scholarly journals Influence of Heating Rates on Kinetic Parameters of Hydrocarbon Generation from Organic Matter

2013 ◽  
Vol 03 (01) ◽  
pp. 1-7
Author(s):  
民 王
Keyword(s):  
Organic Matter ◽  
Kinetic Parameters ◽  
Hydrocarbon Generation ◽  
Heating Rates

scholarly journals A comprehensive study of the high temperature pyrolysis of sewage sludge: kinetics, energy analysis and products formation

2021 ◽  
Keyword(s):  
Organic Matter ◽  
High Temperature ◽  
Sewage Sludge ◽  
Kinetic Parameters ◽  
Energy Requirement ◽  
Liquid Product ◽  
Mineral Matter ◽  
Heating Rates ◽  
Temperature Zone ◽  
Inorganic Matter

<p>This study evaluates the pyrolysis of sewage sludge until 960 °C using heating rates between 3 K/min and 12 K/min in a macro TG/EGA. Mass and energy balances and kinetic parameters are determined. Thermal decomposition is divided into a low temperature zone (until 550 °C to 590 °C), for decomposition of organic matter, and a high temperature zone, for decomposition of inorganic matter and secondary reactions of the residual organic matter. In dry basis at 570 °C solid, liquid and gaseous products amount to 69.2 wt.-%, 29.2 wt.-% and 1.6 wt.-%, respectively. An increment in the final temperature to 960 °C causes a successive decrease of the solid residue to 56.9 wt.-%. The solid product contains more than 80 wt.-% mineral matter with high amounts of valuable elements, such as Ca and P. An energy requirement of 2.18 MJ/kg of dry sewage sludge is calculated for the pyrolysis until 570 °C. At this temperature, 58.5 % of the energy entering the process is concentrated in the liquid product and 40.0 % in the solid. A suitable set of kinetic parameters is determined through a formal independent parallel reactions model with six-pseudo components, using a combination of isoconversional and fitting methods.</p>

scholarly journals Kinetic Parameters of Nut Shells Pyrolysis

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 682
Author(s):  
Tomasz Noszczyk ◽  
Arkadiusz Dyjakon ◽  
Jacek A. Koziel
Keyword(s):  
Kinetic Parameters ◽  
Waste Treatment ◽  
Model Fitting ◽  
Thermal Conversion ◽  
Point Of View ◽  
The European Union ◽  
Heating Rates ◽  
Isothermal Model ◽  
Biomass Residues ◽  
Conversion Point

The European Union created a European Green Deal Program (EGDP). This program aims at a sustainable economy through the transformation of the challenges related to climate and the environment. The main goal of EGDP is climate neutrality by 2050. The increase of alternative biomass residues utilization from various food processing industries and cooperation in the energy and waste management sector is required to meet these expectations. Nut shells are one of the lesser-known, yet promising, materials that can be used as an alternative fuel or a pre-treated product to further applications. However, from a thermal conversion point of view, it is important to know the energy properties and kinetic parameters of the considered biowaste. In this study, the energy and kinetic parameters of walnut, hazelnut, peanut, and pistachio shells were investigated. The results showed that raw nut shells are characterized by useful properties such as higher heating value (HHV) at 17.8–19.7 MJ∙kg−1 and moisture content of 4.32–9.56%. After the thermal treatment of nut shells (torrefaction, pyrolysis), the HHV significantly increased up to ca. 30 MJ∙kg−1. The thermogravimetric analysis (TGA) applying three different heating rates (β; 5, 10, and 20 °C∙min−1) was performed. The kinetic parameters were determined using the isothermal model-fitting method developed by Coats–Redfern. The activation energy (Ea) estimated for β = 5 °C∙min−1, was, e.g., 60.3 kJ∙mol−1∙K−1 for walnut, 59.3 kJ∙mol−1∙K−1 for hazelnut, 53.4 kJ∙mol−1∙K−1 for peanut, and 103.8 kJ∙mol−1∙K−1 for pistachio, respectively. Moreover, the increase in the Ea of nut shells was observed with increasing the β. In addition, significant differences in the kinetic parameters of the biomass residues from the same waste group were observed. Thus, characterization of specific nut shell residues is recommended for improved modeling of thermal processes and designing of bioreactors for thermal waste treatment.

scholarly journals Genetic mechanisms and distribution characteristics of overpressures in the Paleogene reservoirs of the Bohai Bay Basin, East China

2018 ◽  
Vol 36 (3) ◽  
pp. 388-413 ◽  
Author(s):  
Fanghao Xu ◽  
Jiaju Liang ◽  
Guosheng Xu ◽  
Haifeng Yuan ◽  
Yong Liu
Keyword(s):  
Organic Matter ◽  
Oil And Gas ◽  
Bohai Bay ◽  
Hydrocarbon Generation ◽  
Distribution Characteristics ◽  
Well Drilling ◽  
The Third ◽  
Genetic Mechanisms ◽  
Shahejie Formation ◽  
Tectonic Framework

