Optimisation of Adsorption Dynamics in Adsorptive Heat Transformers

2013 ◽  
pp. 63-108
Author(s):  
Yuri Aristov
Keyword(s):  
Adsorption Dynamics

scholarly journals Analysis of Selected Methods Use for Calculation of the Coefficients of Adsorption Isotherms and Simplified Equations of Adsorption Dynamics with the Use of IZO Application

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4192
Author(s):  
Jacek Piekarski ◽  
Katarzyna Ignatowicz ◽  
Tomasz Dąbrowski
Keyword(s):  
Linear System ◽  
Adsorption Isotherms ◽  
Balance Equation ◽  
Laboratory Tests ◽  
Adsorption Process ◽  
Estimation Method ◽  
Linearization Method ◽  
Sufficient Accuracy ◽  
Mass Balance Equation ◽  
Adsorption Dynamics

The purpose of this paper is to present the IZO application that calculates and visualizes coefficients of adsorption isotherms according to Freundlich, Langmuir, and BET in a classic and linear system, in a simple communicative way. The application also calculates the working time of the adsorption bed based on the transformation of the mass balance equation, and according to the Zuchowicki, Zabieziński, Tichonow, and the Bohart-Adams equations. The laboratory tests of the adsorption process of leachate from a municipal landfill on selected active coals ORGANOSORB 10, DESOTEK, and BA-10, were conducted to check the program for accuracy. Results of tests confirm that the linearization method of the calculation of adsorption isotherms coefficients, used in the IZO application, gives sufficient accuracy and may be used as an alternative of, e.g., the nonlinear estimation method.

Supercritical CO2 regeneration of activated carbon loaded with organic adsorbates

1997 ◽  
Vol 35 (7) ◽  
pp. 261-268 ◽  
Author(s):  
Kazuyuki Chihara ◽  
Kanji Oomori ◽  
Takao Oono ◽  
Yosuke Mochizuki
Keyword(s):  
Activated Carbon ◽  
Cost Estimation ◽  
Supercritical Co2 ◽  
Adsorption Equilibrium ◽  
Equilibrium Constants ◽  
Adsorption Dynamics ◽  
Boiling Points ◽  
Organic Adsorbates ◽  
Carbon Regeneration ◽  
Co2 Density

Supercritical CO2 regeneration is one of the possibilities for spent carbon regeneration loaded with some organics. Here, adsorption equilibrium and adsorption dynamics were evaluated for some typical organic pollutants under some supercritical CO2 conditions. A supercritical CO2 chromatograph packed with activated carbon (F-400, CAL) was used to detect the pulse responses of organics, which were analyzed by moment analysis. Adsorption equilibrium constants of some organics varied with CO2 density and their boiling points. Possibility of regeneration of each substance was discussed. Cost estimation was necessary and was the key point of this technique.

An apparatus for adsorption dynamics studies using infrared measurement of the adsorbent temperature

1998 ◽  
Vol 69 (5) ◽  
pp. 2130-2136 ◽  
Author(s):  
V. Bourdin ◽  
P. G. Gray ◽  
Ph. Grenier ◽  
M. F. Terrier
Keyword(s):  
Adsorption Dynamics ◽  
Infrared Measurement

Molecular propane adsorption dynamics on Pt(110)−(1 × 2)

1993 ◽  
Vol 297 (3) ◽  
pp. 253-271 ◽  
Author(s):  
Mark C. McMaster ◽  
Sven L.M. Schroeder ◽  
Robert J. Madix
Keyword(s):  
Adsorption Dynamics

Luteolin Imprinted Polymer with Selective Recognition and Adsorption Performance

2014 ◽  
Vol 809-810 ◽  
pp. 297-301
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li
Keyword(s):  
Adsorption Process ◽  
Selective Adsorption ◽  
Methanol Solution ◽  
Selective Recognition ◽  
Imprinted Polymer ◽  
Molecular Imprinted Polymers ◽  
Adsorption Dynamics ◽  
Adsorption Performance ◽  
Recognition Specificity ◽  
Adsorption Amount

In order to selectively separate luteolin from its crude solution, we synthesized luteolin molecular imprinted polymers (LMIP) with high recognition specificity for luteolin, using an imprinting technique. Luteolin was used as template, methanol as solvent, and N,N’-methylenebisacrylamide (MBAA) as the cross-linking. Then prepared LMIP were characterized and evaluated by scanning electron microscope (SEM) and equilibrium absorption experiments. The results showed that the cavities matching with the template molecules in size and structure were present in the LMIP. Adsorption dynamics analysis suggested that, when the adsorption time reached 4 h, the adsorption process had reached balance and the adsorption capacity was at steady state. The selective adsorption amount reached at 35.65 umol/g for the LMIP, while a lower value of 11.68 umol/g for the blank polymer (i.e. nontemplated). Relative to the corresponding blank polymer, LMIP had an excellent recognition to luteolin in methanol solution. Keywords: Molecular imprinting, Molecular recognition, Adsorbent, Luteolin

The Dynamics for Aqueous Sodium Adsorption and Characterization of Natural Pyrophyllite

2011 ◽  
Vol 117-119 ◽  
pp. 1129-1132
Author(s):  
Bo Liu ◽  
Hai Feng Chen ◽  
Pei Song Tang
Keyword(s):  
Qualitative Analysis ◽  
Internal Structure ◽  
Electron Micrographs ◽  
Scanning Electron Micrographs ◽  
Adsorption Dynamics ◽  
Natural Mineral ◽  
Aqueous Sodium ◽  
Materials Used ◽  
Scanning Electron

In this experiment, pyrophyllite as the main materials used the flame photometer to measure adsorption. Using the qualitative analysis of the samples of XRD with internal structure and found that pyrophyllite used in the experiment as a natural mineral, the presence with other minerals. Meanwhile, scanning electron micrographs (SEM) from the display showed that the effect of pyrophyllite adsorption for cations should be more significant. Therefore, this experiment focused on the time, Na+ concentration, on the pyrophyllite and different pyrophyllite concentrations (adsorbent dosage) effect on the adsorption, in addition to the adsorption dynamics. The results showed that pyrophyllite adsorption sodium in the best time of equilibrium was 20 minutes, the concentration of NaCl was 50 mg/L, pH = 7, temperature was 313 K, the concentration of pyrophyllite was 5 mg/L.

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