scholarly journals MINERAL CARBONATION AS A POTENTIAL CARBON DIOXIDE STORAGE OPTION FOR THE REGION OF WESTERN MACEDONIA, GREECE

2007 ◽  
Vol 40 (2) ◽  
pp. 872
Author(s):  
N. Koukouzas ◽  
H. Ziock ◽  
F. Ziogou ◽  
I. Typou
Keyword(s):  
Carbon Dioxide ◽  
Co2 Emissions ◽  
Power Plants ◽  
Exothermic Reaction ◽  
Magnesium Silicate ◽  
Mineral Carbonation ◽  
Carbon Dioxide Storage ◽  
Carbonation Reaction ◽  
Carbonation Process ◽  
Long Term Storage

The long-term storage of the greenhouse gas C02 generated by fossil fuel-fired power plants in the form of stable mineral carbonates appears to be a promising option for reducing global CO2 emissions. In the case of mineral carbonation captured gaseous CO2 is chemically stored in an exothermic reaction by the carbonation of magnesium or calcium silicate minerals, forming environmentally benign and thermodynamically stable products. The purpose of this paper is to give an overview of the carbon dioxide storage by mineral carbonation and to examine the feasibility of this sequestration option in the region of Western Macedonia. The main candidate minerals for carbonation and their sequestration capacity are presented. Furthermore, the most promising mineral carbonation process routes as well as the thermodynamics and kinetics of carbonation reaction are addressed, based on a review on the published literature. In Greece abundant magnesium-rich ultramafic rocks exist that probably could support the national CO2 emissions abatement policy. The attractiveness stems from the favourable geographical relationship between large stationary CO2 emission sources and potential magnesium silicate deposits. Thus, a roughly description of the olivine deposits and their quality in the region of Western Macedonia will be provided

scholarly journals Mineral carbonation process of carbon dioxide using animal bone

2021 ◽  
Vol 104 (2) ◽  
pp. 003685042110196
Author(s):  
Brendon Mpofu ◽  
Hembe E Mukaya ◽  
Diakanua B Nkazi
Keyword(s):  
Carbon Dioxide ◽  
Carbon Capture ◽  
Carbon Capture And Storage ◽  
Economic Feasibility ◽  
Mineral Carbonation ◽  
Agitation Rate ◽  
Carbonation Reaction ◽  
Carbonation Process ◽  
The Cost ◽  
Cow Bone

Carbon dioxide has been identified as one of the greenhouse gases responsible for global warming. Several carbon capture and storage technologies have been developed to mitigate the large quantities of carbon dioxide released into the atmosphere, but these are quite expensive and not easy to implement. Thus, this research analyses the technical and economic feasibility of using calcium leached from cow bone to capture and store carbon dioxide through the mineral carbonation process. The capturing process of carbon dioxide was successful using the proposed technique of leaching calcium from cow shinbone (the tibia) in the presence of HCl by reacting the calcium solution with gaseous carbon dioxide. AAS and XRF analysis were used to determine the concentration of calcium in leached solutions and the composition of calcium in cow bone respectively. The best leaching conditions were found to be 4 mole/L HCl and leaching time of 6 h. Under these conditions, a leaching efficiency of 91% and a calcium conversion of 83% in the carbonation reaction were obtained. Other factors such as carbonation time, agitation rate, and carbonation reaction temperature had little effect on the yield. A preliminary cost analysis showed that the cost to capture 1 ton of CO2 with the proposed technique is about US$ 268.32, which is in the acceptable range of the capturing process. However, the cost of material used and electricity should be reviewed to reduce the preliminary production cost.

scholarly journals Influencing Factors of the Mineral Carbonation Process of Iron Ore Mining Waste in Sequestering Atmospheric Carbon Dioxide

2021 ◽  
Vol 13 (4) ◽  
pp. 1866
Author(s):  
Noor Allesya Alis Ramli ◽  
Faradiella Mohd Kusin ◽  
Verma Loretta M. Molahid
Keyword(s):  
Carbon Dioxide ◽  
Particle Size ◽  
Chemical Composition ◽  
Iron Ore ◽  
Divalent Cations ◽  
Mining Industry ◽  
Mining Waste ◽  
Aluminum Silicate ◽  
Mineral Carbonation ◽  
Carbonation Process

