Thiolate-based one-dimensional flexible Pb–MOFs exhibiting a large sorption hysteresis phenomenon

2021 ◽  
Author(s):  
Yoshinobu Kamakura ◽  
Ryo Hamano ◽  
Yuiga Nakamura ◽  
Kunihisa Sugimoto ◽  
Hirofumi Yoshikawa ◽  
...  
2019 ◽  
Vol 128 ◽  
pp. 07006 ◽  
Author(s):  
Maroua Maaroufi ◽  
Kamilia Abahri ◽  
Fares Bennai ◽  
Rafik Belarbi

The walls of buildings experience heat, air and moisture transfers. These transfers have a significant influence on indoor climate, since they affect the value of temperature and relative humidity inhouses. High levels of humidity lead to pathologies in the buildings, and influence the air quality and the hygrothermal comfort of the occupants. In this work, a numerical analysis of the behaviour of polystyrene mortar under hydric solicitations was led. The simulations were held using ComsolMultiphysics and MATLAB. There were two different moisture transfer models used in this work: the first one took into account sorption hysteresis phenomenon, and the other one did not. The computed results showed that considering sorption hysteresis in modelling the hydric behaviour of the material allows obtaining more accurate results comparing to a model that does not consider hysteresis.


2014 ◽  
Vol 752 ◽  
pp. 184-218 ◽  
Author(s):  
Akira Umemura ◽  
Jun Osaka

AbstractIt is well known that water slowly issued vertically downward exhibits a hysteresis phenomenon. A jetting-to-dripping transition appearing upon a stepwise decrease in jet issue speed was used to identify the origin of the Plateau–Rayleigh unstable wave elements which disintegrate the jetting liquid. In the present laboratory experiment using a stainless steel nozzle of inner radius 1 mm and length 30 mm, the transition occurred at a dimensionless jet issue speed of $\def \xmlpi #1{}\def \mathsfbi #1{\boldsymbol {\mathsf {#1}}}\let \le =\leqslant \let \leq =\leqslant \let \ge =\geqslant \let \geq =\geqslant \def \Pr {\mathit {Pr}}\def \Fr {\mathit {Fr}}\def \Rey {\mathit {Re}}\sqrt{\rho U^{2}a_{0} /\sigma } =0.8,$ where $\rho $ and $\sigma $ respectively denote the density and surface tension coefficient of the liquid issued at the speed $U$ from the nozzle of radius $a_0$. The jet length gradually shortened with an oscillation of considerably large amplitude and period. High-speed camera images show that this oscillation is caused by tip contraction capillary wave (TCCW) elements which are elongated by the gravitationally accelerating jet flow and become Plateau–Rayleigh unstable wave elements. The jet length increases while the jet tip experiences end-pinching and radiates TCCW elements upstream. Only those TCCW elements destabilized at appropriate locations can grow sufficiently to shorten the jet. Since the unstable wave elements produced nearer the nozzle exit have much smaller amplitude at the jet tip, the end-pinching becomes effective. Thus, these processes are repeatable and constitute a self-destabilizing loop. The observed jetting-to-dripping transition has nothing to do with the random nozzle disturbances which were believed to be the origin of the Plateau–Rayleigh unstable wave in conventional instability theories. It is also different from the feature conjectured from current absolute/convective instability analysis. The underling physics of the self-destabilizing loop are explored in detail by numerical simulations based on a one-dimensional model.


Author(s):  
Maroua Maaroufi ◽  
Kamilia Abahri ◽  
Alexandra Bourdot ◽  
Chady El Hachem

Buildings are responsible for a large portion of the total energy consumption, and have a heavy environmental impact. Wood is one of the most used bio-based building materials, as it helps reducing the environmental footprint of the construction sector. Spruce wood is widely available in France and therefore massively used in buildings. It has interesting thermal and acoustic insulation performances and a good hydric regulation property. Spruce wood microstructure is highly heterogeneous and multiphasic, which makes it harder to apprehend. On the other hand, sorption hysteresis phenomenon is responsible for the moisture accumulation in porous building materials. It is often neglected in hygrothermal transfers modelling, which leads to incorrect water content values. The aim of this work is to investigate the influence of the sorption hysteresis phenomenon on the hydric transfers of spruce wood. The heterogeneity of the microstructure is also considered through 3D tomographic reconstructions included in the modelling.


1966 ◽  
Vol 25 ◽  
pp. 46-48 ◽  
Author(s):  
M. Lecar

“Dynamical mixing”, i.e. relaxation of a stellar phase space distribution through interaction with the mean gravitational field, is numerically investigated for a one-dimensional self-gravitating stellar gas. Qualitative results are presented in the form of a motion picture of the flow of phase points (representing homogeneous slabs of stars) in two-dimensional phase space.


Author(s):  
Teruo Someya ◽  
Jinzo Kobayashi

Recent progress in the electron-mirror microscopy (EMM), e.g., an improvement of its resolving power together with an increase of the magnification makes it useful for investigating the ferroelectric domain physics. English has recently observed the domain texture in the surface layer of BaTiO3. The present authors ) have developed a theory by which one can evaluate small one-dimensional electric fields and/or topographic step heights in the crystal surfaces from their EMM pictures. This theory was applied to a quantitative study of the surface pattern of BaTiO3).


Author(s):  
Peter Sterling

The synaptic connections in cat retina that link photoreceptors to ganglion cells have been analyzed quantitatively. Our approach has been to prepare serial, ultrathin sections and photograph en montage at low magnification (˜2000X) in the electron microscope. Six series, 100-300 sections long, have been prepared over the last decade. They derive from different cats but always from the same region of retina, about one degree from the center of the visual axis. The material has been analyzed by reconstructing adjacent neurons in each array and then identifying systematically the synaptic connections between arrays. Most reconstructions were done manually by tracing the outlines of processes in successive sections onto acetate sheets aligned on a cartoonist's jig. The tracings were then digitized, stacked by computer, and printed with the hidden lines removed. The results have provided rather than the usual one-dimensional account of pathways, a three-dimensional account of circuits. From this has emerged insight into the functional architecture.


Author(s):  
A.Q. He ◽  
G.W. Qiao ◽  
J. Zhu ◽  
H.Q. Ye

Since the first discovery of high Tc Bi-Sr-Ca-Cu-O superconductor by Maeda et al, many EM works have been done on it. The results show that the superconducting phases have a type of ordered layer structures similar to that in Y-Ba-Cu-O system formulated in Bi2Sr2Can−1CunO2n+4 (n=1,2,3) (simply called 22(n-1) phase) with lattice constants of a=0.358, b=0.382nm but the length of c being different according to the different value of n in the formulate. Unlike the twin structure observed in the Y-Ba-Cu-O system, there is an incommensurate modulated structure in the superconducting phases of Bi system superconductors. Modulated wavelengths of both 1.3 and 2.7 nm have been observed in the 2212 phase. This communication mainly presents the intergrowth of these two kinds of one-dimensional modulated structures in 2212 phase.


Author(s):  
J. Fink

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.


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