Pore characteristics and dominant controlling factors of overmature shales: A case study of the Wangyinpu and Guanyintang Formations in the Jiangxi Xiuwu Basin

Because of the great potential for hydrocarbon generation, the Lower Cambrian Wangyinpu and Guanyintang Formations of the Jiangxi Xiuwu Basin have become the most important targets for shale-gas exploration in the Jiangxi province. We investigate the pore characteristics and main controlling factors of overmature shale using field emission-scanning electron microscopy, image-processing software (i.e., the Particles [Pores] and Crack Analysis System), X-ray diffraction, and gas-adsorption experiments. The results show that the shales have a high abundance of organic matter (OM), over maturity, and highly siliceous mineral content. The kerogen type is identified as type I. OM pores are the most developed, followed by interparticle (interP) pores and intraparticle (intraP) pores. We combine complementary image processing and gas-adsorption methods to reveal that micropores are mainly from OM pores; mesopores are from OM pores and interP pores; and macropores are from OM pores, interP pores, and intraP pores. Although the number of micropores is at a maximum, the total contribution of mesopores and macropores to the pore volume (PV) is larger than that of micropores. However, the specific surface area (SSA) is mainly from the micropores. OM content and maturity are the main controlling factors for the development of pore structures. Because of overmaturity, OM loses its potential for hydrocarbon generation and new pores cannot be produced. Gas loss leads to reservoir pressure drop, and the pores generated during the mature stage collapse and even disappear because they lack support. Therefore, PV, SSA, and porosity decrease when the OM content is more than 10%. When the OM content is less than 10%, most of the OM pores are preserved because they are protected by the skeleton particles.

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Pore Characteristics and Controlling Factors of Lacustrine Shales From the Upper Cretaceous Qingshankou Formation of the Songliao Basin, Northeast China: A Study Combining SEM, Low Temperature Gas Adsorption and MICP Experiments

Acta Geologica Sinica - English Edition ◽

10.1111/1755-6724.14419 ◽

2020 ◽

Author(s):

Hui HAN ◽

Chen GUO ◽

Ningning ZHONG ◽

Peng PANG ◽

Zhengang DING ◽

...

Keyword(s):

Low Temperature ◽

Northeast China ◽

Upper Cretaceous ◽

Gas Adsorption ◽

Controlling Factors ◽

Songliao Basin ◽

Pore Characteristics

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Pore characteristics of lacustrine mudstones from the Cretaceous Qingshankou Formation, Songliao Basin

Interpretation ◽

10.1190/int-2017-0010.1 ◽

2017 ◽

Vol 5 (3) ◽

pp. T373-T386 ◽

Cited By ~ 3

Author(s):

Min Wang ◽

Shuangfang Lu ◽

Wenbiao Huang ◽

Wei Liu

Keyword(s):

Organic Matter ◽

Source Rock ◽

Gas Adsorption ◽

Total Pore Volume ◽

Songliao Basin ◽

Hydrocarbon Generation ◽

Shale Oil ◽

Pore Characteristics ◽

Oil Accumulation ◽

Average Pore

Cretaceous Qingshankou ([Formula: see text]) mudstone of lacustrine origin is the major source rock for conventional hydrocarbon currently being produced in the Daqing and Jilin oilfields of the Songliao Basin, which is one of the largest continental basins in the world. Therefore, elucidating the geochemical and petrological characteristics of the [Formula: see text] mudstone is important to help determine its quality as an economically viable source for shale oil production. In our study, eight dark mudstone core samples from the [Formula: see text] formation were subjected to total organic carbon (TOC), Rock-Eval pyrolysis, X-ray diffraction, scanning electron microscopy (SEM), field emission SEM (FE-SEM), and low-pressure [Formula: see text] gas adsorption (LPGA-[Formula: see text]) experiments. Geochemical and petrological analysis results indicated the presence of a high TOC content, which originated mainly from alginate and some plant-derived organic matter, whereas bitumen was frequently present in mudstones with thermal maturity in the oil-generation stage. The [Formula: see text] mudstones were comprised mainly of clay minerals, followed by quartz, feldspar, and carbonates. The LPGA-[Formula: see text] experiments revealed the presence of nanoscale slit-shaped pores, and the contribution from mesopores to the total pore volume was the highest in most of the samples. The average pore diameters (APDs) of the mudstone samples were all smaller than 20 nm (4.36–17.79 nm). We determined that there was a clear positive correlation between the APD and the free oil content; however, there were no clear correlations between the APDs and the quartz, carbonate, and TOC contents. FEM studies revealed the presence of intergranular pores with widths of approximately 10 μm, micron-level autogenetic organic matter pores within spores, organic matter pores caused by the hydrocarbon generation effect within organic matter or clay-organic complexes, and intraparticle pores within clays or pyrite framboids. The microlevel intergranular pores might play an important role in shale oil accumulation from source rock of lacustrine origin.

