%, i.e., within this composition range, the multilayered films could entirely be amorphized by solid state reaction.The recrystallization behavior of the amorphous alloys formed by different methods was also studied and the difference in this aspect was thought to relate to the structures resulting from different processing methods.Possible explanation of the observed sequence of phase transition is also discussed.


2007 ◽  
Vol 361-363 ◽  
pp. 355-358 ◽  
Author(s):  
Aline P. Oliveira ◽  
M. Motisuke ◽  
Claudinete V. Leal ◽  
Marisa Masumi Beppu

It is well known that calcium phosphate compounds are widely used as bone substitute due to their biocompatibility and bioactivity. Furthermore, recent studies have shown that slight changes in morphology or crystal structure can lead to several in vivo behaviours. Therefore, the purpose of this study was to investigate two different β-TCP synthesis routes (solid state reaction and aqueous solution precipitation) and their consequences on the final cement properties. It was found out that both routes are equivalent as there were no significant differences on their cement properties, except for mechanical resistance. The latter difference can also be attributed to the difference on the particle size distributions of the obtained β-TCP. These facts indicate that solid state reaction route is more interesting given its simplicity and yield.


Author(s):  
R.A. Herring

Rapid thermal annealing (RTA) of ion-implanted Si is important for device fabrication. The defect structures of 2.5, 4.0, and 6.0 MeV As-implanted silicon irradiated to fluences of 2E14, 4E14, and 6E14, respectively, have been analyzed by electron diffraction both before and after RTA at 1100°C for 10 seconds. At such high fluences and energies the implanted As ions change the Si from crystalline to amorphous. Three distinct amorphous regions emerge due to the three implantation energies used (Fig. 1). The amorphous regions are separated from each other by crystalline Si (marked L1, L2, and L3 in Fig. 1) which contains a high concentration of small defect clusters. The small defect clusters were similar to what had been determined earlier as being amorphous zones since their contrast was principally of the structure-factor type that arises due to the difference in extinction distance between the matrix and damage regions.


Author(s):  
J. R. Heffelfinger ◽  
C. B. Carter

Transmission-electron microscopy (TEM), scanning-electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) were used to investigate the solid-state reaction between a thin yttria film and a (0001) α-alumina substrate. Systems containing Y2O3 (yttria) and Al2O3 (alumina) are seen in many technologically relevant applications. For example, yttria is being explored as a coating material for alumina fibers for metal-ceramic composites. The coating serves as a diffusion barrier and protects the alumina fiber from reacting with the metal matrix. With sufficient time and temperature, yttria in contact with alumina will react to form one or a combination of phases shown by the phase diagram in Figure l. Of the reaction phases, yttrium aluminum garnet (YAG) is used as a material for lasers and other optical applications. In a different application, YAG is formed as a secondary phase in the sintering of AIN. Yttria is added to AIN as a sintering aid and acts as an oxygen getter by reacting with the alumina in AIN to form YAG.


1990 ◽  
Vol 51 (C4) ◽  
pp. C4-111-C4-117 ◽  
Author(s):  
L. J. GALLEGO ◽  
J. A. SOMOZA ◽  
H. M. FERNANDEZ ◽  
J. A. ALONSO

1979 ◽  
Vol 42 (04) ◽  
pp. 1332-1339 ◽  
Author(s):  
Hiroh Yamazaki ◽  
Takeshi Motomiya ◽  
Minoru Sonoda ◽  
Noboru Miyagawa

SummaryChanges in platelets in 48 patients with uterine myoma before and after hysterectomy with and without ovariectomy were examined. Bilateral ovariectomy in 25 cases (ovariec-tomized group) and unilateral or non-ovariectomy in 23 cases (control group) were performed at the hysterectomy. Platelet count and an appearance rate of secondary aggregation decreased at one day after and increased at one week after the operation, similarly in both the ovariectomized and the control group. The appearance rate of secondary aggregation was reflected in an intensity of aggregation at 5 min after the addition of reagent to PRP. At one month after the operation, the appearance rate of secondary aggregation induced by 3 μM ADP showed a statistically significant decrease in comparison with the preoperation value (P <0.05) and the enhancement of 5-min aggregation was still observed in the control group, while ceased in the ovariectomized group. The difference between the two groups was significant (P < 0.05). There was almost no change in the speed and intensity of primary and secondary aggregation during the observation period. No significant differences in collagen-induced aggregation were noted between the two groups. The results suggest that ovarian hormones, mainly estrogen, facilitate platelet activation which is mediated by the so-called secondary aggregation.


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