The Corrosion Resistance and Mechanism of AT13/Fe-Based Amorphous Composite Coatings

Due to high strength, high wear resistance and high corrosion resistance, the amorphous metallic glasses were investigated widely. In the present study, the corrosion resistance of amorphous coating and composite coatings with various proportions of AT13 (Al2O3–13 wt.% TiO2) ceramic as additions in 3.5 wt.% NaCl solution were studied. The corrosion resistance was improved obviously as the addition of AT13, and when the content of AT13 was 15 wt.%, the composite coating had the lowest corrosion current density (1.75 × 10−6 A cm−2) and the highest corrosion potential (−411 mV), which was 5.14 × 10−5 A cm−2 and −580 mV for Fe-based metallic glassy coating, respectively. The corrosion mechanism was proposed according to the long-time immersion corrosion test.

Microstructure Examination and Sliding Wear Behavior of Al-15%Mg2Si-xGd In Situ Composites before and after Hot Extrusion

In current study; the effect of various Gadolinium (Gd) additions on the microstructure and sliding wear behaviour of Al-15%Mg2Si composite before and after the hot extrusion process was examined. Optical microscopy (OM), scanning electron microscopy (SEM) equipped with EDX facility and X-ray diffraction (XRD) were used to characterize the microstructure. The results showed that with addition of 1.0 wt.% Gd to Al-15%Mg2Si composite, the primary Mg2Si particles size reduced from 44 µm to 23 µm and its morphology altered from dendritic to polygonal shape. Further refinement of primary Mg2Si particles was achieved after conducting hot extrusion which resulted in a decrease in its size to 19 µm with a transfer to near-spherical morphology. The Vickers hardness value increased from 55.6 HV in the as-cast and unmodified composite to 72.9 HV in the extruded 1.0% Gd modified composite. The wear test results revealed that composites treated with Gd possess higher wear resistance in comparison with those of without Gd. The highest wear resistance obtained with the lowest wear rates of 0.19 mm3/km and 0.14 mm3/km in the Al-15%Mg2Si-1.0% Gd before and after the hot extrusion, respectively. The high wear resistance of extruded Gd-modified Al-15%Mg2Si composite is due to the refinement of primary Mg2Si particles with uniform distribution in the composite matrix along with fragmentation of Gd intermetallic compounds.

Thermal and Mechanical Analyses of Dry Clutch Disk made of Functionally Graded Material.

This paper presents an innovative utility of Functionally Graded Aluminum Matrix Composite (FGAMC) with Silicon Carbide as a friction material in clutches since having an acceptable friction coefficient and high wear resistance. FGAMC’s properties were calculated using rule-of-mixture and power law, represented by layered geometry. FGAMC’s behavior is examined considering statics, dynamics, thermal and wear. Analyses were done using Finite Element method, by ANSYS. Results are discussed by comparing FGAMC’s clutch to Aluminum matrix composite with 20% of Silicon Carbide clutch and E-glass clutch. Clutches design based on the common size and working conditions of clutches in mid-size and heavy automobiles. Most analyses revels FGAMC’s clutch has higher strain than AMC’s clutch with less deformation in thickness direction and less stresses. FGAMC’s clutch has higher mass leading to lower first natural frequency but with low resulted deformations. Transient analyses showed 10 times fewer maximum deformations for FGAMC’s clutch than AMC and E-glass with lower strains and higher stress but in much less area for FGAMC’s clutch. Wear which indicates working life of a clutch, have been studied using Archard Wear Equation in ANSYS, FGAMC’s clutch has 10 times lower wear with much less affected area compared to AMC and E-glass. Thermal analysis results of the three clutches are close to each other with 0.07 watts between FGAMC’s and AMC’s clutches, and 0.03 watts between FGAMC’s and E-Glass’s clutches.

