Diamond-like carbon (DLC) films have been intensively studied with a
view to improving orthopaedic implants. Studies have indicated
smoothness of the surface, low friction, high wear resistance, corrosion
resistance and biocompatibility [1-4]. DLC coatings can be deposited
using various techniques, such as plasma assisted chemical vapour
deposition (PACVD), magnetron sputtering, laser ablation, and others
[5]. However it has proved difficult to obtain films which exhibit good
adhesion. The plasma immersion process, unlike the conventional
techniques, allows the deposition of DLC on three-dimensional
workpieces, even without moving the sample, without an intermediate
layer, and with high adhesion [6], an important aspect for orthopaedic
articulations. In our previous work, DLC coatings were deposited on
silicon and Ti-13Nb-13Zr alloy substrates using the plasma immersion
process for the characterization of microstructure, mechanical
properties and corrosion behaviour [7-9]. Hardness, measured by a
nanoindenter, ranged from 16.4-17.6 GPa, the pull test results indicate
the good adhesion of DLC coatings to Ti-13Nb-13Zr, and electrochemical
assays (polarization test and electrochemical impedance spectroscopy)
indicate that DLC coatings produced by plasma immersion can improve the
corrosion resistance [9].