The Bohai Bay region is a primary accumulation area of oil and gas in offshore China, in which overpressure commonly occurs in the Paleogene strata; the analysis on distribution characteristics and genetic mechanisms of the overpressure would provide geologic evidences for making plans of well drilling and logging as well as oil and gas exploitation; additionally, it could lay the geological foundation for studying how overpressure controlled hydrocarbon accumulation. Based on research, the overpressure of the study area starts from the second member of the Dongying Formation and ends in the third member of the Shahejie Formation. The distribution of overpressure is mainly controlled by the sag–salient tectonic framework within the basin, which means overpressure mainly develops in sags or slopes; however, high areas stay normal pressured. In the study area, pressure develops around Bozhong Sag and in northern Liaodong Bay reaches the peak. The genetic mechanisms of overpressures in the Paleogene reservoirs are mainly disequilibrium compaction, hydrocarbon generation of the organic matter, fluid charging, and transmission or the superimposition of the former two. Different strata have different genetic mechanisms of overpressure. The chief genetic mechanisms for the generation of overpressure of the Dongying Formation are disequilibrium compaction while the genesis of the formation of overpressure in the Shahejie Formation is more complicated in some extent. The first member of the Shahejie Formation dominated by disequilibrium compaction and hydrocarbon generation of the organic matter plays a supplemental role, while the second member of the Shahejie Formation, as the primary reservoir strata, is dominated by fluid charging and transmission, and the third member of the Shahejie Formation is the main source rock interval; its overpressure is closely related to hydrocarbon generation. Each contribution ratio for overpressure forming by different genetic mechanisms has been judged and figured out quantitatively according to geological, geophysical, and geochemical characteristics of the target strata.

scholarly journals Characterization of organic matter from a stratigraphic sequence intercepted by the Nemo-1X well, Mozambique: Potential for hydrocarbon generation

2018 ◽  
Vol 36 (5) ◽  
pp. 1157-1171
Author(s):  
Agostinho Mussa ◽  
Deolinda Flores ◽  
Joana Ribeiro ◽  
Ana MP Mizusaki ◽  
Mónica Chamussa ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Hydrocarbon Exploration ◽  
Published Data ◽  
Organic Carbon Content ◽  
Hydrocarbon Generation ◽  
Offshore Area ◽  
Type Iii ◽  
Kerogen Type

The Mozambique Basin, which occurs onshore and offshore in the central and southern parts of Mozambique, contains a thick sequence of volcanic and sedimentary rocks that range in age from the Jurassic to Cenozoic. This basin, along with the Rovuma basin to the north, has been the main target for hydrocarbon exploration; however, published data on hydrocarbon occurrences do not exist. In this context, the present study aims to contribute to the understanding of the nature of the organic matter of a sedimentary sequence intercepted by the Nemo-1X exploration well located in the offshore area of the Mozambique Basin. The well reached a depth of 4127 m, and 33 samples were collected from a depth of 2219–3676 m ranging in age from early to Late Cretaceous. In this study, petrographic and geochemical analytical methods were applied to assess the level of vitrinite reflectance and the organic matter type as well as the total organic carbon, total sulfur, and CaCO3 contents. The results show that the total organic carbon content ranges from 0.41 to 1.34 wt%, with the highest values determined in the samples from the Lower Domo Shale and Sena Formations, which may be related to the presence of the solid bitumens that occur in the carbonate fraction of those samples. The vitrinite random reflectances range from 0.65 to 0.86%Rrandom, suggesting that the organic matter in all of the samples is in the peak phase of the “oil generation window” (0.65–0.9%Rrandom). The organic matter is mainly composed of vitrinite and inertinite macerals, with a minor contribution of sporinite from the liptinite group, which is typical of kerogen type III. Although all of the samples have vitrinite reflectances corresponding to the oil window, the formation of liquid hydrocarbons is rather limited because the organic matter is dominated by gas-prone kerogen type III.

scholarly journals Curing Kinetic Parameters of Epoxy Composite Reinforced with Mallow Fibers

Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3939 ◽  
Author(s):  
Lucio Fabio Cassiano Nascimento ◽  
Fernanda Santos da Luz ◽  
Ulisses Oliveira Costa ◽  
Fábio de Oliveira Braga ◽  
Édio Pereira Lima Júnior ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Industrial Process ◽  
Diglycidyl Ether ◽  
Response Surfaces ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Exponential Factor ◽  
Curing Kinetic ◽  
Technological Tool

Knowledge about the curing behavior of a thermosetting resin and its composites includes the determination of kinetic parameters and constitutes an important scientific and technological tool for industrial process optimization. In the present work, the differential scanning calorimetry (DSC) technique was used to determine several curing parameters for pure epoxy and its composite reinforced with 20 vol % mallow fibers. Analyses were performed with heating rates of 5, 7.5, and 10 °C/min, as per the ASTM E698 standard. The kinetic related parameters, that is, activation energy (E), Avrami’s pre-exponential factor (Z), and mean time to reach 50% cure (t½), were obtained for the materials, at temperatures ranging from 25 to 100 °C. Response surfaces based on the mathematical relationship between reaction time, transformed fraction, and temperature were provided for optimization purposes. The results showed that the average curing time used for the production of diglycidyl ether of bisphenol A/triethylenetetramine (DGEBA/TETA) epoxy systems or their composites reinforced with natural mallow fibers can be considerably reduced as the temperature is increased up to a certain limit.

Sign in / Sign up

Export Citation Format

Share Document