Bond coating issues in thermal barrier coatings for industrial gas turbines

2005 ◽  
Vol 219 (2) ◽  
pp. 101-107 ◽  
Author(s):  
I. G. Wright ◽  
B. A. Pint
Keyword(s):  
High Temperature ◽  
Oxide Layer ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Metallic Surface ◽  
Thermal Barrier ◽  
Protective Oxide ◽  
Barrier Coatings ◽  
Bond Coating ◽  
Industrial Gas Turbines

Thermal barrier coatings are intended to work in conjunction with internal cooling schemes to reduce the metal temperature of critical hot gas path components in gas turbine engines. The thermal resistance is typically provided by a 100-250 μm thick layer of ceramic (most usually zirconia stabilized with an addition of 7–8 wt% of yttria), and this is deposited on to an approximately 50 μ thick, metallic bond coating that is intended to anchor the ceramic to the metallic surface, to provide some degree of mechanical compliance, and to act as a reservoir of protective scale-forming elements (Al) to protect the underlying superalloy from high-temperature corrosion. A feature of importance to the durability of thermal barrier coatings is the early establishment of a continuous, protective oxide layer (preferably α-alumina) at the bond coating—ceramic interface. Because zirconia is permeable to oxygen, this oxide layer continues to grow during service. Some superalloys are inherently resistant to high-temperature oxidation, so a separate bond coating may not be needed in those cases. Thermal barrier coatings have been in service in aeroengines for a number of years, and the use of this technology for increasing the durability and/or efficiency of industrial gas turbines is currently of significant interest. The data presented were taken from an investigation of routes to optimize bond coating performance, and the focus of the paper is on the influences of reactive elements and Pt on the oxidation behaviour of NiAl-based alloys determined in studies using cast versions of bond coating compositions.

The Effect of Laser Glazing on High Temperature Oxidation Resistance of Thermal Barrier Coatings

2012 ◽  
Vol 433-440 ◽  
pp. 315-318
Author(s):  
Seyid Fehmi Diltemiz ◽  
Melih Cemal Kushan
Keyword(s):  
High Temperature ◽  
Oxidation Resistance ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
High Temperature Oxidation ◽  
304 Stainless Steel ◽  
Thermal Barrier ◽  
Laser Glazing ◽  
Temperature Oxidation ◽  
Barrier Coatings

Thermal barrier coatings (TBCs) have been widely used by aero and land based gas turbines to protect hot section parts from oxidation and thermal loads. These coatings are generally consisting of multiple layers of coating (usually two) with each layer having a specific function. TBCs are generally deposited with air plasma spray (APS) or electron beam physical vapor deposition (EB-PVD) techniques. In this paper plasma sprayed TBCs were deposited on to 304 stainless steel substrates then ceramic surfaces were glazing with Nd-YAG laser. Metallographic examinations were applied to the samples to investigate microstructural changes in glazed ceramic layer. Both glazed and as-coated samples were subjected to oxidation tests to measure the high temperature oxidation resistance. The tests showed that, laser glazing is beneficial to oxidation resistance of TBCs. This improvement is attributed to sintering of zirconia layer which act as oxygen barrier and formed during glazing process.

Fundamental Coating Development Study to Improve the Isothermal Oxidation Resistance and Thermal Cycle Durability of Thermal Barrier Coatings

2006 ◽  
Vol 522-523 ◽  
pp. 247-254 ◽  
Author(s):  
Taiji Torigoe ◽  
Hidetaka Oguma ◽  
Ikuo Okada ◽  
Guo Chun Xu ◽  
Kazuhisa Fujita ◽  
...  
Keyword(s):  
High Temperature ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Turbine Blades ◽  
Atmospheric Plasma ◽  
Zirconia Ceramic ◽  
Thermal Barrier ◽  
Temperature Oxidation ◽  
Barrier Coatings ◽  
Oxidation Properties

