scholarly journals THE RHEOLOGY OF A CEMENT PASTE AND THE FROST RESISTANCE OF A PERMEABLE CONCRETE WITH AN EMULSIFIED ASPHALT MODIFIED BY A SILANE COUPLING AGENT

2020 ◽  
pp. 1-9
Author(s):  
Zhen Yan
Keyword(s):  
Cement Paste ◽  
Coupling Agent ◽  
Frost Resistance ◽  
Silane Coupling Agent ◽  
Silane Coupling ◽  
Emulsified Asphalt

scholarly journals A cement paste–tail sealant interface modified with a silane coupling agent for enhancing waterproofing performance in a concrete lining system

RSC Advances ◽  
2019 ◽  
Vol 9 (13) ◽  
pp. 7165-7175 ◽  
Author(s):  
Fan Li ◽  
Yuyou Yang ◽  
Mingjiang Tao ◽  
Xiangqian Li
Keyword(s):  
Cement Paste ◽  
Coupling Agent ◽  
Surface Coating ◽  
Silane Coupling Agent ◽  
Hydrophobic Surface ◽  
Concrete Lining ◽  
Underground Structures ◽  
System P ◽  
Silane Coupling

Although hydrophobic surface coating of concrete is currently used to enhance waterproofing performance of underground structures, the chemical and mechanical incompatibility between them is a challenge to ensure long-term waterproofing properties.

scholarly journals High-Performance Semi-Flexible Pavement Coating Material with the Microscopic Interface Optimization

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 268 ◽  
Author(s):  
Yinshan Xu ◽  
Yingjun Jiang ◽  
Jinshun Xue ◽  
Xi Tong ◽  
Yuanyuan Cheng
Keyword(s):  
Coupling Agent ◽  
Silane Coupling Agent ◽  
Cement Mortar ◽  
Flexible Pavement ◽  
Pavement Performance ◽  
Interface Characteristics ◽  
Silane Coupling ◽  
Emulsified Asphalt ◽  
Styrene Butadiene ◽  
Asphalt Mortar

This paper aims to optimize the asphalt-mortar interface characteristics of semi-flexible pavement coating material (SFPCM), three types of the interface modifiers, namely the silane coupling agent, carboxylated styrene-butadiene latex, and cationic emulsified asphalt, are selected to add into the cement mortar to optimize the asphalt-mortar interface. The microscopic characteristics of the asphalt-mortar interface and the macroscopic pavement performance of the SFPCM after the interface optimization are investigated to reveal the effect of interface modifiers and determine the best formula. Results show that: (1) The dry shrinkage of the cement mortar is increased with the increased dosage of the interface modifiers, while the strength is decreased accordingly; (2) the optimum dosages of the silane coupling agent, carboxylated styrene butadiene latex, and cationic emulsified asphalt are 0.5%, 10%, and 5%, respectively; (3) the microscopic asphalt-mortar interface characteristics of the SFPCM with different interface modifiers have significant differences; (4) the SFPCM with the cationic emulsified asphalt presents the best pavement performance, particularly the high-temperature stability. These results can be attributed to improve the pavement properties of SFPCM.

scholarly journals Modification Mechanism and Rheological Properties of Emulsified Asphalt Evaporative Residues Reinforced by Coupling-Modified Fiber

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7363
Author(s):  
Zhaofeng Lu ◽  
Lin Kong ◽  
Zhaoyi He ◽  
Hao Xu ◽  
Kang Yang ◽  
...  
Keyword(s):  
Coupling Agent ◽  
Low Temperatures ◽  
Silane Coupling Agent ◽  
Basalt Fiber ◽  
Evaporation Residue ◽  
Soaking Time ◽  
Silane Coupling ◽  
Emulsified Asphalt ◽  
Rheological Test ◽  
Treatment Concentration