Mining waste may contain potential minerals that can act as essential feedstock for long-term carbon sequestration through a mineral carbonation process. This study attempts to identify the mineralogical and chemical composition of iron ore mining waste alongside the effects of particle size, temperature, and pH on carbonation efficiency. The samples were found to be alkaline in nature (pH of 6.9–7.5) and contained small-sized particles of clay and silt, thus indicating their suitability for mineral carbonation reactions. Samples were composed of important silicate minerals needed for the formation of carbonates such as wollastonite, anorthite, diopside, perovskite, johannsenite, and magnesium aluminum silicate, and the Fe-bearing mineral magnetite. The presence of Fe2O3 (39.6–62.9%) and CaO (7.2–15.2%) indicated the potential of the waste to sequester carbon dioxide because these oxides are important divalent cations for mineral carbonation. The use of small-sized mine-waste particles enables the enhancement of carbonation efficiency, i.e., particles of <38 µm showed a greater extent of Fe and Ca carbonation efficiency (between 1.6–6.7%) compared to particles of <63 µm (0.9–5.7%) and 75 µm (0.7–6.0%). Increasing the reaction temperature from 80 °C to 150–200 °C resulted in a higher Fe and Ca carbonation efficiency of some samples between 0.9–5.8% and 0.8–4.0%, respectively. The effect of increasing the pH from 8–12 was notably observed in Fe carbonation efficiency of between 0.7–5.9% (pH 12) compared to 0.6–3.3% (pH 8). Ca carbonation efficiency was moderately observed (0.7–5.5%) as with the increasing pH between 8–10. Therefore, it has been evidenced that mineralogical and chemical composition were of great importance for the mineral carbonation process, and that the effects of particle size, pH, and temperature of iron mining waste were influential in determining carbonation efficiency. Findings would be beneficial for sustaining the mining industry while taking into account the issue of waste production in tackling the global carbon emission concerns.

scholarly journals The Assesment for CO2 Sequestration Potential by Magnesium silicate Minerals in Turkey: Cases of Orhaneli-Bursa and Divrigi-Sivas Regions

2008 ◽  
Vol 26 (5) ◽  
pp. 293-309 ◽  
Author(s):  
K. Baris ◽  
A. Ozarslan ◽  
N. Sahin
Keyword(s):  
Co2 Sequestration ◽  
Power Plants ◽  
Thermal Power ◽  
Magnesium Silicate ◽  
Open Pit ◽  
Mineral Carbonation ◽  
Silicate Mineral ◽  
Open Pit Mines ◽  
Silicate Minerals ◽  
Sequestration Potential

This paper examines the CO2 sequestration potential of magnesium silicate minerals in Turkey for two example cases, the Orhaneli-Bursa and Divrigi-Sivas regions. The distribution and properties of the silicate mineral deposits are provided and the quantities of CO2 that can be sequestered in these deposits is estimated. The silicate minerals in the Orhaneli and Divrigi deposits provide significant CO2 sequestration capacity. Assuming 100% mineral carbonation efficiency, approximately 2.4 million tons/year of olivine and 6.5 million tons/year of serpentine would be required to sequester the CO2 released by the power plants investigated in this study. Although more detailed studies are needed, it is concluded that this approach has potential given Turkey's large dunite (olivine) and serpentine reserves. Furthermore, the proximity of these deposits and active open-pit mines to thermal power plants emitting CO2 facilitate the utilization of mineral carbonation.

scholarly journals Observing carbon dioxide emissions over China's cities and industrial areas with the Orbiting Carbon Observatory-2

2020 ◽  
Vol 20 (14) ◽  
pp. 8501-8510 ◽  
Author(s):  
Bo Zheng ◽  
Frédéric Chevallier ◽  
Philippe Ciais ◽  
Grégoire Broquet ◽  
Yilong Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Co2 Emissions ◽  
Carbon Dioxide Emissions ◽  
Power Plants ◽  
Global Climate ◽  
Large Cities ◽  
Independent Evaluation ◽  
Paris Climate Agreement ◽  
Carbon Dioxide Co2 ◽  
The Individual

