Discharge Behavior in Liquid Electrolyte

1994 ◽  
pp. 281-283
Keyword(s):  
Liquid Electrolyte ◽  
Discharge Behavior

scholarly journals Charge–discharge behavior of a Na2FeP2O7 positive electrode in an ionic liquid electrolyte between 253 and 363 K

2014 ◽  
Vol 133 ◽  
pp. 583-588 ◽  
Author(s):  
Chih-Yao Chen ◽  
Kazuhiko Matsumoto ◽  
Toshiyuki Nohira ◽  
Changsheng Ding ◽  
Takayuki Yamamoto ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrolyte ◽  
Positive Electrode ◽  
Ionic Liquid Electrolyte ◽  
Discharge Behavior ◽  
Charge Discharge

Charge–Discharge Behavior of Bismuth in a Liquid Electrolyte for Rechargeable Batteries Based on a Fluoride Shuttle

2017 ◽  
Vol 2 (6) ◽  
pp. 1460-1464 ◽  
Author(s):  
Ken-ichi Okazaki ◽  
Yoshiharu Uchimoto ◽  
Takeshi Abe ◽  
Zempachi Ogumi
Keyword(s):  
Liquid Electrolyte ◽  
Rechargeable Batteries ◽  
Discharge Behavior ◽  
Charge Discharge

Intensification of Extraction of Thermolabile Organic Polymers into a Liquid Electrolyte

1998 ◽  
Vol 29 (1-3) ◽  
pp. 140-145
Author(s):  
R. Sh. Vainberg ◽  
S. A. Bogdanov ◽  
N. D. Butskii
Keyword(s):  
Liquid Electrolyte ◽  
Organic Polymers

Enhanced Ion Transport in an Ether Aided Super Concentrated Ionic Liquid Electrolyte for Long-Life Practical Lithium Metal Battery Applications

2020 ◽  
Author(s):  
Urbi Pal ◽  
Fangfang Chen ◽  
Derick Gyabang ◽  
Thushan Pathirana ◽  
Binayak Roy ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ion Transport ◽  
Current Density ◽  
Coulombic Efficiency ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Mass ◽  
Lithium Metal ◽  
Ionic Liquid Electrolyte ◽  
Lithium Metal Battery

We explore a novel ether aided superconcentrated ionic liquid electrolyte; a combination of ionic liquid, <i>N</i>-propyl-<i>N</i>-methylpyrrolidinium bis(fluorosulfonyl)imide (C<sub>3</sub>mpyrFSI) and ether solvent, <i>1,2</i> dimethoxy ethane (DME) with 3.2 mol/kg LiFSI salt, which offers an alternative ion-transport mechanism and improves the overall fluidity of the electrolyte. The molecular dynamics (MD) study reveals that the coordination environment of lithium in the ether aided ionic liquid system offers a coexistence of both the ether DME and FSI anion simultaneously and the absence of ‘free’, uncoordinated DME solvent. These structures lead to very fast kinetics and improved current density for lithium deposition-dissolution processes. Hence the electrolyte is used in a lithium metal battery against a high mass loading (~12 mg/cm<sup>2</sup>) LFP cathode which was cycled at a relatively high current rate of 1mA/cm<sup>2</sup> for 350 cycles without capacity fading and offered an overall coulombic efficiency of >99.8 %. Additionally, the rate performance demonstrated that this electrolyte is capable of passing current density as high as 7mA/cm<sup>2</sup> without any electrolytic decomposition and offers a superior capacity retention. We have also demonstrated an ‘anode free’ LFP-Cu cell which was cycled over 50 cycles and achieved an average coulombic efficiency of 98.74%. The coordination chemistry and (electro)chemical understanding as well as the excellent cycling stability collectively leads toward a breakthrough in realizing the practical applicability of this ether aided ionic liquid electrolytes in lithium metal battery applications, while delivering high energy density in a prototype cell.

