128 Effects of Additives with Isocyanate Group on Static Tensile Properties of PLLA/PBSL Polymer Blends

2013 ◽  
Vol 2013.21 (0) ◽  
pp. _128-1_-_128-2_
Author(s):  
Masahiro NISHIDA ◽  
Yoshitaka ITO ◽  
Tetsuo TAKAYAMA ◽  
Mitsugu TODO
Author(s):  
Asma Ul Hosna Meem ◽  
Kyle Rudolph ◽  
Allyson Cox ◽  
Austin Andwan ◽  
Timothy Osborn ◽  
...  

Abstract Digital light processing (DLP) is an emerging vatphotopolymerization-based 3D-printing technology where full layers of photosensitive resin are irradiated and cured with projected ultraviolet (UV) light to create a three-dimensional part layer-by-layer. Recent breakthroughs in polymer chemistry have led to a growing number of UV-curable elastomeric photoresins developed exclusively for vat photopolymerization additive manufacturing (AM). Coupled with the practical manufacturing advantages of DLP AM (e.g., industry-leading print speeds and sub-micron-level print resolution), these novel elastomeric photoresins are compelling candidates for emerging applications requiring extreme flexibility, stretchability, conformability, and mechanically-tunable stiffness (e.g., soft robotic actuators and stretchable electronics). To advance the role of DLP AM in these novel and promising technological spaces, a fundamental understanding of the impact of DLP manufacturing process parameters on mechanical properties is requisite. This paper highlights our recent efforts to explore the process-property relationship for ELAST-BLK 10, a new commercially-available UV-curable elastomer for DLP AM. A full factorial design of experiments is used to investigate the effect of build orientation and layer thickness on the quasi-static tensile properties (i.e., small-strain elastic modulus, ultimate tensile strength, and elongation at fracture) of ELAST-BLK 10. Statistical results, based on a general linear model via ANOVA methods, indicate that specimens with a flat build orientation exhibit the highest elastic modulus, ultimate tensile strength, and elongation at fracture, likely due to a larger surface area that enhances crosslink density during the curing process. Several popular hyperelastic constitutive models (e.g., Mooney-Rivlin, Yeoh, and Gent) are calibrated to our quasi-static tensile data to facilitate component-level predictive analyses (e.g., finite-element modeling) of soft robotic actuators and other emerging soft-matter applications.


2017 ◽  
Vol 885 ◽  
pp. 36-41 ◽  
Author(s):  
Károly Dobrovszky ◽  
Ferenc Ronkay

Blending polymers is an effective method to develop novel materials, tailoring the properties of the components. However, different morphology structures can be formed during the preparation, which could result in a wide diversity of mechanical and physical properties. The properties of polymer blends are most significantly influenced by the emerging range of phase inversion, which depends on the composition ratio and the viscosity ratio. In this paper various blends were prepared, utilizing polyethylene terephthalate (PET), polystyrene (PS) and two high density polyethylenes (HDPE), which differ in flowability. After preliminary homogenization by twin screw extruder, standard injection moulded specimen were prepared in order to present the effects of phase inversion on tensile properties, shrinkage and burning characteristics in binary polymer blends.


1988 ◽  
Vol 58 (5) ◽  
pp. 274-279 ◽  
Author(s):  
D. S. Varma ◽  
V. K. Dhar

Nylon 6/PET (polyethylene terephthalate) polymer blends (PET varying from 10–50%) were melt spun into fibers. Their tensile properties (at room temperature) and dynamic mechanical properties (at 110 Hz from room temperature to 200°C) were studied. An increase in the initial modulus with increasing PET content was observed. The tenacity showed an increase and then a subsequent decrease after 70/30 nylon 6/PET composition. The blend fibers showed lower extensibility. Various theories connecting modulus and tenacity (independently) with composition, interfacial adhesion, and dispersed phase morphology helped to explain the observed tensile properties. The loss tangent maxima is shifted to a higher temperature with increased PET content in the blend fiber, while the relaxation peaks become broader up to a certain composition. Further, the storage modulus increases throughout with the increase in the PET content. The Takayanagi series and parallel models have been applied, and the results describe the structural and morphological features of the blend fiber, besides explaining some of the properties.


1979 ◽  
Vol 50 (10) ◽  
pp. 6052-6060 ◽  
Author(s):  
J. R. Fried ◽  
W. J. MacKnight ◽  
F. E. Karasz

2008 ◽  
Vol 22 (09n11) ◽  
pp. 1712-1717
Author(s):  
Y. TAKAHASHI ◽  
M. DAIMARUYA ◽  
H. KOBAYASHI ◽  
H. TSUDA ◽  
H. FUJIKI

The tensile properties of YAG laser welded butt joints using different high strength steel sheets with a tensile strength of 270 MPa, 590 MPa and 980 MPa (denoted HR270, HR590 and HR980, respectively) were investigated at static and dynamic rates, together with the three kinds of laser welded joints made by the same steel sheets. The impact tensile tests were performed by using the vertical type of split Hopkinson tension bar apparatus, while the static tensile tests were carried out using a universal testing machine INSTRON5586. The impact tensile strengths were significantly increased in comparison with the static ones due to the effect of strain rate, which might be the contribution of the part of HR270 base metal. And in both of static and impact tests, the fracture strains of HR270-HR590 joint, HR270-HR980 joint and HR590-HR980 joint were about one half of the fracture strains observed in the same steel welded joints of HR270-HR270, HR270-HR270 and HR590-HR590, respectively.


2012 ◽  
Vol 2012 (0) ◽  
pp. _OS1002-1_-_OS1002-2_
Author(s):  
Masahiro NISHIDA ◽  
Seiya KUNO ◽  
Tetsuo TAKAYAMA ◽  
Mitsugu TODO

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