Abstract. In order to track progress towards the global climate targets, the parties that signed the Paris Climate Agreement will regularly report their anthropogenic carbon dioxide (CO2) emissions based on energy statistics and CO2 emission factors. Independent evaluation of this self-reporting system is a fast-growing research topic. Here, we study the value of satellite observations of the column CO2 concentrations to estimate CO2 anthropogenic emissions with 5 years of the Orbiting Carbon Observatory-2 (OCO-2) retrievals over and around China. With the detailed information of emission source locations and the local wind, we successfully observe CO2 plumes from 46 cities and industrial regions over China and quantify their CO2 emissions from the OCO-2 observations, which add up to a total of 1.3 Gt CO2 yr−1 that accounts for approximately 13 % of mainland China's annual emissions. The number of cities whose emissions are constrained by OCO-2 here is 3 to 10 times larger than in previous studies that only focused on large cities and power plants in different locations around the world. Our satellite-based emission estimates are broadly consistent with the independent values from China's detailed emission inventory MEIC but are more different from those of two widely used global gridded emission datasets (i.e., EDGAR and ODIAC), especially for the emission estimates for the individual cities. These results demonstrate some skill in the satellite-based emission quantification for isolated source clusters with the OCO-2, despite the sparse sampling of this instrument not designed for this purpose. This skill can be improved by future satellite missions that will have a denser spatial sampling of surface emitting areas, which will come soon in the early 2020s.

scholarly journals Carbon dioxide sequestration by direct mineral carbonation: process mineralogy of feed and products

2002 ◽  
Vol 19 (2) ◽  
pp. 95-101 ◽  
Author(s):  
W. K. O’Connor ◽  
D. C. Dahlin ◽  
G. E. Rush ◽  
C. L. Dahlin ◽  
W. K. Collins
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Sequestration ◽  
Mineral Carbonation ◽  
Carbonation Process ◽  
Process Mineralogy

APPLICATION OF THE CARNOL PROCESS TO PRODUCE METHANOL AND REDUCE CARBON DIOXIDE EMISSIONS

2021 ◽  
Vol 3 (1) ◽  
pp. 104-110
Author(s):  
A. S. SVIRIDOV ◽  
◽  
P. E. NOR ◽  
Keyword(s):  
Carbon Dioxide ◽  
Natural Gas ◽  
Co2 Emissions ◽  
Carbon Dioxide Emissions ◽  
Power Plants ◽  
Raw Materials ◽  
Alternative Fuel ◽  
Raw Material ◽  
Motor Vehicles ◽  
Methanol Production

The Carnol system is the production of methanol from carbon dioxide (obtained from coal-fired power plants) and natural gas, and the use of the resulting methanol as an alternative fuel. The Carnol process produces hydrogen by thermal decomposition of natural gas, which then interacts with the CO2 extracted from the flue emissions of power plants. The resulting carbon can be stored or used as a raw material. The paper provides an estimated characteristic of the reduction of CO2 emissions of the Carnol process and system, and compares it with other traditional methanol production processes, including the use of biomass of industrial raw materials and vehicles powered by methanol fuel cells. CO2 emissions from a Carnol system that uses methanol as an alternative fuel can be reduced by 56 % compared to a conventional coal-fired power plant system. In the case of the use of methanol as fuel for motor vehicles, carbon dioxide emissions.

CO2 Emission Abatement in CC-IGCC Power Plants: Energy and Economic Comparisons

2008 ◽  
Author(s):  
Marco Gambini ◽  
Michela Vellini
Keyword(s):  
Carbon Dioxide ◽  
Natural Gas ◽  
Co2 Emissions ◽  
Power Plants ◽  
Fossil Fuels ◽  
Combined Cycle ◽  
Exhaust Gas ◽  
Gas Treatment ◽  
Low Co2 ◽  
Global Efficiency