Thermal barrier coatings(TBCs) are used in high temperature gas turbines to reduce the surface temperature of cooled metal parts such as turbine blades[1]. TBC consist of a bondcoat (e.g. MCrAlY where M is Co, Ni, CoNi, etc.) and a partially stabilized zirconia ceramic topcoat. Usually, the MCrAlY bondcoat is applied by LPPS (low pressure plasma spray) or HVOF(high velocity oxi-fuel spray). The topcoat is applied by APS (atmospheric plasma splay) or EB-PVD (electron beam-physical vapor deposition). High temperature oxidation properties, thermal barrier properties and durability of TBC are very important to increase the reliability in high temperature service. In this study, new TBC has been investigated. The new TBC consists of a two-layered bondcoat (LPPS-MCrAlY plus dense PVD overlay MCrAlY) and the EB-PVD type YSZ columnar structure topcoat. As a result of evaluation tests, it was confirmed that the new TBC had better oxidation properties and durability than a conventional TBC system.

scholarly journals Effects of Alloy Composition on the Performance of Yttria Stabilized Zirconia–Thermal Barrier Coatings

1999 ◽  
Author(s):  
Josh Kimmel ◽  
Zaher Mutasim ◽  
William Brentnall
Keyword(s):  
Gas Turbine ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Base Alloy ◽  
Critical Factor ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Turbine Component ◽  
Industrial Gas Turbines ◽  
Materials Used

Thermal barrier coatings (TBCs) provide an alloy surface temperature reduction when applied to turbine component surfaces. Thermal barrier coatings can be used as a tool for the designer to augment the power and/or enhance the efficiency of gas turbine engines. TBCs have been used successfully in the aerospace industry for many years, with only limited use for industrial gas turbine applications. Industrial gas turbines operate for substantially longer cycles and time between overhauls, and thus endurance becomes a critical factor. There are many factors that affect the life of a TBC including the composition and microstructure of the base alloy and bond coating. Alloys such as Mar-M 247, CMSX-4 and CMSX-10 are materials used for high temperature turbine environments, and usually require protective and/or thermal barrier coatings for increased performance. Elements such as hafnium, rhenium, and yttrium have shown considerable improvements in the strength of these alloys. However these elements may result in varying effects on the coatability and environmental performance of these alloys. This paper discusses the effects of these elements on the performance of thermal barrier coatings.

High-Temperature Performance of Self-Healing SiC-YSZ Thermal Barrier Coatings Deposited by Using Various Plasma Spray Concepts

2021 ◽  
Author(s):  
Mohammad Hassanzadeh ◽  
Paweł Sokołowski ◽  
Radek Musalek ◽  
Jan Medricky ◽  
Stefan Csaki
Keyword(s):  
High Temperature ◽  
Thermal Barrier Coatings ◽  
Plasma Spray ◽  
Gas Turbines ◽  
Isothermal Oxidation ◽  
Atmospheric Plasma ◽  
Flash Method ◽  
Thermal Barrier ◽  
Self Healing ◽  
Barrier Coatings

Abstract In this study; a novel self-healing concept is considered in order to increase the lifetime of thermal barrier coatings (TBCs) in modern gas turbines. For that purpose; SiC healing particles were introduced to conventional 8YSZ topcoats by using various plasma spray concepts; i.e.; composite or multilayered coatings. All topcoats were sprayed by SG-100 plasma torch on previously deposited NiCrAlY bondcoats produced by conventional atmospheric plasma spraying. Coatings were subjected to thermal conductivity measurements by laser flash method up to 1000°C; isothermal oxidation testing up to 200h at 1100°C and finally thermal cyclic fatigue (TCF) lifetime testing at 1100°C. Microstructural coating evaluation was performed by scanning electronic microscope (SEM); in the as-produced and post high-temperature tested states. This was done to analyze the self-healing phenomena and its influence on the hightemperature performance of the newly developed TBCs.