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The Evaluation of Potential of Shale Oil Resources in K1qn1 Formation of Southern Songliao Basin

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.1006-1007.107 ◽

2014 ◽

Vol 1006-1007 ◽

pp. 107-111

Author(s):

Yan Wang ◽

Wen Biao Huang ◽

Min Wang

Keyword(s):

Organic Matter ◽

Source Rock ◽

Thermal Evolution ◽

Songliao Basin ◽

Mature Stage ◽

Type I ◽

Hydrocarbon Generation ◽

Shale Oil ◽

Oil Resources ◽

Geochemical Method

Based on the analysis of source rock geochemical index, with K1qn1 Formation of southern Songliao basin as the research objective layer, it’s concluded that the mean TOC value of shale in K1qn1 Formation is higher, generally more than 1%, which belongs to the best source rock. Most of shale organic matter types are type I and type II1. The thermal evolution degree of organic matter is generally in the mature stage: a stage of large hydrocarbon generation. With logging geochemical method applied, the calculated total resources of shale oil in K1qn1 formation are 15.603 billion tons. The II level of resources are 8.765 billion tons, which is more than 50% of the total resources. The I level of resources are 4.808 billion tons while the III level of resources 2.03 billion tons. Overall, the southern Songliao Basin still has a certain degree of prospecting and mining value.

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Petroleum Geochemistry of the Loperot-1 Well in Lokichar Basin, Kenya

10.2118/afrc-2557372-ms ◽

2016 ◽

Cited By ~ 1

Author(s):

David M. Katithi ◽

David O. Opar

Keyword(s):

Organic Matter ◽

Source Rock ◽

Shale Gas ◽

Source Rocks ◽

Geochemical Data ◽

Mature Stage ◽

Type I ◽

Hydrocarbon Generation ◽

Gas Generation ◽

Gas Targets

ABSTRACT The work reports an in-depth review of bulk and molecular geochemical data to determine the organic richness, kerogen type and thermal maturity of the Lokhone and the stratigraphically deeper Loperot shales of the Lokichar basin encountered in the Loperot-1 well. Oil-source rock correlation was also done to determine the source rocks’ likelihood as the source of oil samples obtained from the well. A combination of literature and geochemical data analyses show that both shales have good to excellent potential in terms of organic and hydrogen richness to act as conventional petroleum source rocks. The Lokhone shales have TOC values of 1.2% to 17.0% (average 5.16%) and are predominantly type I/II organic matter with HI values in the range of 116.3 – 897.2 mg/g TOC. The Lokhone source rocks were deposited in a lacustrine depositional environment in episodically oxic-dysoxic bottom waters with periodic anoxic conditions and have Tmax values in addition to biomarker signatures typical of organic matter in the mid-mature to mature stage with respect to hydrocarbon generation and immature for gas generation with Ro values of 0.51 – 0.64%. The Loperot shales were shown to be possibly highly mature type II/III source rocks with TOC values of 0.98% – 3.18% (average 2.4%), HI of 87 – 115 mg/g TOC and Ro of 1.16 – 1.33%. The Lokhone shale correlate well with the Loperot-1 well oils and hence is proposed as the principal source rock for the oils in the Lokichar basin. Although both source rocks have good organic richness to act as shale gas plays, they are insufficiently mature to act as shale gas targets but this does not preclude their potential deeper in the basin where sufficient gas window maturities might have been attained. The Lokhone shales provide a prospective shale oil play if the reservoir suitability to hydraulic fracturing can be defined. A basin wide study of the source rocks thickness, potential, maturation and expulsion histories in the Lokichar basin is recommended to better understand the present-day distribution of petroleum in the basin.

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