In this paper two methodologies, able to avoid CO2 dispersion in atmosphere, have been analyzed: • treating exhaust gases in order to remove, liquefy and store the produced carbon dioxide; • de-carbonizing fossil fuels before using them in the combustion in order to inhibit completely carbon dioxide production. These methodologies have been implemented in advanced power plants based on gas turbine: a combined cycle power plant (CC), fed by natural gas, and an integrated gasification combined cycle (IGCC), fed by coal. The exhaust gas treatment is based on a chemical process of absorption, while the fossil fuel decarbonization is based on partial oxidation of methane, steam methane reforming and coal gasification. These systems require material and energetic integrations with the power sections and so the best interconnections must be investigated in order to obtain good overall performance. With reference to thermodynamic and economic performance, significant comparisons have been made between the above mentioned reference plants. An efficiency decrease and an increase in the cost of electricity have been obtained when power plants are equipped with systems able to reduce CO2 emissions. However, in order to obtain low CO2 emissions when coal is used, the coal decarbonization must be implemented: in this case it is possible to attain a global efficiency of about 38%, a specific emission of 0.1117 kg/kWh and an increase of kWh cost of about 32%. Vice versa, in order to obtain low CO2 emissions when natural gas is used, the exhaust gas treatment must be implemented: in this case it is possible to attain a global efficiency of about 50.7%, a specific emission of 0.0391 kg/kWh and an increase of kWh cost of about 15%. The clean use of coal seems to have good potential because it allows low energy penalizations (about 7.5 percentage points) and economic increases of about 32%. Because of the great availability, the homogeneous distribution and the low cost of this fuel, these results seem to be very interesting especially in the viewpoint of a transition towards the “hydrogen economy”, based, at least in the medium term, on fossil fuels.

scholarly journals Observing carbon dioxide emissions over China's cities with the Orbiting Carbon Observatory-2

2020 ◽  
Author(s):  
Bo Zheng ◽  
Frederic Chevallier ◽  
Philippe Ciais ◽  
Gregoire Broquet ◽  
Yilong Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Co2 Emissions ◽  
Carbon Dioxide Emissions ◽  
Power Plants ◽  
Global Climate ◽  
Large Cities ◽  
Independent Evaluation ◽  
Paris Climate Agreement ◽  
Carbon Dioxide Co2 ◽  
The Individual

Abstract. In order to track progress towards the global climate targets, the parties that signed the Paris Climate Agreement will regularly report their anthropogenic carbon dioxide (CO2) emissions based on energy statistics and CO2 emission factors. Independent evaluation of this self-reporting system is a fast-growing research topic. Here, we study the value of satellite observations of the column CO2 concentrations to estimate CO2 anthropogenic emissions with five years of the Orbiting Carbon Observatory-2 (OCO-2) retrievals over and around China. With the detailed information of emission source locations and the local wind, we successfully observe CO2 plumes from 60 cities and industrial regions over China and quantify their CO2 emissions from the OCO-2 observations, which add up to a total of 1.6 Gt CO2 yr−1 that account for 17 % of mainland China's annual emissions. The number of cities whose emissions are constrained by OCO-2 here is three to ten times larger than previous studies that only focused on large cities and power plants in different locations around the world. Our satellite-based emission estimates are broadly consistent with the independent values from the detailed China's emission inventory MEIC, but are more different from those of two widely used global gridded emission datasets (i.e., EDGAR and ODIAC), especially for the emission estimates for the individual cities. These results demonstrate some skill in the satellite-based emission quantification for isolated source clusters with the OCO-2, despite the sparse sampling of this instrument not designed for this purpose. This skill can be improved by future satellite missions that will have a denser spatial sampling of surface emitting areas, which will come soon in the early 2020s.

scholarly journals Cyclic Carbonates Based on Vegetable Oils

2014 ◽  
Vol 27 ◽  
pp. 20-29 ◽  
Author(s):  
D. Miloslavskiy ◽  
E. Gotlib ◽  
O. Figovsky ◽  
D. Pashin
Keyword(s):  
Carbon Dioxide ◽  
Chemical Composition ◽  
Vegetable Oils ◽  
Catalyst Concentration ◽  
Raw Materials ◽  
Cyclic Carbonates ◽  
Carbonation Reaction ◽  
Carbonation Process ◽  
Carbon Dioxide Pressure ◽  
Vegetable Raw Materials

The analysis of literary data on the obtaining of cyclic carbonates based on the vegetable oils has been carried out. The influence on carbonation reaction the type of vegetable oil, the chemical composition and catalyst concentration, state of carbon dioxide, pressure and temperature have thus been considered. The carbonation process of epoxidized oils that are valuable renewable vegetable raw materials is studied insufficiently.

scholarly journals Author Correction: Carbon dioxide storage through mineral carbonation

2020 ◽  
Vol 1 (12) ◽  
pp. 695-695
Author(s):  
Sandra Ó. Snæbjörnsdóttir ◽  
Bergur Sigfússon ◽  
Chiara Marieni ◽  
David Goldberg ◽  
Sigurður R. Gislason ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mineral Carbonation ◽  
Carbon Dioxide Storage
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