Effects of Alloy Composition on the Performance of Yttria Stabilized Zirconia—Thermal Barrier Coatings

2000 ◽  
Vol 122 (3) ◽  
pp. 393-400 ◽  
Author(s):  
Josh Kimmel ◽  
Zaher Mutasim ◽  
William Brentnall
Keyword(s):  
Gas Turbine ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Base Alloy ◽  
Critical Factor ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Turbine Component ◽  
Industrial Gas Turbines ◽  
Materials Used

Thermal barrier coatings (TBCs) provide an alloy surface temperature reduction when applied to turbine component surfaces. Thermal barrier coatings can be used as a tool for the designer to augment the power and/or enhance the efficiency of gas turbine engines. TBCs have been used successfully in the aerospace industry for many years, with only limited use for industrial gas turbine applications. Industrial gas turbines operate for substantially longer cycles and time between overhauls, and thus endurance becomes a critical factor. There are many factors that affect the life of a TBC including the composition and microstructure of the base alloy and bond coating. Alloys such as Mar-M 247, CMSX-4, and CMSX-10 are materials used for high temperature turbine environments, and usually require protective and/or thermal barrier coatings for increased performance. Elements such as hafnium, rhenium, and yttrium have shown considerable improvements in the strength of these alloys. However, these elements may result in varying effects on the coatability and environmental performance of these alloys. This paper discusses the effects of these elements on the performance of thermal barrier coatings. [S0742-4795(00)02603-X]

Life Prediction of High-Temperature MCrAlY Coatings Based on Microstructural Observations

2014 ◽  
Vol 922 ◽  
pp. 143-148 ◽  
Author(s):  
Robert Eriksson ◽  
Kang Yuan ◽  
Sten Johansson ◽  
Ru Lin Peng ◽  
Xin Hai Li
Keyword(s):  
High Temperature ◽  
Thermal Barrier Coatings ◽  
Bond Coat ◽  
Gas Turbines ◽  
Life Prediction ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Mcraly Coatings ◽  
Barrier Coating ◽  
Coating Composition

Thermal barrier coatings are commonly used in gas turbines for protection against high tem-perature and oxidation. Life prediction of oxidation protective coatingsmay be done bymicrostructure-based techniques such as -depletion based life criteria. In this study, a thermal barrier coating sys-tem, with an overlay NiCoCrAlY coating as bond coat, was oxidised up to 10000 h at 900 C. Themicrostructure was studied and related to Al depletion. It was found that a -depletion based lifecriterion could not be used for the studied coating composition and temperature as it would be tooconservative. A 0-depletion based model was instead suggested and supported by interdiffusion sim-ulation.

scholarly journals The Effect of Coating Composition and Geometry on Thermal Barrier Coatings Lifetime

2018 ◽  
Vol 141 (3) ◽  
Author(s):  
Bruce A. Pint ◽  
Michael J. Lance ◽  
J. Allen Haynes
Keyword(s):  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Average Lifetime ◽  
Thermal Barrier ◽  
Air Plasma ◽  
Barrier Coatings ◽  
Bond Coatings ◽  
Bond Coating ◽  
Negative Effect ◽  
Plasma Sprayed

Several factors are being investigated that affect the performance of thermal barrier coatings (TBC) for use in land-based gas turbines where coatings are mainly thermally sprayed. This study examined high velocity oxygen fuel (HVOF), air plasma-sprayed (APS), and vacuum plasma-sprayed (VPS) MCrAlYHfSi bond coatings with APS YSZ top coatings at 900–1100 °C. For superalloy 247 substrates and VPS coatings tested in 1 h cycles at 1100 °C, removing 0.6 wt %Si had no effect on average lifetime in 1 h cycles at 1100 °C, but adding 0.3%Ti had a negative effect. Rod specimens were coated with APS, HVOF, and HVOF with an outer APS layer bond coating and tested in 100 h cycles in air + 10%H2O at 1100 °C. With an HVOF bond coating, initial results indicate that 12.5 mm diameter rod specimens have much shorter 100 h cycle lifetimes than disk specimens. Much longer lifetimes were obtained when the bond coating had an inner HVOF layer and outer APS layer.