In order to solve the problems of the smooth surface of basalt fiber and its weak interfacial adhesion with emulsified asphalt cold recycled mixture, a silane coupling agent (KH550) was used to treat the surface of basalt fiber and the effects of treatment concentration and soaking time on fiber modification were studied. The influence of silane coupling-modified basalt fiber (MBF) on the rheological properties of emulsified asphalt evaporation residue was studied at high and low temperatures using three routine index tests: a dynamic shear rheological test (DSR), a bending beam rheological test (BBR), and a force ductility test. The elemental changes of the fiber before and after modification and the microstructure of the emulsified asphalt evaporation residue with the coupling-modified fiber were analyzed by Fourier infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and X-ray energy dispersive spectroscopy (EDS), which is used to study the modification mechanism of emulsified asphalt evaporation residue reinforced by coupling-modified fiber. The results indicate that the concentration and soaking time of the silane coupling agent have a great influence on the surface morphology and mechanical properties of the fiber, and that the optimal treatment concentration is 1.0% and the optimal soaking time is 60 min. The addition of coupling-modified fibers can reduce the phase angle and unrecoverable creep compliance of emulsified asphalt evaporation residue, increase the rutting factor and creep recovery rate, and improve the elastic recovery ability and permanent deformation resistance. However, excessive fiber will weaken the ductility of emulsified asphalt at low temperatures. The appropriate content of silane coupling-modified fiber (MBF) is 1.5%. After silane coupling modification, the fiber surface becomes rough and cohesion is enhanced between the fiber and the emulsified asphalt base. Silane coupling-modified basalt fiber (MBF) acts as reinforcement for stability and bridging cracks.

scholarly journals Improved Hydrophobicity of Macroalgae Biopolymer Film Incorporated with Kenaf Derived CNF Using Silane Coupling Agent

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2254
Author(s):  
Adeleke A. Oyekanmi ◽  
N. I. Saharudin ◽  
Che Mohamad Hazwan ◽  
Abdul Khalil H. P. S. ◽  
Niyi G. Olaiya ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Coupling Agent ◽  
Silane Coupling Agent ◽  
Cellulose Nanofibrils ◽  
Hydroxyl Groups ◽  
Water Contact ◽  
Silane Coupling ◽  
Cnf Films ◽  
Kenaf Bast ◽  
Thermal Stability Of

Hydrophilic behaviour of carrageenan macroalgae biopolymer, due to hydroxyl groups, has limited its applications, especially for packaging. In this study, macroalgae were reinforced with cellulose nanofibrils (CNFs) isolated from kenaf bast fibres. The macroalgae CNF film was after that treated with silane for hydrophobicity enhancement. The wettability and functional properties of unmodified macroalgae CNF films were compared with silane-modified macroalgae CNF films. Characterisation of the unmodified and modified biopolymers films was investigated. The atomic force microscope (AFM), SEM morphology, tensile properties, water contact angle, and thermal behaviour of the biofilms showed that the incorporation of Kenaf bast CNF remarkably increased the strength, moisture resistance, and thermal stability of the macroalgae biopolymer films. Moreover, the films’ modification using a silane coupling agent further enhanced the strength and thermal stability of the films apart from improved water-resistance of the biopolymer films compared to unmodified films. The morphology and AFM showed good interfacial interaction of the components of the biopolymer films. The modified biopolymer films exhibited significantly improved hydrophobic properties compared to the unmodified films due to the enhanced dispersion resulting from the silane treatment. The improved biopolymer films can potentially be utilised as packaging materials.

Evaluation of epoxy asphalt rubber with silane coupling agent used as tack coat for seasonally frozen orthotropic steel bridge decks

2020 ◽  
Vol 241 ◽  
pp. 117957 ◽  
Author(s):  
Qibo Huang ◽  
Zhendong Qian ◽  
Leilei Chen ◽  
Meng Zhang ◽  
Xiaorui Zhang ◽  
...  
Keyword(s):  
Coupling Agent ◽  
Silane Coupling Agent ◽  
Bridge Decks ◽  
Steel Bridge ◽  
Asphalt Rubber ◽  
Epoxy Asphalt ◽  
Silane Coupling ◽  
Tack Coat

A DENSITY FUNCTIONAL STUDY OF THE STRUCTURE OF SILANE COUPLING AGENT 3–AMINOPROPYLTRIETHOXYSILANE

2005 ◽  
Vol 04 (01) ◽  
pp. 117-126
Author(s):  
N. L. MA ◽  
P. WU
Keyword(s):  
Coupling Agent ◽  
Density Functional ◽  
Solution Structure ◽  
Silane Coupling Agent ◽  
Industrial Applications ◽  
Functional Study ◽  
Stable Form ◽  
Functional Theory ◽  
Silane Coupling ◽  
The Stability

Using density functional theory, we predicted the solution structure of the hydrolyzed 3–aminopropyltriethoxysilane (h–APS), which is a silane coupling agent commonly used in many industrial applications. We have located five stable minima on the potential energy surface of h–APS in which four of them are "neutral", and the remaining one is zwitterionic (dipolar) in nature. Our calculations suggested that the stability of the most stable form of h–APS in water (denoted as II_N) arose from strong intramolecular OH ⋯ N hydrogen bond. The least stable form is the zwitterionic form (I_ZW), which is estimated to be over 90 kJ mol -1 less stable than II_N. The factors governing the relative stabilities of different forms are discussed.

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