Plasmas Generated with Gas Mixtures at the Atmospheric Pressure

2011 ◽  
Vol 20 (4) ◽  
Author(s):  
M. D. Calzada ◽  
J. Muñoz ◽  
R. Rincón ◽  
M. Jiménez ◽  
M. Sáez

AbstractSeveral applications, such as metal surface nitriding, medical instrument sterilization and chemical analysis, have been developed or improved using a gas mixture as plasmogen gas. Research carried out on these subjects covers the aspect of knowing the processes that take place in plasmas which depend on the densities of the different plasma particles and their energy values. In this paper, the results obtained from the application of spectroscopic techniques for the characterization of surface wave discharges at the atmospheric pressure, generated with more than one gas type, are presented, particularly for the Ar-He, Ar-Ne and Ar-N

2009 ◽  
Vol 3 (1) ◽  
pp. 52-57 ◽  
Author(s):  
Jose Munoz ◽  
Jose Antonio Bravo ◽  
Maria Dolores Calzada

2012 ◽  
Vol 45 (5) ◽  
pp. 055201 ◽  
Author(s):  
J Hnilica ◽  
V Kudrle ◽  
P Vašina ◽  
J Schäfer ◽  
V Aubrecht

2005 ◽  
Vol 59 (4) ◽  
pp. 519-528 ◽  
Author(s):  
M. C. García ◽  
C. Yubero ◽  
M. D. Calzada ◽  
M. P. Martínez-Jiménez

A surface-wave-sustained discharge created by using a surfatron device in a tube open to the atmosphere can be used to maintain a microwave (2.45 GHz) plasma at atmospheric pressure at powers of less than 300 W. The TIA ( Torche à Injection Axiale) is a device also producing a plasma that, moreover, permits us to work at high power (higher than 200 W and up to 1000 W). A study of the departure from the thermodynamic equilibrium existing in the argon plasmas created by both devices has been done by using optical emission spectroscopy techniques in order to characterize them and to evaluate their possible advantages when they are used for applied purposes.


1997 ◽  
Vol 51 (5) ◽  
pp. 707-717 ◽  
Author(s):  
R. L. Webb ◽  
J. T. Dickinson ◽  
G. J. Exarhos

We present observations of submicrometer- to micrometer-sized particles generated by high-fluence (≥10 J/cm2) 248-nm laser ablation of single-crystal NaNO3 in vacuum and at atmospheric pressure. Small particles (50–200 nm in diameter) are ejected by hydrodynamic sputtering. Larger particles (1–20 μm in diameter) are produced by cavitation and spallation in the melt. Many particles formed in air carry electric charge, with roughly equal numbers of positively and negatively charged particles. The particle composition is consistent with substantial nitrate decomposition. The implications of these observations with respect to laser-based chemical analysis are discussed.


2015 ◽  
Vol 35 (6) ◽  
pp. 993-1014 ◽  
Author(s):  
J. A. Bravo ◽  
R. Rincón ◽  
J. Muñoz ◽  
A. Sánchez ◽  
M. D. Calzada

Author(s):  
Bradley L. Thiel ◽  
Chan Han R. P. ◽  
Kurosky L. C. Hutter ◽  
I. A. Aksay ◽  
Mehmet Sarikaya

The identification of extraneous phases is important in understanding of high Tc superconducting oxides. The spectroscopic techniques commonly used in determining the origin of superconductivity (such as RAMAN, XPS, AES, and EXAFS) are surface-sensitive. Hence a grain boundary phase several nanometers thick could produce irrelevant spectroscopic results and cause erroneous conclusions. The intergranular phases present a major technological consideration for practical applications. In this communication we report the identification of a Cu2O grain boundary phase which forms during the sintering of YBa2Cu3O7-x (1:2:3 compound).Samples are prepared using a mixture of Y2O3. CuO, and BaO2 powders dispersed in ethanol for complete mixing. The pellets pressed at 20,000 psi are heated to 950°C at a rate of 5°C per min, held for 1 hr, and cooled at 1°C per min to room temperature. The samples show a Tc of 91K with a transition width of 2K. In order to prevent damage, a low temperature stage is used in milling to prepare thin foils which are then observed, using a liquid nitrogen holder, in a Philips 430T at 300 kV.


Author(s):  
K.M. Jones ◽  
M.M. Al-Jassim ◽  
J.M. Olson

The epitaxial growth of III-V semiconductors on Si for integrated optoelectronic applications is currently of great interest. GaP, with a lattice constant close to that of Si, is an attractive buffer between Si and, for example, GaAsP. In spite of the good lattice match, the growth of device quality GaP on Si is not without difficulty. The formation of antiphase domains, the difficulty in cleaning the Si substrates prior to growth, and the poor layer morphology are some of the problems encountered. In this work, the structural perfection of GaP layers was investigated as a function of several process variables including growth rate and temperature, and Si substrate orientation. The GaP layers were grown in an atmospheric pressure metal organic chemical vapour deposition (MOCVD) system using trimethylgallium and phosphine in H2. The Si substrates orientations used were (100), 2° off (100) towards (110), (111) and (211).


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