scholarly journals Anisotropic in Situ Metal Matrix Composite Reinforced with VC Carbide Fibres

2015 ◽  
Vol 15 (1) ◽  
pp. 21-24 ◽  
Author(s):  
M. Kawalec ◽  
M. Górny ◽  
G. Sikora

Abstract A eutectic reaction is a basic liquid-solid transformation, which can be used in the fabrication of high-strength in situ composites. In this study an attempt was made to ensure directional solidification of Fe-C-V alloy with hypereutectic microstructure. In this alloy, the crystallisation of regular fibrous eutectic and primary carbides with the shape of non-faceted dendrites takes place. According to the data given in technical literature, this type of eutectic is suitable for the fabrication of in-situ composites, owing to the fact that a flat solidification front is formed accompanied by the presence of two phases, where one of the phases can crystallise in the form of elongated fibres. In the present study an attempt was also made to produce directionally solidifying vanadium eutectic using an apparatus with a very high temperature gradient amounting to 380 W/cm at a rate of 3 mm/h. Alloy microstructure was examined in both the initial state and after directional solidification. It was demonstrated that the resulting microstructure is of a non-homogeneous character, and the process of directional solidification leads to an oriented arrangement of both the eutectic fibres and primary carbides.

2011 ◽  
Vol 284-286 ◽  
pp. 230-233 ◽  
Author(s):  
Chun Juan Cui ◽  
You Ping Ma ◽  
Lei Yang ◽  
Ke Yong Zhai

Ni3Si compound is one of the excellent high temperature structural materials, because it possesses the attributes of high melting point, high strength, low density, excellent oxidation resistance at elevated temperatures, and magnificent corrosion resistance in acid environments, particularly sulfuric acid solutions, while the application of this compound is limited due to poor ductility at ambient temperatures and lack of fabricability at high temperatures. The incorporation of a ductile phase into the intermetallic materials has become an attractive means to modify the ductility. In this paper Ni-Ni3Si hypoeutectic in situ composites are obtained by Bridgman directional solidification technology. Microstructure of the Ni- Ni3Si hypoeutectic in situ composites are regular lamellar eutectic structure at the lower solidification rates, whereas eutectic cells or dendrites can be found with the increase of the solidification rate, due to the increase of the composition undercooling. Moreover, the directional solidification mechanism was investigated as well.


2007 ◽  
Vol 336-338 ◽  
pp. 1406-1408 ◽  
Author(s):  
Xiao Hui Zhi ◽  
Jian Dong Xing ◽  
Yi Min Gao ◽  
Xiao Jun Wu ◽  
Xiao Le Cheng

In the present study, a Fe-Cr-C hypereutectic alloy was prepared from industry-grade materials and subjected to modification and fluctuation, through which new types of particle reinforced composites, hypereutectic in-situ composite, was generated. The structures of the composite modified or not with the range of fluctuation addition from 0% to 2.8wt.%, were investigated. The primary carbides were refined with the addition of modifying agents and fluctuations. Increasing the amount of fluctuation resulted in finer primary carbides. At 1380oC, with the addition of modifying agents and 2.8wt.% fluctuation addition, the structure was well modified.


2012 ◽  
Vol 1516 ◽  
pp. 255-260 ◽  
Author(s):  
G. Zhang ◽  
L. Hu ◽  
W. Hu ◽  
G. Gottstein ◽  
S. Bogner ◽  
...  

ABSTRACTMo fiber reinforced NiAl in-situ composites with a nominal composition Ni-43.8Al-9.5Mo (at.%) were produced by specially controlled directional solidification (DS) using a laboratory-scale Bridgman furnace equipped with a liquid metal cooling (LMC) device. In these composites, single crystalline Mo fibers were precipitated out through eutectic reaction and aligned parallel to the growth direction of the ingot. Mechanical properties, i.e. the creep resistance at high temperatures (HT, between 900 °C and 1200 °C) and the fracture toughness at room temperature (RT) of in-situ NiAl-Mo composites, were characterized by tensile creep (along the growth direction) and flexure (four-point bending, vertical to the growth direction) tests, respectively. In the current study, a steady creep rate of 10-6s-1 at 1100 °C under an initial applied tensile stress of 150MPa was measured. The flexure tests sustained a fracture toughness of 14.5 MPa·m1/2at room temperature. Compared to binary NiAl and other NiAl alloys, these properties showed a remarkably improvement in creep resistance at HT and fracture toughness at RT that makes this composite a potential candidate material for structural application at the temperatures above 1000 °C. The mechanisms responsible for the improvement of the mechanical properties in NiAl-Mo in-situ composites were discussed based on the investigation results.