Influence of Combined Mechanical Processes on Tribological Properties of Tool Steels Vanadis 8 and Vancron 40 With a Similar Hardness

Surface integrity is important factor for components exposed to wear, like cold working tools, which need to possess high hardness combined with high wear resistance. Surface treatments such as grinding, hard turning, and hard turning with slide burnishing have been developed for its improvement. Vancron 40 and Vanadis 8 tool steels, of different chemical composition and different types and amounts of carbides, were now investigated. Heat treatment was carried out in vacuum furnaces with gas quenching to hardness of Vancron 64 ± 1 HRC and of Vanadis 65 ± 1 HRC. 3D topography, optical and scanning electron microscopy, X-ray diffraction and ball-on-disc tribological tests against Al2O3 and 100Cr6 balls as counterparts were used to examine wear and friction. For both steels, the lowest values of dynamic frictions and wear rates against Al2O3 counterbodies were achieved after sequential process of hard turning with slide burnishing with a burnishing force of 180 N. For alumina balls, the increase of wear resistance, achieved after hard turning plus burnishing in comparison to grinding exceeds 50 and 60%, respectively for Vanadis 8 and Vancron 40 steels.

Structure and Tribo-Mechanical Properties of MoSx:N:Mo Thin Films Synthesized by Reactive dcMS/HiPIMS

Modifying MoS2 thin films by additional elements shows great potential in order to adjust the property profile and to meet the increasing requirements regarding high wear resistance and low friction properties of industrial components. Within that context, MoSx:N:Mo thin films were deposited by a reactive hybrid dcMS/HiPIMS process. By systematically increasing the Mo target cathode power, an investigation of the structural and the mechanical properties was conducted to understand the evolution of the tribological behavior. A low Mo target cathode power of 1 kW is related to the formation of the preferential (002) MoS2 basal-plane and thus a low friction with µ = 0.2. With an increasing amount of Mo, the film loses its solid lubricant MoS2 properties and a nitride constitution of the thin film is developing due to the formation of crystalline Mo and MoN phases. Related to this transformation, the hardness and elastic modulus are increased, but the adhesion and the tribological properties are impaired. The film loses its plasticity and the generated film material is directly removed from the contact area during the sliding contact.

Effect of Nano-Si3N4 on the Mechanical Properties of Cement-Based Materials

In this paper, in order to improve the wear resistance of road cement, nano-Si3N4 (NSN) was incorporated into cement, and the effect of NSN on compressive strength and wear resistance of road cement was investigated. The main variable of the experimental investigation was the dosage of NSN. The experimental results showed that the addition of NSN could significantly improve the compressive strength and wear resistance of cement paste. Compared with the reference group, the wear resistance can be improved by 46.5% and the compressive strength of cement paste can be improved by 12.3% when the addition of NSN is 0.16% by weight. In addition, the improvement mechanisms of NSN on cement paste were revealed by hydration heat, XRD, DTA-TG, nanoindentation, nitrogen adsorption, and SEM for microscopic phase tests. Through the microscopic analysis, the addition of NSN can accelerate the hydration reaction and promote the hydration degree, optimize the pore structure, and make the cement paste more compact. Additionally, NSN can improve the performance of the interface transition zone (ITZ) and increase the content of HD C-S-H gel. The action mechanism of NSN is mainly dominated by the surface effect, filling effect, and larger surface energy of NSN thereby improving the mechanical properties of cement-based materials. These research results have guiding significance for the design of the high wear resistance and high compressive strength of cement-based materials.

Increasing the durability of the coupling "crankshaft neck – bearing liner" by applying nanocomposite additives to the engine oils of marine medium-speed diesel engines