scholarly journals Corrosion and discharge behavior of Mg−xLa alloys (x=0.0−0.8) as anode materials

2021 ◽  
Vol 31 (7) ◽  
pp. 1979-1992
Author(s):  
Yan SONG ◽  
Hua-bao YANG ◽  
Yan-fu CHAI ◽  
Qing-hang WANG ◽  
Bin JIANG ◽  
...  
Keyword(s):  
Anode Materials ◽  
Discharge Behavior

scholarly journals Probing the Na metal solid electrolyte interphase via cryo-transmission electron microscopy

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Bing Han ◽  
Yucheng Zou ◽  
Zhen Zhang ◽  
Xuming Yang ◽  
Xiaobo Shi ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Metal Electrode ◽  
Liquid Electrolyte ◽  
Battery Materials ◽  
Cryogenic Transmission Electron Microscopy ◽  
Transmission Electron ◽  
Fluoroethylene Carbonate

AbstractCryogenic transmission electron microscopy (cryo-TEM) is a valuable tool recently proposed to investigate battery electrodes. Despite being employed for Li-based battery materials, cryo-TEM measurements for Na-based electrochemical energy storage systems are not commonly reported. In particular, elucidating the chemical and morphological behavior of the Na-metal electrode in contact with a non-aqueous liquid electrolyte solution could provide useful insights that may lead to a better understanding of metal cells during operation. Here, using cryo-TEM, we investigate the effect of fluoroethylene carbonate (FEC) additive on the solid electrolyte interphase (SEI) structure of a Na-metal electrode. Without FEC, the NaPF6-containing carbonate-based electrolyte reacts with the metal electrode to produce an unstable SEI, rich in Na2CO3 and Na3PO4, which constantly consumes the sodium reservoir of the cell during cycling. When FEC is used, the Na-metal electrode forms a multilayer SEI structure comprising an outer NaF-rich amorphous phase and an inner Na3PO4 phase. This layered structure stabilizes the SEI and prevents further reactions between the electrolyte and the Na metal.

Enabling highly reversible sodium metal cycling across a wide temperature range with dual-salt electrolytes

2021 ◽  
Author(s):  
Akila C. Thenuwara ◽  
Pralav P. Shetty ◽  
Neha Kondekar ◽  
Chuanlong Wang ◽  
Weiyang Li ◽  
...  
Keyword(s):  
Wide Temperature Range ◽  
High Energy ◽  
Liquid Electrolyte ◽  
Metal Cycling ◽  
Temperature Range ◽  
Sodium Metal ◽  
Wide Range

A new dual-salt liquid electrolyte is developed that enables the reversible operation of high-energy sodium-metal-based batteries over a wide range of temperatures down to −50 °C.

scholarly journals The third form electric organ discharge of electric eels

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jun Xu ◽  
Xiang Cui ◽  
Huiyuan Zhang
Keyword(s):  
High Voltage ◽  
Low Voltage ◽  
Electric Organ Discharge ◽  
Electric Organ ◽  
The Third ◽  
Electric Organs ◽  
Electric Eel ◽  
New Finding ◽  
Discharge Behavior ◽  
Unique Species

AbstractThe electric eel is a unique species that has evolved three electric organs. Since the 1950s, electric eels have generally been assumed to use these three organs to generate two forms of electric organ discharge (EOD): high-voltage EOD for predation and defense and low-voltage EOD for electrolocation and communication. However, why electric eels evolved three electric organs to generate two forms of EOD and how these three organs work together to generate these two forms of EOD have not been clear until now. Here, we present the third form of independent EOD of electric eels: middle-voltage EOD. We suggest that every form of EOD is generated by one electric organ independently and reveal the typical discharge order of the three electric organs. We also discuss hybrid EODs, which are combinations of these three independent EODs. This new finding indicates that the electric eel discharge behavior and physiology and the evolutionary purpose of the three electric organs are more complex than previously assumed. The purpose of the middle-voltage EOD still requires clarification.

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