scholarly journals Dynamical and technological consequences of multiple isolas of steady states in a catalytic fluidised-bed reactor

2017 ◽  
Vol 38 (3) ◽  
pp. 411-422
Author(s):  
Katarzyna Bizon

Abstract Steady-state characteristics of a catalytic fluidised bed reactor and its dynamical consequences are analyzed. The occurrence of an untypical steady-state structure manifesting in a form of multiple isolas is described. A two-phase bubbling bed model is used for a quantitative description of the bed of catalyst. The influence of heat exchange intensity and a fluidisation ratio onto the generation of isolated solution branches is presented for two kinetic schemes. Dynamical consequences of the coexistence of such untypical branches of steady states are presented. The impact of linear growth of the fluidisation ratio and step change of the cooling medium temperature onto the desired product yield is analyzed. The results presented in this study confirm that the identification of a region of the occurrence of multiple isolas is important due to their strong impact both on the process start-up and its control.

Author(s):  
A. Andreini ◽  
D. Bertini ◽  
L. Mazzei ◽  
S. Puggelli

Incoming standards on NOx emissions are motivating many aero-engines manufacturers to adopt the lean burn combustion concept. However, several technological issues have to be faced in this transition, among which limited availability of air for cooling purpose and thermoacoustics phenomena that should be managed to safely implement this burning mode. In this scenario, standard numerical design tools are not often capable of characterizing such devices. Thus, considering also the difficulties of experimental investigations in a highly pressurized and reactive environment, unsteady scale resolved CFD methods are required to correctly understand the combustor performances. In the last years Large Eddy (LES) and hybrid RANS-LES models such as Scale Adaptive Simulations (SAS) have undergone considerable developments. Such approaches have been already applied for gaseous flames, leading to a strong enhancement in phenomena prediction with respect to standard steady-state simulations. However, huge research efforts are still required when spray flames are considered, since all the numerical models chosen to describe spray dynamics and the related reactive processes can have a strong impact on the accuracy of the whole simulation. In this work a set of scale resolved simulations have been carried out on the DLR Generic Single Sector Combustor spray flame for which measurements both in non-reactive and reactive test conditions are available. Exploiting a two-phase Eulerian-Lagrangian approach combined with a Flamelet Generated Manifold (FGM) combustion model, LES simulations have been performed in order to assess the potential improvements with respect to steady state solutions. Additional comparisons have also been accomplished with SAS calculations based on Eddy Dissipation combustion model (EDM). The comparison with experimental results shows that the chosen unsteady strategies lead to a more physical description of reactive processes with respect to RANS simulations. FGM model showed some limitations in reproducing the partially-premixed nature of the flame, whereas SAS-EDM proved to be a robust modelling strategy within an industrial perspective. A new set of spray boundary conditions for liquid injection is also proposed whose realiability is proved through a detailed comparison against experimental data.


2009 ◽  
Vol 16 (6) ◽  
pp. 677-690 ◽  
Author(s):  
J. C. Zahnow ◽  
U. Feudel

Abstract. We present results from an individual particle based model for the collision, coagulation and fragmentation of heavy drops moving in a turbulent flow. Such a model framework can help to bridge the gap between the full hydrodynamic simulation of two phase flows, which can usually only study few particles and mean field based approaches for coagulation and fragmentation relying heavily on parameterization and are for example unable to fully capture particle inertia. We study the steady state that results from a balance between coagulation and fragmentation and the impact of particle properties and flow properties on this steady state. We compare two different fragmentation mechanisms, size-limiting fragmentation where particles fragment when exceeding a maximum size and shear fragmentation, where particles break up when local shear forces in the flow exceed the binding force of the particle. For size-limiting fragmentation the steady state is mainly influenced by the maximum stable particle size, while particle and flow properties only influence the approach to the steady state. For shear fragmentation both the approach to the steady state and the steady state itself depend on the particle and flow parameters. There we find scaling relationships between the steady state and the particle and flow parameters that are determined by the stability condition for fragmentation.


Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3478
Author(s):  
Przemysław Rybiński ◽  
Bartłomiej Syrek ◽  
Witold Żukowski ◽  
Dariusz Bradło

The article illustrates the impact of basalt filler in the form of flakes and fibres on the toxicity of gaseous products that formed during the thermal decomposition of silicone rubber composites. The values of specific emissions of gases were determined with the help of the IR spectroscopy and further applied to calculate the toxicometric index. The presented method of measuring the concentrations of gaseous products resulting from thermal decomposition consists in the application of a fluidised bed reactor, which makes it possible to conduct the decomposition of a sample at a precisely assumed temperature value and imitate the conditions of a real fire. At a temperature lower than 700 °C, the gases resulting from the thermal decomposition of composites are particularly toxic due to the presence of significant concentrations of formaldehyde that does not undergo oxidation to more stable inorganic products. At a temperature of 600 °C the toxicity of gases for the samples with ceramizable additives and without them was similar. In the first case, there appeared to be a positive synergistic effect of mineral and basalt additives, and the basalt additives themselves increased the toxicity of gases. At higher temperatures of decomposition, the exponentially increasing rate of the oxidation reaction in the gaseous phase results in the lack of significant differences between the toxicity of gases for the samples with and without basalt additives. The toxicometric index value at temperatures of 700 °C and 800 °C was by one or two orders of magnitude higher, respectively, than the one that was observed in the temperature range of 500–600 °C, as inorganic components appear in the place of formaldehyde.


2020 ◽  
Author(s):  
M Testori ◽  
M Kempf ◽  
RB Hoyle ◽  
Hedwig Eisenbarth

© 2019 Hogrefe Publishing. Personality traits have been long recognized to have a strong impact on human decision-making. In this study, a sample of 314 participants took part in an online game to investigate the impact of psychopathic traits on cooperative behavior in an iterated Prisoner's dilemma game. We found that disinhibition decreased the maintenance of cooperation in successive plays, but had no effect on moving toward cooperation after a previous defection or on the overall level of cooperation over rounds. Furthermore, our results underline the crucial importance of a good model selection procedure, showing how a poor choice of statistical model can provide misleading results.


Author(s):  
Md. Ziaul Haque

The tourism sector is experiencing numerous challenges as a result of the global economic crisis. After a significant contraction in 2009, tourism rebounded strongly  in  2010  and  in  2011  the  international  tourist  arrivals  and  receipts  are projected to increase substantially. The Tourism industry is expected to show a sustained recovery in 2012. The crisis has particularly strong impact and slightly negative consequences in Bangladesh. The country is undergoing a political crisis, as well, and it seems that the forthcoming elections may be the only solution for the restoration of stability and social peace.  In addition, tourism can be the driving force behind Bangladesh economic recovery. However, for its achievement the country’s policy makers should take several measures towards restructuring and improving the sector. These measures include: enhancement of alternative forms of tourism; environmental protection; creation of quality infrastructure; and boost of competitiveness through a tourism product that offers value for money


Author(s):  
Md. Ziaul Haque

The tourism sector is experiencing numerous challenges as a result of the global economic crisis. After a significant contraction in 2009, tourism rebounded strongly  in  2010  and  in  2011  the  international  tourist  arrivals  and  receipts  are projected to increase substantially. The Tourism industry is expected to show a sustained recovery in 2012. The crisis has particularly strong impact and slightly negative consequences in Bangladesh. The country is undergoing a political crisis, as well, and it seems that the forthcoming elections may be the only solution for the restoration of stability and social peace.  In addition, tourism can be the driving force behind Bangladesh economic recovery. However, for its achievement the country’s policy makers should take several measures towards restructuring and improving the sector. These measures include: enhancement of alternative forms of tourism; environmental protection; creation of quality infrastructure; and boost of competitiveness through a tourism product that offers value for money


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