Повышение долговечности трибосопряжений судовых дизелей, определяющих их ресурс, представляет собой актуальнейшую проблему, обусловленную как безопасностью мореплавания, так и экономическими факторами. Основной причиной отказов коленчатых валов двигателей, определяющих необходимость капитального ремонта, является износ шеек. Решение проблемы повышения износостойкости и, соответственно, долговечности связано с применением трибоактивных присадок в смазку. Несмотря на глубокие и обстоятельные исследования в области применения органо-неорганических материалов для использования в качестве присадок в моторное масло для повышения долговечности трибоузлов осуществить выбор оптимального материала для конкретных условий практически невозможно, так как исследования выполнены для различных условий эксплуатации и по различным методикам. Цель работы – разработка триботехнической присадки к моторным маслам, обеспечивающей повышение надежности и эффективности технической эксплуатации судовыхсреднеоборотных дизелей путем формирования тонкопленочного металлокерамического покрытия на поверхностях трения стальных деталей трибоузлов, позволяющего получить оптимальный комплекс параметров материала износостойкого покрытия. В работе представлены исследования эксплуатационных свойств присадок в моторное масло 17 органо-неорганических триботехнических материалов 4 групп — природные и искусственные полимеры, из которых были изготовлены свыше 20 композиций и композитов. Установлено, что наиболее перспективным является использование нанокомпозитов на основе вермикулита, модифицированного кислотой, в качестве присадок в моторное масло, так как они обладают минимальными коэффициентом трения при граничной смазке (0,007–0,014) а также высокой износостойкостью стали 40Х и обеспечивают минимальную величину скорости изнашивания вкладыша подшипника, благодаря чему повышается ресурс трибосопряжения более, чем в 3 раза, и соответственно снижаются эксплуатационные расходы. Increasing the durability of the tribo-couplings of marine diesel engines, which determine their resource, is an urgent problem due to both the safety of navigation and economic factors. The main reason for engine crankshafts failures, which determine the need for major repairs, is the wear of the necks. The solution to the problem of increasing wear resistance and, accordingly, durability is associated with the use of triboactive additives in the lubricant. Despite in-depth and thorough research in the field of application of organo-inorganic materials for use as additives in engine oil to increase the durability of tribo-nodes, it is almost impossible to choose the optimal material for specific conditions, since the studies were carried out for various operating conditions and according to various methods. The purpose of the work is to develop a tribotechnical additive to motor oils that provides an increase in the reliability and efficiency of technical operation of medium-speed marine diesel engines by forming a thin-film metal-ceramic coating on the friction surfaces of steel parts of tribo-nodes, which allows to obtain an optimal set of parameters of the wear-resistant coating material. The paper presents studies of the operational properties of additives in engine oil of 17 organo-inorganic tribotechnical materials of 4 groups — natural and artificial polymers, from which more than 20 compositions and composites were made. It has been established that the most promising is the use of nanocomposites based on vermiculite modified with acid as additives in engine oil, since they have a minimum coefficient of friction with boundary lubrication (0.007-0.014) as well as high wear resistance of 40X steel and provide a minimum wear rate of the bearing liner, thereby increasing the tribo-tension life by more than 3 times, and, accordingly, operating costs are reduced.

ASSAB 2083

Assab 2083 is a 13.5% chromium corrosion resistant mold steel that is characterized by high wear resistance and good polishability. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as heat treating and machining. Filing Code: TS-822. Producer or source: Assab Group.

Investigation of friction and wear behavior of hydroxyl-functionalized graphene nanoplatelets filled elastomer nanocomposites

The use of unfilled pure elastomer parts is limited in friction wheels, roller tires, sealing elements, and dynamic friction air suspension applications requiring high wear resistance. This study investigates the mechanical and tribological properties of new nanocomposites obtained by adding hydroxyl-functionalized graphene nanoplatelets at 1, 4, and 8 phr (parts per hundred rubber) ratios to the carbon black filled main rubber compound of sealing elements designed for axle hubs. The synergistic effect of nanofiller materials on the wear behavior of nanocomposites was tested with a block-on-ring wear tester under dry sliding conditions at 1000 rpm and 15 N normal load conditions. The worn surfaces were examined with scanning electron microscopy and circularly polarized light–differential interference contrast topology microscopy to reveal the wear mechanism. The addition of functionalized graphene nanoplatelets to the nanocomposite compound caused significant changes in tensile strength and elongation values by changing the cross-link density. The wear rate of nanocomposites prepared with graphene nanoplatelets at 1, 4, and 8 phr ratios was 11.15%, 25.24%, and 36.54% lower than the main rubber mixture used, respectively. While the hysteresis loss decreased by 14.83% at 1 phr, this value increased in other filler ratios. Significant differences in temperature change occurred as the amount of filler increased. After the test, the temperature values of nanocomposites with 1 and 4 phr filler ratios were between about 85–89°C, while it was measured as 99°C in nanocomposites with 8 phr filler ratios. It has been observed that the homogeneous distribution of two-dimensional carbon allotropes such as graphene nanoplatelet added to the rubber matrix at the optimum rate will improve tribological properties such as better surface lubrication, low wear rate, and low friction coefficient.