2020 ◽  
Vol 181 ◽  
pp. 121-126 ◽  
Author(s):  
Shifeng Liu ◽  
Jingbo Liu ◽  
Liqiang Wang ◽  
Robin Lok-Wang Ma ◽  
Yinsheng Zhong ◽  
...  

Author(s):  
Narendra Kumar ◽  
Gaurav Gautam ◽  
Rakesh Kumar Gautam ◽  
Anita Mohan ◽  
Sunil Mohan

In the present study, in situ reaction technique has been employed to prepare AA5052 matrix composites reinforced with different vol. % of ZrB2 particles (i.e., 0, 4.5, and 9 vol. %). Composites have been characterized by X-ray diffraction (XRD) to confirm the in situ formation of ZrB2 particles in the matrix. Optical Microscopy (OM) studies reveal the refinement of aluminum-rich phase due to the presence of ZrB2 particles. Scanning electron microscopy (SEM) studies reveal size and distribution of ZrB2 particles while transmission electron microscopy (TEM) reveals the presence of dislocations in the matrix around ZrB2 particles. Hardness and tensile testing of composites have been carried out at room temperature to evaluate the mechanical properties. The results reveal the improvement in hardness and strength with increased amount of ZrB2 particles. Strength of AA5052/ZrB2 in situ composites has been analyzed by various strengthening mechanism models. The analysis revealed that Orowan and Solid solution strengthening mechanisms are the predominant mechanism for high strength composites. Theoretical yield strength is about 6–10% higher than the experimental values due to clustering tendency of ZrB2 particles.


2004 ◽  
Vol 261-263 ◽  
pp. 1439-1444 ◽  
Author(s):  
Sheng Wu Wang ◽  
Hisatoshi Hirai ◽  
Tatsuo Tabaru ◽  
A. Kitahara ◽  
Hideto Ueno

Nb base in-situ composites with the base composition of Nb-5Mo-2W-18Si were prepared by conventional arc-melting and induction heating floating zone melting followed by directional solidification. To investigate the effect of HfC addition, Nb was replaced with 0, 1 and 2 mol% HfC. The in-situ composites predominantly have an eutectic microstructure consisting of Nb solid solution (NbSS) and (Nb,Mo,W))5Si3 (5-3 silicide). The strength at 1470 K and 1670 K increases without fracture toughness decreasing, with increasing the HfC content. Directional solidification also improves the strength at the high temperature. The slip band under the shearing stress occurs in the NbSS during plastic deformation, which contributes to suppress microcrack propagation. It seems that HfC addition reinforces the bonding strength at grain boundary or NbSS/5-3 silicide interface.


2000 ◽  
Vol 646 ◽  
Author(s):  
B.P. Bewlay ◽  
C.L. Briant ◽  
E.T. Sylven ◽  
M.R. Jackson ◽  
G. Xiao

ABSTRACTNb-silicide composites combine a ductile Nb-based solid solution with high-strength silicides, and they show great promise for aircraft engine applications. Previous work has shown that the silicide composition has an important effect on the creep rate. If the Nb:(Hf+Ti) ratio is reduced below ∼1.5, the creep rate increases significantly. This observation could be related to the type of silicide present in the material. To understand the effect of each phase on the composite creep resistance, the creep rates of selected monolithic phases were determined. To pursue this goal, monolithic alloys with compositions similar to the Nb-based solid solution and to the silicide phases, Laves, and T2 phases, were prepared. The creep rates were measured under compression at 1100 and 1200°C. The stress sensitivities of the creep rates of the monolithic phases were also determined. These results allow quantification of the load bearing capability of the individual phases in the Nb-silicide based in-situ composites.


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