Effects of EB-PVD Process TGO Formation and Growth within Thermal Barrier Coatings

2007 ◽  
Vol 546-549 ◽  
pp. 1781-1788 ◽  
Author(s):  
Li Min He
Keyword(s):  
High Temperature ◽  
Oxide Layer ◽  
Thermal Barrier Coatings ◽  
Mixed Oxide ◽  
Physical Vapor Deposition ◽  
High Temperature Oxidation ◽  
Thermal Barrier ◽  
Al2o3 Layer ◽  
Temperature Oxidation ◽  
Barrier Coatings

It has been found that under oxygen partial pressure of ~2×10-6 kPa, the high-temperature oxidation of thermal barrier coatings (TBCs) occurred during an electron beam physical vapor deposition (EB-PVD) process for producing the TBCs top ceramic coating. In the present investigation, two modified bond coats (BCs) of NiCrAlY with Si addition, and NiCrAlY with Co and Hf additions, were developed by Arc Ion-plating technique to study the effects of the EB-PVD process on thermally grown oxide (TGO) formation and growth. The isothermal and cyclic oxidation tests were conducted and the cross-sectional morphologies of the specimens were examined to compare the high-temperature oxidation behaviors of the two TBCs. It was found that a mixed oxide layer have been developed in the as-deposited TBCs with a NiCrAlYSi BC. The mixed oxide layer mainly included Cr2O3, NiO, Al2O3 and their spinel. With the mixed oxide layer, TBCs with the NiCrAlYSi BC showed a superior high-temperature resistance on later high-temperature exposure to TBCs with NiCoCrAlYHf BC, where no mixed oxide layer was observed. The pre-formed mixed oxide layer apparently shortened the time to fully develop a protective α-Al2O3 layer and therefore restrained the TGO growth in TBCs.

Modelling Failures of Thermal Barrier Coatings

2007 ◽  
Vol 333 ◽  
pp. 155-166 ◽  
Author(s):  
Anette M. Karlsson
Keyword(s):  
High Temperature ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Metal Substrate ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Design Engineers ◽  
Material Physics ◽  
Temperature Exposure ◽  
And Diffusion

Thermal barrier coatings are commonly used in high temperature parts of gas turbines, to protect the underlying metal substrate from deterioration during high temperature exposure. Unfortunately, the coatings fail prematurely, preventing the design engineers to fully utilize their implementation. Due to the complexity of the coatings, there are many challenges involved with developing failure hypotheses for the failures. This paper reviews some aspects of the current stateof- the-art on modeling failures of thermal barrier coatings, focusing on mechanics based models (such as finite element simulations) where the material physics is incorporated (such as oxidation and diffusion).

Thermal Cycling Fatigue of Thermal Barrier Coatings - Rig and Experiment Design

2014 ◽  
Vol 891-892 ◽  
pp. 641-646
Author(s):  
Robert Eriksson ◽  
Hakan Brodin ◽  
Sten Johansson ◽  
Lars Östergren ◽  
Xin Hai Li
Keyword(s):  
High Temperature ◽  
Thermal Cycling ◽  
Cooling Rate ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Coefficient Of Thermal Expansion ◽  
Thermal Barrier ◽  
Short Side ◽  
Metallic Component ◽  
Barrier Coatings

Ceramic thermal barrier coatings are used for thermal insulation in gas turbines to protect metallic components from high-temperature degradation. The ceramic coating may, due to its different coefficient of thermal expansion, crack and spall off the metallic component, thus rendering the component unprotected against high-temperature. Thermal cycling rigs of various designs are used to evaluate the durability of thermal barrier coatings. The present paper reports the result from a round robin test including three thermal cycling rigs at different locations. To better understand the influence of rig design on the thermal cyclic lives of thermal barrier coatings, some test parameters, such as the material of the specimen table and the cooling rate, were varied in one of the rigs. Furthermore, two different specimen geometries, rectangular and disc-shaped, were tested. The specimen table material was found to greatly influence the cooling rate of the specimens, more so than variations in the cooling airflow. The rectangular specimens were found to be more sensitive to test setup than the disc-shaped specimens; under certain conditions, the rectangular specimens could be made to fracture from the long side, rather than the short side of the specimen edge, which shortened the thermal cyclic life of the coatings.

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